Colorants portfolio for sensitive applications. Pigments for plastics

Transcription

1 Colorants portfolio for sensitive applications Pigments for plastics

2 Table of contents Pigments for plastics 3 Table of contents Introduction 4 Legislation on toys 45 Colorants portfolio for sensitive applications 6 Colorants for food contact materials 8 Colorants for toys 28 Other sensitive applications 46 Disclaimer 47 Appendix: Definitions and abbreviations 48 Legislation for food contact materials 39

3 Introduction Pigments for plastics 5 Introduction This document gives an overview of BASF selected colorants portfolio for plastics listed by national regulations and additionally provides a summary of the key regulations ruling colorants for plastics going into food contact materials and toys. It is meant as a general introduction for everyone who wants to get a baseline understanding of the regulatory framework for food contact material and toys. If further information is required, please contact pigments-safety@basf.com. Where general comments are provided, the original text of the law or standard has to be consulted to avoid misunderstandings and incorrect interpretations. All information in this document has been compiled with great care and reflects BASF best knowledge at the date of issue (September 2017). Due to continuous evolution of the subject, information may rapidly change and therefore this document can only be considered as a snapshot of the current situation as at the date of publication (September 2017). To ensure the full updated compliance status of a given product to the newest legislation requirements or technology changes, we strongly recommend that our customers systematically check this status with their BASF representative or contact BASF via pigments-safety@basf.com.

4 Colorants portfolio for sensitive applications 6 Pigments for plastics Pigments for plastics 7 Colorants portfolio for sensitive applications Colorants portfolio for sensitive applications Product scoping This document lists the BASF portfolio of colorants for plastics and fibers that will be actively supported for use in sensitive applications such as food packaging and toys. Detailed compliance status of BASF organic, inorganic and effect pigments as well as polymer soluble colorants and pigments preparations is provided in the Appendix table, listed for each product per national regulations. Definition and revisions BASF colorants for plastics portfolio screened for sensitive applications have been initially assessed through specific criteria such as product fingerprint including purity profile, as well as manufacturing set-up including consideration of cross-contamination risk. Also, when necessary, product processing behavior in plastics was assessed and when needed, a product would have to undergo a risk assessment under standard or specific conditions of use. As a result of all those precautionary measures, BASF can now, for all products listed in this colorants portfolio for sensitive applications, deliver Food Contact Certificates (FCC) moving forward. FCC provided by BASF for plastic food contact materials is the official document that covers the EU Declaration of Compliance (DoC) legal requirements as well as the compliance requirements of other regional jurisdictions as applicable. BASF colorants portfolio for sensitive applications is regularly reviewed in line with evolving regulatory requirements, new developments in product technol ogy and new findings in legal environment or product toxicology. In order to ensure that the regulatory requirements are continuously met, the BASF Food Contact Certificates for products in our colorants portfolio for food contact applications in plastics are updated on a 18 months basis, in order to cover the periodic updates of the Plastics Regulation (EU) No. 10/2011, or earlier in case of relevant regulatory changes. The BASF Food Contact Certificates for colorants portfolio for food contact applications in Plastics are valid for 18 months. Purity limits for BASF products in colorants portfolio for sensitive applications For products that have been selected in BASF colorants portfolio for sensitive applications, spot testing program with an adapted testing scope and frequencies are defined in order to regularly check that products are manufactured in line with target purity levels. If required, spot testing can be extended for systematic batch to batch analysis by setting up an internal specification ensuring strict monitoring of target purity profile. Typical purity limits as defined by BASF for colorants portfolio for sensitive applications are detailed below (BASF Purity Limits): Extractable impurity in the colorant Limit [ppm] Aluminum (Al) 1,000 Antimony (Sb) 45 Arsenic (As) 3 Barium (Ba) 100 Boron (B) 1,000 Cadmium (Cd) 1 Chromium (Cr III + Cr VI) 1 Cobalt (Co) 10 Copper (Cu) 600 Lead (Pb) 2 Manganese (Mn) 800 Mercury (Hg) 5 Nickel (Ni) 50 Selenium (Se) 25 Strontium (Sr) 4,500 Tin (Sn) 15,000 Zinc (Zn) 1,000 Iron (Fe) 4,500 For those products, the Management of Change process at BASF systematically aims at retaining existing compliance status for products affected by modifications such as raw materials changes or manufacturing process modifications. Even though it is the intention of BASF to sustain as much as possible the compliance scope and depth of the selective colorants portfolio for sensitive applications, no guarantee can be given that all products will remain compliant under all circumstances, e.g., future evolutions of the regulatory environment. In such cases that shall remain exceptional, BASF will strive to provide updated information to customers with pre-notice time. Lithium (Li) 500 Primary aromatic amines (PAA) 500 Benzidine, beta-naphthylamine, 4-aminobiphenyl 10 Polychlorinated biphenyls (PCB) 25 Table 1: BASF purity limits These purity limits make it possible to meet the requirements of most of the targeted end use applications, e.g., food contact packaging and toys applications.

5 Colorants for food contact materials Pigments for plastics 9 Colorants for food contact materials Status as of September 2017 This portfolio is regularly reviewed according to business needs and regulatory requirements. For any updates please contact the pigments-safety@basf.com mailbox. The overview of products compliance status in the tables on the next pages should be used as a general guide only. In any case, it does not replace the product detailed information in the Food Contact Certifi cates. For more detailed information on specifi c country requirements and conditions of use, please refer to the relevant Food Contact Certifi cates, which are available via pigments-safety@basf.com upon request.

