Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet Issuing Date data available Revision Date 07-Apr-2014 Revision Number 2 1. PRODUCT AND COMPANY IDENTIFICATION Product Name Recommended Use AIRBORNE Dual Action Tablets Vitamins. Supplier Address Reckitt Benckiser 399 Interpace Parkway Parsippany NJ US Phone: Fax: Contact:Michael Pleus michael.pleus@reckittbenckiser.com Contact Phone WARNING! 2. HAZARDS IDENTIFICATION Emergency Overview May cause eye irritation Appearance White Physical State Solid. Odor Characteristic Potential Health Effects Principle Routes of Exposure Acute Toxicity Eyes Skin Inhalation Ingestion Chronic Effects Aggravated Medical Conditions Environmental Hazard Eye contact. Skin contact. May cause irritation. known effect based on information supplied. known effect based on information supplied. hazard from product as supplied. Ingestion above therapeutic dose may cause nausea, vomiting, dizziness, and headache. Titanium dioxide has been classified by the International Agency for Research on Cancer (IARC) as possibly carcinogenic to humans (Group 2B) by inhalation. This product contains titanium dioxide in a non-respirable form. Inhalation of titanium dioxide is unlikely to occur from exposure to this product. ne known. See Section 12 for additional Ecological Information. 3. COMPOSITION/INFORMATION ON INGREDIENTS. Chemical Name CAS- Weight % Cellulose Magnesium oxide Silicon dioxide Titanium dioxide Page 1 / 7

2 Magnesium stearate Manganese sulfate monohydrate FIRST AID MEASURES Eye Contact Skin Contact Inhalation Ingestion tes to Physician Rinse thoroughly with plenty of water, also under the eyelids. If symptoms persist, call a physician. Wash skin with soap and water. In the case of skin irritation or allergic reactions see a physician. Move to fresh air. If symptoms persist, call a physician. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Consult a physician if necessary Treat symptomatically. 5. FIRE-FIGHTING MEASURES Flammable Properties Flash Point Suitable Extinguishing Media Hazardous Combustion Products Explosion Data Sensitivity to Mechanical Impact Sensitivity to Static Discharge t flammable. t determined. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Carbon oxides... Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health Hazard 1 Flammability 0 Stability 0 Physical and Chemical Hazards - 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Environmental Precautions Methods for Containment Methods for Cleaning Up Ensure adequate ventilation. Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. Pick up and transfer to properly labeled containers. 7. HANDLING AND STORAGE Handling Storage Handle in accordance with good industrial hygiene and safety practice. Avoid contact with eyes. Keep container tightly closed. Keep in properly labeled containers. Page 2 / 7

3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Cellulose TWA: 10 mg/m Magnesium oxide Silicon dioxide Titanium dioxide Magnesium stearate Manganese sulfate monohydrate TWA: 15 mg/m 3 total dust TWA: 5 mg/m 3 respirable fraction (vacated) TWA: 15 mg/m 3 total dust (vacated) TWA: 5 mg/m 3 respirable fraction TWA: 10 mg/m 3 inhalable fraction TWA: 15 mg/m 3 fume, total particulate (vacated) TWA: 10 mg/m 3 total particulate 10 mg/m 3 20 mppcf TWA; ((80)/(% SiO2) mg/m 3 ) TWA: 10 mg/m 3 TWA: 15 mg/m 3 total dust (vacated) TWA: 10 mg/m 3 total dust TWA: 10 mg/m 3 TWA: 0.2 mg/m 3 Mn (vacated) Ceiling: 5 mg/m 3 Ceiling: 5 mg/m 3 Mn TWA: 10 mg/m 3 total dust TWA: 5 mg/m 3 respirable dust IDLH: 750 mg/m 3 fume IDLH: 3000 mg/m 3 TWA: 6 mg/m 3 IDLH: 5000 mg/m 3 IDLH: 500 mg/m 3 Mn TWA: 1 mg/m 3 Mn STEL: 3 mg/m 3 Mn ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value. OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits. NIOSH IDLH: Immediately Dangerous to Life or Health. Other Exposure Guidelines Engineering Measures Personal Protective Equipment Eye/Face Protection Skin and Body Protection Respiratory Protection Hygiene Measures Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). See section 15 for national exposure control parameters. Showers Eyewash stations Ventilation systems special protective equipment required. special protective equipment required. protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. Handle in accordance with good industrial hygiene and safety practice. When using, do not eat, drink or smoke. Provide regular cleaning of equipment, work area and clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance White. Odor Characteristic. Odor Threshold information available Physical State Solid ph information available Flash Point information available. Autoignition Temperature information available Decomposition Temperature information available Boiling Point/Range information available Melting Point/Range information available Flammability Limits in Air information available Explosion Limits information available Water Solubility partially soluble Solubility information available. Evaporation Rate information available Vapor Pressure data available Vapor Density data available Page 3 / 7