6 Colorants for food contact materials 10 Pigments for plastics Pigments for plastics 11 Colorants for food contact materials Colorants for food contact materials Status: September 2017 Food Contact Regulations Product Old product name C.I. name European Union USA Japan Australia China Mercosur EC Regulation 10/2011 AP(89)1 Germany BfR IX France Brochure 1227 Spain Real Decreto 847/2011 Italy Decreto 21/3/73 FDA, 21CFR JHOSPA JHPA AS GB GB Art. 3.1 GMC Resolución N 15/2010 Cinquasia Magenta K 4535 Cinquasia Magenta RT-235-D PR Cinquasia Magenta K 4535 FP Cromophtal Magenta P PR Cinquasia Pink K 4410 Cromophtal Pink 2000 PR Cinquasia Pink K 4430 FP Cromophtal Pink PT PR Cinquasia Red K 4104 Cromophtal Red 2020 PV Cinquasia Red K 4111 Cromophtal Red TBR PV Cinquasia Red K 4330 Cinquasia Red B RT-195-D Cinquasia Violet K 5350 Cinquasia Violet R RT-891-D PV Cinquasia Violet K 5350 FP Cromophtal Violet RP PV Cromophtal Brown K 3001 Cromophtal Brown 5R PBr Cromophtal Orange K 2960 Cromophtal Orange GP PO Cromophtal Red K 3830 Cromophtal Red G PR Cromophtal Red K 3890 Cromophtal Red BRN PR Cromophtal Red K 3890 FP Cromophtal Red BRNP PR Cromophtal Red K 3900 Cromophtal Red BN PR Cromophtal Red K 3900 FP Cromophtal Red BNFP PR Cromophtal Red K 4035 Cromophtal Red 2B PR Cromophtal Scarlet K 3540 Cromophtal Scarlet RN PR Cromophtal Violet K 5700 Cromophtal Violet B PV Cromophtal Yellow 2GF - PY Cromophtal Yellow K 0990 Cromophtal Yellow 8GN PY Cromophtal Yellow K 0990 FP Cromophtal Yellow 8GNP PY Cromophtal Yellow K 1210 Cromophtal Yellow 3G PY Cromophtal Yellow K 1210 FP Cromophtal Yellow 3GNP PY Cromophtal Yellow K 1310 Cromophtal Yellow 4GV PY Cromophtal Yellow K 1410 Cromophtal Yellow 2GO PY Cromophtal Yellow K 1500 Cromophtal Yellow GR PY Cromophtal Yellow K 1500 FP Cromophtal Yellow GRP PY Eupolen PE Blue PB 15: Eupolen PE Blue PB 15: Eupolen PE Blue PB 15: * For more information please contact pigments-safety@basf.com

7 Colorants for food contact materials 12 Pigments for plastics Pigments for plastics 13 Colorants for food contact materials Colorants for food contact materials Status: September 2017 Food Contact Regulations Product Old product name C.I. name European Union USA Japan Australia China Mercosur EC Regulation 10/2011 AP(89)1 Germany BfR IX France Brochure 1227 Spain Real Decreto 847/2011 Italy Decreto 21/3/73 FDA, 21CFR JHOSPA JHPA AS GB GB Art. 3.1 GMC Resolución N 15/2010 Eupolen PE Blue PB 15: Eupolen PE Blue PB 15: Eupolen PE Blue PB 15: Eupolen PE Blue PB 15: Eupolen PE Blue PB 15: Eupolen PE Brown PR Eupolen PE Green PG Eupolen PE Green PG Eupolen PE Green PG Eupolen PE Green PG Eupolen PE Green PG Eupolen PE Red PR Eupolen PE Red PR Eupolen PE Yellow PY Eupolen PE Yellow PY Eupolen PE Yellow PY Eupolen PE Yellow PY 191: Eupolen PE Yellow PY 191: Eupolen PE Yellow Eupolen PE Yellow PY Eupolen PE Yellow PY Eupolen PE Yellow PY Eupolen PE Yellow PY Eupolen PE Yellow PY Firemist Blue 9G630L Firemist Gold 9G230L Firemist Green 9G830L Firemist Pearl 9G130L Firemist Red 9G430L Firemist Turquoise 9G730L Firemist Violet 9G530L Glacier Crystal White EH * For more information please contact pigments-safety@basf.com

8 Colorants for food contact materials 14 Pigments for plastics Pigments for plastics 15 Colorants for food contact materials Colorants for food contact materials Status: September 2017 Food Contact Regulations Product Old product name C.I. name European Union USA Japan Australia China Mercosur EC Regulation 10/2011 AP(89)1 Germany BfR IX France Brochure 1227 Spain Real Decreto 847/2011 Italy Decreto 21/3/73 FDA, 21CFR JHOSPA JHPA AS GB GB Art. 3.1 GMC Resolución N 15/2010 Glacier Frost White 9S130D Glacier Silk White EH 2012 (9S130V) Glacier Sparkle White EH Heliogen Blue K PB Heliogen Blue K PB Heliogen Blue K PB 15: Heliogen Blue K PB 15: Heliogen Blue K PB 15: Heliogen Blue K 6911 Heliogen Blue K 6911 D PB 15: Heliogen Blue K 6912 FP - PB 15: Heliogen Blue K PB 15: Heliogen Blue K PB 15: Heliogen Blue K 7090 FP - PB 15: Heliogen Blue K 7097 Cromophtal Blue 4GNP. PB 15: Heliogen Blue K 7104 LW - PB 15: Heliogen Green K PG Heliogen Green K PG Heliogen Green K 8730 FP - PG Heliogen Green K 8730 Z - PG Heliogen Green K 8740 Heliogen Green K 8740 LW PG Heliogen Green K 9360 FK - PG Irgalite Red K 4060 FP Irgalite Red 2BSP PR 48: Irgalite Red K 4170 FP Irgalite Red 2BP PR 48: Irgalite Rubine K 4270 FP Irgalite Rubine 4BP PR 57: Irgalite Scarlet K PR 48: Irgazin Flame Red K 3800 Cromophtal DPP Flame Red FP PR Irgazin Orange K 2890 Cromophtal Orange 2G PO Irgazin Orange K 2910 Cromophtal DPP Orange TRP PO Irgazin Red K 3840 Cromophtal Red 2030 PR Irgazin Red K 3840 LW Cromophtal Red 2028 PR Irgazin Red K 3840 SQ Cromophtal Red 1030-P PR * For more information please contact pigments-safety@basf.com

9 Colorants for food contact materials 16 Pigments for plastics Pigments for plastics 17 Colorants for food contact materials Colorants for food contact materials Status: September 2017 Food Contact Regulations Product Old product name C.I. name European Union USA Japan Australia China Mercosur EC Regulation 10/2011 AP(89)1 Germany BfR IX France Brochure 1227 Spain Real Decreto 847/2011 Italy Decreto 21/3/73 FDA, 21CFR JHOSPA JHPA AS GB GB Art. 3.1 GMC Resolución N 15/2010 Irgazin Red K 3842 Cromophtal DPP Red BP PR Irgazin Red K 3845 Irgazin DPP Red BO PR Irgazin Red K 3845 LW Cromophtal DPP Red BOC PR Irgazin Rubine K 4080 Cromophtal Rubine TR Irgazin Rubine K 4085 Irgazin Rubine L 4025 PR Irgazin Yellow K PY Irgazin Yellow K 2060 FP Cromophtal Yellow 3RLP PY Irgazin Yellow K 2060 SQ - PY Irgazin Yellow K 2070 Cromophtal Yellow 2RLTS PY Irgazin Yellow K 2080 Cromophtal Yellow 2RLP PY Lumina Aqua Blue 9A30D Lumina Brass 9232D Lumina Gold 9Y30D Lumina Green 9G30D Lumina Red 9R30D Lumina Red Blue 9B30D Lumina Royal Aqua Blue 9780H Lumina Royal Blue 9680H Lumina Royal Copper 9390H Lumina Royal Indigo 9580H Lumina Royal Magenta EH Lumina Turquoise 9T30D Magnapearl Magnapearl 1000 DF Magnapearl Magnapearl Magnapearl Magnapearl 2000 DF Magnapearl Magnapearl Magnapearl 2110 DF * For more information please contact pigments-safety@basf.com

10 Colorants for food contact materials 18 Pigments for plastics Pigments for plastics 19 Colorants for food contact materials Colorants for food contact materials Status: September 2017 Food Contact Regulations Product Old product name C.I. name European Union USA Japan Australia China Mercosur EC Regulation 10/2011 AP(89)1 Germany BfR IX France Brochure 1227 Spain Real Decreto 847/2011 Italy Decreto 21/3/73 FDA, 21CFR JHOSPA JHPA AS GB GB Art. 3.1 GMC Resolución N 15/2010 Magnapearl Magnapearl 2300 DF Magnapearl Magnapearl Magnapearl 3100 DF Magnapearl Magnapearl 4000 DF Magnapearl Magnapearl Mearlin Aztec Gold 9363 C Mearlin Brilliant Gold 9212 G Mearlin Copper 9340 A Mearlin Inca Gold 9222 G Mearlin Majestic Gold 9222 X Mearlin Majestic Gold 9222 X DF Mearlin Mayan Gold 9233 X Mearlin Micro Bronze 9250M Mearlin Satin White 9130 F Mearlin Satin White 9130 F DF Mearlin Sparkle Blue 9620 J Mearlin Sparkle Brass 9222 J Mearlin Sparkle Bronze 9250 J Mearlin Sparkle Copper 9350 J Mearlin Sparkle Gold 9212 P Mearlin Sparkle Gold 9220 J Mearlin Sparkle Green 9820 J Mearlin Sparkle Orange 9320 J Mearlin Sparkle Red 9420 J Mearlin Sparkle Russet 9450 J Mearlin Sparkle Violet 9520 J Mearlin Super Blue 9630 Z * For more information please contact pigments-safety@basf.com

11 Colorants for food contact materials 20 Pigments for plastics Pigments for plastics 21 Colorants for food contact materials Colorants for food contact materials Status: September 2017 Food Contact Regulations Product Old product name C.I. name European Union USA Japan Australia China Mercosur EC Regulation 10/2011 AP(89)1 Germany BfR IX France Brochure 1227 Spain Real Decreto 847/2011 Italy Decreto 21/3/73 FDA, 21CFR JHOSPA JHPA AS GB GB Art. 3.1 GMC Resolución N 15/2010 Mearlin Super Blue-Russet 9650 Z Mearlin Super Brass 9232 Z Mearlin Super Bronze 9250 Z Mearlin Super Copper 9350 Z Mearlin Super Gold 9230 Z Mearlin Super Green 9830 Z Mearlin Super Orange 9330 Z Mearlin Super Red 9430 Z Mearlin Super Russet 9450 Z Mearlin Super Sparkle 9110 S Mearlin Super Violet 9530 Z Mearlin Super White 9020 C Meteor Yellow 9379 FF FK Microlen Black 0068 MCN - PBk Microlen Blue 6907 MCN - PB 15: Microlen Blue 6911 MCN - PB 15: Microlen Blue 6916 MCN - PB 15: Microlen Blue 7090 MCN - PB 15: Microlen Blue 7079 MCN - PB 15: Microlen Blue 7098 MCN - PB 15: Microlen Flame Red 3800 MCN - PR Microlen Green 8730 MCN - PG Microlen Green 8745 LW MCN - PG Microlen Magenta 4535 MCN - PR Microlen Orange 2910 MCN - PO Microlen Orange 2960 MP Microlen Orange GP-MP PO Microlen Pink 4430 MCN - PR Microlen Red 3840 LW MCN - PR Microlen Red 3840 MCN - PR Microlen Red 3845 LW MCN - PR Microlen Red 3890 MCN - PR * For more information please contact pigments-safety@basf.com