4 10. STABILITY AND REACTIVITY Stability Incompatible Products Conditions to Avoid Hazardous Decomposition Products Hazardous Polymerization Stable under recommended storage conditions. ne known. ne known. Carbon oxides. Hazardous polymerization does not occur. 11. TOXICOLOGICAL INFORMATION Acute Toxicity Product Information Chronic Toxicity Chronic Toxicity Carcinogenicity Titanium dioxide has been classified by the International Agency for Research on Cancer (IARC) as possibly carcinogenic to humans (Group 2B) by inhalation. This product contains titanium dioxide in a non-respirable form. Inhalation of titanium dioxide is unlikely to occur from exposure to this product. The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA Cellulose Silicon dioxide Group 3 Titanium dioxide Group 2B X IARC: (International Agency for Research on Cancer) Group 2B - Possibly Carcinogenic to Humans Group 3 - t Classifiable as to Carcinogenicity in Humans OSHA: (Occupational Safety & Health Administration) X - Present Target Organ Effects Eyes. Lungs. Respiratory system. Skin. 12. ECOLOGICAL INFORMATION Ecotoxicity The environmental impact of this product has not been fully investigated. Chemical Name Silicon dioxide Toxicity to Algae EC50: 440 mg/l (72 h ) Pseudokirchneriella subcapitata Toxicity to Fish LC50: 5000 mg/l (96 h static) Brachydanio rerio Toxicity to Microorganisms Daphnia Magna (Water Flea) EC50: 7600 mg/l (48 h ) Ceriodaphnia dubia 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements. Page 4 / 7

5 Contaminated Packaging Dispose of in accordance with local regulations. California Hazardous Waste Codes TRANSPORT INFORMATION DOT TDG MEX ICAO IATA IMDG/IMO NOT REGULATED Page 5 / 7

6 15. REGULATORY INFORMATION International Inventories TSCA DSL Complies t determined U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Chemical Name CAS- Weight % SARA Threshold Values % Manganese sulfate monohydrate SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ). Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product contains the following substances which are listed hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act: Chemical Name CAS- Weight % HAPS data VOC Chemicals Class 1 Ozone Depletors Class 2 Ozone Depletors Manganese sulfate monohydrate CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material. U.S. State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals: Chemical Name CAS- California Prop. 65 Titanium dioxide Carcinogen U.S. State Right-to-Know Regulations Chemical Name Massachusetts New Jersey Pennsylvania Illinois Rhode Island Saccharomyces cerevisiae, X X chromium-rich Cellulose X X X X - Magnesium oxide X X X Silicon dioxide X X Titanium dioxide X X X International Regulations Page 6 / 7

7 Mexico - Grade Moderate risk, Grade 2 Canada Chemical Name Carcinogen Status Exposure Limits Cellulose Mexico: TWA 10 mg/m 3 Mexico: STEL 20 mg/m 3 Magnesium oxide Mexico: TWA 10 mg/m 3 Titanium dioxide Mexico: TWA= 10 mg/m 3 Mexico: STEL= 20 mg/m 3 Manganese sulfate monohydrate Mexico: TWA 0.2 mg/m 3 This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class n-controlled 16. OTHER INFORMATION Revision Date Revision te 07-Apr-2014 information available. General Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of Safety Data Sheet Page 7 / 7