12 Colorants for food contact materials 22 Pigments for plastics Pigments for plastics 23 Colorants for food contact materials Colorants for food contact materials Status: September 2017 Food Contact Regulations Product Old product name C.I. name European Union USA Japan Australia China Mercosur EC Regulation 10/2011 AP(89)1 Germany BfR IX France Brochure 1227 Spain Real Decreto 847/2011 Italy Decreto 21/3/73 FDA, 21CFR JHOSPA JHPA AS GB GB Art. 3.1 GMC Resolución N 15/2010 Microlen Red 3890 MCNQ - PR Microlen Red 4060 MCN - PR 48: Microlen Red 4104 MCN - PV Microlen Red 4170 MCN - PR 48: Microlen Red 4330 MCN Microlen Rubine 4085 MCN - PR Microlen Rubine 4270 MCN - PR 57: Microlen Violet 5700 MCN - PV Microlen Yellow 1070 MCN - PY Microlen Yellow 1210 MCN - PY Microlen Yellow 1410 MCN - PY Microlen Yellow 1500 MCN - PY Microlen Yellow 2070 MCN - PY Microlith Blue 7080 KP Microlith Blue 4G-KP PB 15: Microlith Brown 3001 KP Microlith Brown 5R-KP PBr Microlith Red 3840 KP Microlith DPP Red B-KP PR Microlith Red 3890 KP Microlith Red BR-KP PR Microlith Scarlet 3540 KP Microlith Scarlet R-KP PR Microlith Violet 5700 KP - PV Microlith Yellow 1210 KP Microlith Yellow 3G-KP PY Microlith Yellow 2060 KP Microlith Yellow 3R-KP PY Oracet Blue 690 Oracet Blue PD2104 SB Oracet Blue 780 FE Filester Blue GN SB Oracet Magenta 460 Oracet Red 5B SR Oracet Orange 220 Oracet Orange ES SO Oracet Orange 230 Oracet Orange G SO Oracet Red 344 Oracet Red GN SR Oracet Red 454 Thermoplast Red 454 SR Oracet Yellow 125 Oracet Yellow PD 2114 SY Oracet Yellow SY Oracet Yellow 140 Oracet Yellow RB PY * For more information please contact pigments-safety@basf.com

13 Colorants for food contact materials 24 Pigments for plastics Pigments for plastics 25 Colorants for food contact materials Colorants for food contact materials Status: September 2017 Food Contact Regulations Product Old product name C.I. name European Union USA Japan Australia China Mercosur EC Regulation 10/2011 AP(89)1 Germany BfR IX France Brochure 1227 Spain Real Decreto 847/2011 Italy Decreto 21/3/73 FDA, 21CFR JHOSPA JHPA AS GB GB Art. 3.1 GMC Resolución N 15/2010 Oracet Yellow 144 FE Filester Yellow RNB PY Oracet Yellow 180 Oracet Yellow GHS SY Paliogen Red K 3911 Paliogen Red K 3911 HD PR Paliogen Red K PR Paliotol Orange K PO Paliotol Yellow K 0961 Paliotol Yellow K 0961 HD PY Paliotol Yellow K 1070 Irgalite Yellow WGP PY Paliotol Yellow K PY Paliotol Yellow K PY Paliotol Yellow K 1760 FP Cromophtal Yellow HRPN PY 191: Paliotol Yellow K 1800 Paliotol Yellow K 2270 PY Paliotol Yellow K PY Paliotol Yellow K 1841 FP - PY Rightfi t Red K PR Rightfi t Red K PR Sicopal Black K PBr Sicopal Blue K PB Sicopal Blue K PB Sicopal Blue K PB Sicopal Brown K PY Sicopal Brown K PBr Sicopal Brown K 2795 FG - PBr Sicopal Green K 9715 FK - PG Sicopal Orange K PO Sicopal Yellow 1120 FG - PY Sicotan Brown K PY Sicotan Brown K PY Sicotan Yellow K PY Sicotan Yellow K PY Sicotan Yellow K 1011 FG - PY Sicotan Yellow K PBr * For more information please contact pigments-safety@basf.com

14 Colorants for food contact materials 26 Pigments for plastics Pigments for plastics 27 Colorants for food contact materials Colorants for food contact materials Status: September 2017 Food Contact Regulations Product Old product name C.I. name European Union USA Japan Australia China Mercosur EC Regulation 10/2011 AP(89)1 Germany BfR IX France Brochure 1227 Spain Real Decreto 847/2011 Italy Decreto 21/3/73 FDA, 21CFR JHOSPA JHPA AS GB GB Art. 3.1 GMC Resolución N 15/2010 Sicotan Yellow K 2001 FG - PBr Sicotan Yellow K PBr Sicotan Yellow K 2011 FG - PBr Sicotan Yellow K PBr Sicotan Yellow K PBr Sicotan Yellow K 2111 FG - PBr Sicotan Yellow K PBr Sicotan Yellow K 2112 FG - PBr Sicotrans Red K PR Sicotrans Red K PR * For more information please contact pigments-safety@basf.com

15 Colorants for toys Pigments for plastics 29 Colorants for toys Status as of September 2017 This portfolio is regularly reviewed according to business needs and regulatory requirements. For any updates please contact the mailbox. The overview of products status in the table below should be used as a guide only. In any case, it does not replace the product detailed information contained in specifi c statements about toys applications. For more detailed information on specifi c country or application requirements, please contact us via pigments-safety@basf.com. Please note that in EU, toys for children under 3 years and toys for mouth contact have to fulfi ll Article 3 of the Framework Regulation (EC) No. 1935/2004.

16 Colorants for toys Colorants for toys 30 Pigments for plastics Pigments for plastics 31 Colorants for toys Status: September 2017 SST Status Statement Toys (EN 71-3:2013 Heavy Metal Status Statement) Status: September 2017 SST Status Statement Toys (EN 71-3:2013 Heavy Metal Status Statement) Product Old product name C.I. name Toys for children under 3 years and toys for mouth contact European Union Toys for children above 3 years and no mouth contact Europe USA Australia Product Old product name C.I. name Toys for children under 3 years and toys for mouth contact European Union Toys for children above 3 years and no mouth contact Europe USA Australia 3, , 2013 ASTM F AS/NZS ISO8124.3:2003 3, , 2013 ASTM F AS/NZS ISO8124.3:2003 Cinquasia Magenta K 4535 Cinquasia Magenta RT-235-D PR Cinquasia Magenta K 4535 FP Cromophtal Magenta P PR Cinquasia Pink K 4410 Cromophtal Pink 2000 PR Cinquasia Pink K 4430 FP Cromophtal Pink PT PR Cinquasia Red K 4104 Cromophtal Red 2020 PV Cinquasia Red K 4111 Cromophtal Red TBR PV Cinquasia Red K 4330 Cinquasia Red B RT-195-D Cinquasia Violet K 5350 Cinquasia Violet R RT-891-D PV Cinquasia Violet K 5350 FP Cromophtal Violet RP PV Cromophtal Brown K 3001 Cromophtal Brown 5R PBr Cromophtal Orange K 2960 Cromophtal Orange GP PO Cromophtal Red K 3830 Cromophtal Red G PR Cromophtal Red K 3890 Cromophtal Red BRN PR Cromophtal Red K 3890 FP Cromophtal Red BRNP PR Cromophtal Red K 3900 Cromophtal Red BN PR Cromophtal Red K 3900 FP Cromophtal Red BNFP PR Cromophtal Red K 4035 Cromophtal Red 2B PR Cromophtal Scarlet K 3540 Cromophtal Scarlet RN PR Cromophtal Violet K 5700 Cromophtal Violet B PV Cromophtal Yellow 2GF - PY Cromophtal Yellow K 0990 Cromophtal Yellow 8GN PY Cromophtal Yellow K 0990 FP Cromophtal Yellow 8GNP PY Cromophtal Yellow K 1210 Cromophtal Yellow 3G PY Cromophtal Yellow K 1210 FP Cromophtal Yellow 3GNP PY Cromophtal Yellow K 1310 Cromophtal Yellow 4GV PY Cromophtal Yellow K 1410 Cromophtal Yellow 2GO PY Cromophtal Yellow K 1500 Cromophtal Yellow GR PY Cromophtal Yellow K 1500 FP Cromophtal Yellow GRP PY Eupolen PE Blue PB 15: Eupolen PE Blue PB 15: Eupolen PE Blue PB 15: Eupolen PE Blue PB 15: Eupolen PE Blue PB 15: Eupolen PE Blue PB 15: Eupolen PE Blue PB 15: Eupolen PE Blue PB 15: Eupolen PE Brown PR Eupolen PE Green PG Eupolen PE Green PG Eupolen PE Green PG Eupolen PE Green PG Eupolen PE Green PG Eupolen PE Red PR Eupolen PE Red PR Eupolen PE Yellow PY Eupolen PE Yellow PY Eupolen PE Yellow PY Eupolen PE Yellow PY 191: Eupolen PE Yellow PY 191: Eupolen PE Yellow Eupolen PE Yellow PY Eupolen PE Yellow PY Eupolen PE Yellow PY Eupolen PE Yellow PY Eupolen PE Yellow PY Firemist Blue 9G630L Firemist Gold 9G230L * For more information please contact pigments-safety@basf.com * For more information please contact pigments-safety@basf.com

17 Colorants for toys 32 Pigments for plastics Pigments for plastics 33 Colorants for toys Colorants for toys Status: September 2017 SST Status Statement Toys (EN 71-3:2013 Heavy Metal Status Statement) Status: September 2017 SST Status Statement Toys (EN 71-3:2013 Heavy Metal Status Statement) Product Old product name C.I. name Toys for children under 3 years and toys for mouth contact European Union Toys for children above 3 years and no mouth contact Europe USA Australia Product Old product name C.I. name Toys for children under 3 years and toys for mouth contact European Union Toys for children above 3 years and no mouth contact Europe USA Australia 3, , 2013 ASTM F AS/NZS ISO8124.3:2003 3, , 2013 ASTM F AS/NZS ISO8124.3:2003 Firemist Green 9G830L Firemist Pearl 9G130L Firemist Red 9G430L Firemist Turquoise 9G730L Firemist Violet 9G530L Glacier Crystal White EH Glacier Frost White 9S130D Glacier Silk White EH 2012 (9S130V) Glacier Sparkle White EH Heliogen Blue K PB Heliogen Blue K PB Heliogen Blue K PB 15: Heliogen Blue K PB 15: Heliogen Blue K PB 15: Heliogen Blue K 6911 Heliogen Blue K 6911 D PB 15: Heliogen Blue K 6912 FP - PB 15: Heliogen Blue K PB 15: Heliogen Blue K PB 15: Heliogen Blue K 7090 FP - PB 15: Heliogen Blue K 7097 Cromophtal Blue 4GNP. PB 15: Heliogen Blue K 7104 LW - PB 15: Heliogen Green K PG Heliogen Green K PG Heliogen Green K 8730 FP - PG Heliogen Green K 8730 Z - PG Heliogen Green K 8740 Heliogen Green K 8740 LW PG Heliogen Green K 9360 FK - PG Irgalite Red K 4060 FP Irgalite Red 2BSP PR 48:3 5 1 SST 1 1 Irgalite Red K 4170 FP Irgalite Red 2BP PR 48: Irgalite Rubine K 4270 FP Irgalite Rubine 4BP PR 57: Irgalite Scarlet K PR 48:3 5 1 SST 1 1 Irgazin Flame Red K 3800 Cromophtal DPP Flame Red FP PR Irgazin Orange K 2890 Cromophtal Orange 2G PO Irgazin Orange K 2910 Cromophtal DPP Orange TRP PO Irgazin Red K 3840 Cromophtal Red 2030 PR Irgazin Red K 3840 LW Cromophtal Red 2028 PR Irgazin Red K 3840 SQ Cromophtal Red 1030-P PR Irgazin Red K 3842 Cromophtal DPP Red BP PR Irgazin Red K 3845 Irgazin DPP Red BO PR Irgazin Red K 3845 LW Cromophtal DPP Red BOC PR Irgazin Rubine K 4080 Cromophtal Rubine TR Irgazin Rubine K 4085 Irgazin Rubine L 4025 PR Irgazin Yellow K PY Irgazin Yellow K 2060 FP Cromophtal Yellow 3RLP PY Irgazin Yellow K 2060 SQ - PY Irgazin Yellow K 2070 Cromophtal Yellow 2RLTS PY Irgazin Yellow K 2080 Cromophtal Yellow 2RLP PY Lumina Aqua Blue 9A30D Lumina Brass 9232D Lumina Gold 9Y30D Lumina Green 9G30D Lumina Red 9R30D Lumina Red Blue 9B30D Lumina Royal Aqua Blue 9780H Lumina Royal Blue 9680H Lumina Royal Copper 9390H * For more information please contact pigments-safety@basf.com * For more information please contact pigments-safety@basf.com

18 Colorants for toys Colorants for toys 34 Pigments for plastics Pigments for plastics 35 Colorants for toys Status: September 2017 SST Status Statement Toys (EN 71-3:2013 Heavy Metal Status Statement) Status: September 2017 SST Status Statement Toys (EN 71-3:2013 Heavy Metal Status Statement) Product Old product name C.I. name Toys for children under 3 years and toys for mouth contact European Union Toys for children above 3 years and no mouth contact Europe USA Australia Product Old product name C.I. name Toys for children under 3 years and toys for mouth contact European Union Toys for children above 3 years and no mouth contact Europe USA Australia 3, , 2013 ASTM F AS/NZS ISO8124.3:2003 3, , 2013 ASTM F AS/NZS ISO8124.3:2003 Lumina Royal Indigo 9580H Lumina Royal Magenta EH Lumina Turquoise 9T30D Magnapearl Magnapearl 1000 DF Magnapearl Magnapearl Magnapearl Magnapearl 2000 DF Magnapearl Magnapearl Magnapearl 2110 DF Magnapearl Magnapearl 2300 DF Magnapearl Magnapearl Magnapearl 3100 DF Magnapearl Magnapearl 4000 DF Magnapearl Magnapearl Mearlin Aztec Gold 9363 C Mearlin Brilliant Gold 9212 G Mearlin Copper 9340 A Mearlin Inca Gold 9222 G Mearlin Majestic Gold 9222 X Mearlin Majestic Gold 9222 X DF Mearlin Mayan Gold 9233 X Mearlin Micro Bronze 9250M Mearlin Satin White 9130 F Mearlin Satin White 9130 F DF Mearlin Sparkle Blue 9620 J Mearlin Sparkle Brass 9222 J Mearlin Sparkle Bronze 9250 J Mearlin Sparkle Copper 9350 J Mearlin Sparkle Gold 9212 P Mearlin Sparkle Gold 9220 J Mearlin Sparkle Green 9820 J Mearlin Sparkle Orange 9320 J Mearlin Sparkle Red 9420 J Mearlin Sparkle Russet 9450 J Mearlin Sparkle Violet 9520 J Mearlin Super Blue 9630 Z Mearlin Super Blue-Russet 9650 Z Mearlin Super Brass 9232 Z Mearlin Super Bronze 9250 Z Mearlin Super Copper 9350 Z Mearlin Super Gold 9230 Z Mearlin Super Green 9830 Z Mearlin Super Orange 9330 Z Mearlin Super Red 9430 Z Mearlin Super Russet 9450 Z Mearlin Super Sparkle 9110 S Mearlin Super Violet 9530 Z Mearlin Super White 9020 C Meteor Yellow 9379 FF FK SST 1 1 * For more information please contact pigments-safety@basf.com * For more information please contact pigments-safety@basf.com

19 Colorants for toys Colorants for toys 36 Pigments for plastics Pigments for plastics 37 Colorants for toys Status: September 2017 SST Status Statement Toys (EN 71-3:2013 Heavy Metal Status Statement) Status: September 2017 SST Status Statement Toys (EN 71-3:2013 Heavy Metal Status Statement) Product Old product name C.I. name Toys for children under 3 years and toys for mouth contact European Union Toys for children above 3 years and no mouth contact Europe USA Australia Product Old product name C.I. name Toys for children under 3 years and toys for mouth contact European Union Toys for children above 3 years and no mouth contact Europe USA Australia 3, , 2013 ASTM F AS/NZS ISO8124.3:2003 3, , 2013 ASTM F AS/NZS ISO8124.3:2003 Microlen Black 0068 MCN - PBk Microlen Blue 6907 MCN - PB 15: Microlen Blue 6911 MCN - PB 15: Microlen Blue 6916 MCN - PB 15: Microlen Blue 7079 MCN - PB 15: Microlen Blue 7090 MCN - PB 15: Microlen Blue 7098 MCN - PB 15: Microlen Flame Red 3800 MCN - PR Microlen Green 8730 MCN - PG Microlen Green 8745 LW MCN - PG Microlen Magenta 4535 MCN - PR Microlen Orange 2910 MCN - PO Microlen Orange 2960 MP - PO Microlen Pink 4430 MCN - PR Microlen Red 3840 LW MCN - PR Microlen Red 3840 MCN - PR Microlen Red 3845 LW MCN - PR Microlen Red 3890 MCN - PR Microlen Red 3890 MCNQ - PR Microlen Red 4060 MCN - PR 48:3 5 1 SST 1 1 Microlen Red 4104 MCN - PV Microlen Red 4170 MCN - PR 48: Microlen Red 4330 MCN Microlen Rubine 4085 MCN - PR Microlen Rubine 4270 MCN - PR 57: Microlen Violet 5700 MCN - PV Microlen Yellow 1070 MCN - PY Microlen Yellow 1210 MCN - PY Microlen Yellow 1410 MCN - PY Microlen Yellow 1500 MCN - PY Microlen Yellow 2070 MCN - PY Microlith Blue 7080 KP Microlith Blue 4G-KP PB 15: Microlith Brown 3001 KP Microlith Brown 5R-KP PBr Microlith Red 3840 KP Microlith DPP Red B-KP PR Microlith Red 3890 KP Microlith Red BR-KP PR Microlith Scarlet 3540 KP Microlith Scarlet R-KP PR Microlith Violet 5700 KP - PV Microlith Yellow 1210 KP Microlith Yellow 3G-KP PY Microlith Yellow 2060 KP Microlith Yellow 3R-KP PY Oracet Blue 690 Oracet Blue PD2104 SB Oracet Blue 780 FE Filester Blue GN SB Oracet Magenta 460 Oracet Red 5B SR Oracet Orange 220 Oracet Orange ES SO Oracet Orange 230 Oracet Orange G SO Oracet Red 344 Oracet Red GN SR Oracet Red 454 Thermoplast Red 454 SR Oracet Violet 580 Oracet Violet TR SV Oracet Yellow 125 Oracet Yellow PD 2114 SY Oracet Yellow 130 Oracet Yellow 3GN SY Oracet Yellow 140 Oracet Yellow RB PY Oracet Yellow 144 FE Filester Yellow RNB PY Oracet Yellow 180 Oracet Yellow GHS SY Paliogen Red K 3911 Paliogen Red K 3911 HD PR Paliogen Red K PR Paliotol Orange K PO Paliotol Yellow K 0961 Paliotol Yellow K 0961 HD PY * For more information please contact pigments-safety@basf.com * For more information please contact pigments-safety@basf.com

20 Colorants for toys Legislation for food contact materials 38 Pigments for plastics Pigments for plastics 39 Colorants for toys Status: September 2017 SST Status Statement Toys (EN 71-3:2013 Heavy Metal Status Statement) Status: September 2017 SST Status Statement Toys (EN 71-3:2013 Heavy Metal Status Statement) Product Old product name C.I. name Toys for children under 3 years and toys for mouth contact European Union Toys for children above 3 years and no mouth contact Europe USA Australia 3, , 2013 ASTM F AS/NZS ISO8124.3:2003 Paliotol Yellow K 1070 Irgalite Yellow WGP PY Paliotol Yellow K PY Paliotol Yellow K PY Paliotol Yellow K 1760 FP Cromophtal Yellow HRPN PY 191: Paliotol Yellow K 1800 Paliotol Yellow K 2270 PY Paliotol Yellow K PY Paliotol Yellow K 1841 FP - PY Rightfi t Red K PR Rightfi t Red K PR Sicopal Black K PBr SST 1 1 Sicopal Blue K PB SST 1 1 Sicopal Blue K PB SST 1 1 Sicopal Blue K PB SST 1 1 Sicopal Brown K PY SST 1 1 Sicopal Brown K PBr SST 1 1 Sicopal Brown K 2795 FG - PBr SST 1 1 Sicopal Green K 9715 FK - PG SST 1 1 Sicopal Orange K PO SST 1 1 Sicopal Yellow 1120 FG - PY SST 1 1 Product Old product name C.I. name Toys for children under 3 years and toys for mouth contact Toys for children above 3 years and no mouth contact European Union Europe USA Australia 3, , 2013 ASTM F AS/NZS ISO8124.3:2003 Sicotan Yellow K 2011 FG - PBr SST 1 1 Sicotan Yellow K PBr SST 1 1 Sicotan Yellow K PBr SST 1 1 Sicotan Yellow K 2111 FG - PBr SST 1 1 Sicotan Yellow K PBr SST 1 1 Sicotan Yellow K 2112 FG - PBr SST 1 1 Sicotrans Red K PR Sicotrans Red K PR * For more information please contact pigments-safety@basf.com Legislation for food contact materials EU legislation European regulations are directly binding to all 28 member states. In addition to the direct members of the European Regulation (EC) No. 1935/2004 Framework Union, some countries within Europe are transforming these regulations into their national law, e.g., Switzerland. Regulation (EC) No. 2023/2006 Good Manufacturing Practice Applicable to all Food Contact Sicotan Brown K PY SST 1 1 Sicotan Brown K PY SST 1 1 Sicotan Brown K PY SST 1 1 Sicotan Yellow K PY SST 1 1 Sicotan Yellow K PY SST 1 1 Directive 2007/42/EC Regenerated Cellulose Film Directive 84/500EEC Ceramics Directive 2005/31/EC 1st amendment Plastic material Regulation (EU) No. 10/2011 Regulation (EC) 372/2007 Transition migration limits for plasticizers in gaskets in lids Regulation (EC) No. 282/2008 Recycled Plastics Regulation (EC) 1895/2005 BADGE/BFDGE/ NOGE Elastomers and rubbers Directive 93/11/EEC Nitrosamines Regulation (EC) No. 450/2009 Active & Intelligent Packaging Sicotan Yellow K 1011 FG - PY SST 1 1 Sicotan Yellow K PBr SST 1 1 Sicotan Yellow K 2001 FG - PBr SST 1 1 Sicotan Yellow K PBr SST 1 1 * For more information please contact pigments-safety@basf.com Glass Paper & board Wood Metals & alloys Figure 1: Overview of the EU legislation for food contact materials Cork lon-exchange Textiles Adhesives Printing Silicones Varnishes & Waxes resins inks coatings

21 Legislation for food contact materials Legislation for food contact materials 40 Pigments for plastics Pigments for plastics 41 All food contact materials and articles Regulation (EC) No. 1935/2004, the framework regulation on materials and articles intended to come into contact with food, sets general requirements for all food contact materials. The framework regulation sets following rules: General safety principles Groups of food contact materials and articles Procedure for authorization Establishment of a European Reference Laboratory for food contact materials Mandates the development of implementing measures for specific requirements General safety principles of the framework regulation The framework regulation in force since December 3, 2004 requires that food contact materials: Meet Article 3 of the regulation: Must not transfer their components into food in quantities that could endanger human health, change food composition in an unacceptable way or deteriorate its taste and odor. Are manufactured according to good manufacturing practice as detailed in The Good Manufacturing Practice Regulation (EC) No. 2023/2006 that sets down the requirements/principles of good manufacturing practices for all food contact materials and articles. An article intended for food contact must be labelled or bear the glass-and-fork symbol. This labelling is not obligatory if food contact is obvious by the article s nature, e.g., knife, fork, wine glass. Labelling, advertising and presentation of food contact materials must not mislead consumers. Accompanied by a Declaration of Compliance containing information on the appropriate use of food contact materials or articles, if necessary. (Article 16) Are traceable throughout the production chain.gene Plastic food contact materials and articles Regulation (EU) No. 10/2011 on plastic materials and articles intended to come into contact with food, and with additional amendments, sets the rules for plastic food contact materials. This regulation is commonly known as the PIM or Plastics Implementation Measure. It is one of the implementing measures mandated by the framework regulation and addresses plastics specifically. The regulation entered in force on May 11, 2011, and foresees transitional provisions up to January 1, By then all food contact materials and articles on the market will have to fulfill the requirements of the Regulation (EU) No. 10/2011. What the regulation covers Plastic materials and articles, whether printed and coated or not Plastic multi-layer materials and articles held together by adhesives or by other means, whether printed and coated or not Plastic layers or plastic coatings, forming gaskets in caps and closures, that make a set of two or more layers of different types of materials Plastic layers in multi-material multi-layer materials and articles Rules set by the regulation Union list (Annex I) of authorized monomers and additives for use in plastics manufacture Restrictions and specification for authorized substances including specific migration limits (SML) defined based on toxicological evaluation and exposure scenario. According to EFSA Note for Guidance, substances for which no specific migration limit or other restrictions are provided in Annex I, a generic specific migration limit of 60 mg/kg needs to be observed Rules on non-intentionally added substances, i.e., impurities and reaction products Overall migration limit (OML) It means the maximum permitted amount of nonvolatile substances released from a material or article into food simulants. According to Article 12 plastic materials and articles intended to be brought into contact with food shall not transfer their constituents to food simulants in quantities exceeding 60 mg/kg (OML) of food simulant Rules on compliance, especially migration testing, listing simulants, testing conditions The concept of functional barrier Authorization for nano-materials before use Declaration of compliance and supporting documentation As mentioned in the Union Guideline to Regulation (EU) No. 10/2011 published in February 2014: Even though colorants fall under the definition of additives, they are not covered by the Union list of substances. Colorants used in plastics are covered by national measures. However, they have to comply with the general safety requirements of Article 3 of the Framework Regulation (EC) No. 1935/2004 and are subject to risk assessment in accordance with Article 19* of the Plastics Regulation (EU) No. 10/2011. Compliance with Article 3 of regulation (EC) No. 1935/2004 of substances referred to in Articles 6(1), 6(2), 6(4), 6(5) and 14(2) of this regulation, which are not covered by an inclusion in Annex I to this regulation shall be assessed in accordance with internationally recognized scientific principles on risk assessment. Council of Europe resolutions The Council of Europe has established general recommendations for various types of materials that are frequently used in the production, distribution, processing and consumption of foodstuffs. The following (nonplastic) materials have been addressed: coatings, cork, glass, inks, metals and alloys, paper and board, resins for ion exchange and adsorption, rubber, silicones. For all materials, the requirement is present that they should not transfer their constituents to foodstuffs in quantities that could endanger human health, bring about an unacceptable change in the composition or deterioration of organoleptic characteristics. Specific requirements are set in the supplementary technical documents and substance inventories can be found in the Appendixes of the resolutions. The substance inventories are based on notifications by industry or national authorities. Listed substances have not necessarily been risk assessed. All resolutions are not legally binding. They have the character of a guideline, as long as they are not transferred into national law. Resolution AP (89) 1 Resolution AP (89) 1 applies to the use of colorants in plastic materials and articles coming into contact with food. The resolution defines purity requirements for pigments including concentration limits for extractable heavy metals, primary aromatic amines (PAA) and polychlorinated biphenyls (PCB). Soluble metal and metalloids Limit [ppm] Antimony (Sb) 500 Arsenic (As) 100 Barium (Ba) 100 Cadmium (Cd) 100 Chromium (Cr III) 1,000 Lead (Pb) 100 Mercury (Hg) 50 Selenium (Se) 100 Primary aromatic amines (PAA) 500 Polychlorinated biphenyls (PCB) 25 Table 2: Purity limits of AP(89) 1 * Article 19 Assessment of substances not included in the Union list