World Virtual Conference on Advanced Research in Mechanical and Materials Engineering.

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1 World Virtual Conference on Advanced Research in Mechanical and Materials Engineering.

2 PRESENTER : FATIMAH ABD. RAJAK HAMIM SUPERVISOR: ASSOC PROF DR SUPRI A. GHANI DR. FIRUZ ZAINUDDIN

3 Composites are combinations of at least two materials which is matrix and filler as reinforcement. Natural filler offers many advantages such as low in weight, enhanced biodegradability, and high filling level in composites. Compatibilizer has the ability to react with organic fillers and matrices, forming bridges across the interface.

4 EVA is the copolymer of ethylene and vinyl acetate segments which formed via radical polymerization with different acetate contents. RHDPE is recycled plastic from HDPE which can be used for same application of HDPE with slightly different properties. Taro is an ancient crop that originated in Asia, but is now grown in many parts of the world where it is also known as eddo, dasheen or cocoyam. Taro can be used as potential filler in plastic field.

5 Materials RecycledHigh Density Polyethylene (RHDPE) Description MFI = 0.7 g/10min Density = kg/m 3 Ethylene Vinyl Acetate (EVA) Caprolactam Maleic Anhydride Vinyl content = 18.1 wt% MFI = 2.5 g/10min Density = 0.93 g/cm 3 Density = 1.01 g/cm 3 Melting Point = 69.2 C Density = 1.48 g/cm 3 Melting Point = 52.8 C

6 Content of Taro Filler: Content Quantity Calories (Kcal) 274 Carbohydrate (%) 52.6 Fat (%) 1.2 Protein (%) 13.1

7 Composite Code RHDPE [phr] EVA [phr] TF [phr] CL-MAH [phr] DBP [phr] RHDPE/EVA/TF RHDPE/EVA/TF RHDPE/EVA/TF RHDPE/EVA/TF RHDPE/EVA/TF RHDPE/EVA/TF5 -CL-MAH RHDPE/EVA/TF10 -CL-MAH RHDPE/EVA/TF15 -CL-MAH RHDPE/EVA/TF20 -CL-MAH RHDPE/EVA/TF25 -CL-MAH

8 Washing, drying and, crushing of Taro RHDPE/EVA Taro Powder Filler (TPF) Mixing with Brabender Compounding of RHDPE/EVA/TPF composites Compression of RHDPE/EVA/TPF composites Specimen of RHDPE/EVA/TPF composites Testing and Analysis

9 Tensile Strength (Mpa) RHDPE80/EVA20 RHDPE80/EVA20/CL-MAH Filler Loadings (phr)

10 Elongation at Break (%) RHDPE80/EVA20 RHDPE80/EVA20/CL-MAH Filler Loadings (phr)

11 Percentage Mass Swell (%) Taro filler Taro Filler CLMAH Filler Loadings (phr)

12 Increase in filler loading of Taro fillers to RHDPE/EVA/ Taro composites improved tensile strength but reduced elongation at break and mass swell resistance of the composites. Addition of CL-MAH as compatibilizer improved the compatibility and stress transfers of the composites lead to increased in tensile strength and decreased of elongation at break.

13 [1] F. P. La Mantia, M. Morreale, Green composites: A brief review, Composites:Part A, 42 (2011) [2] F. Klaus, F. Stoyko, Z. Zhong, Polymer Composite, from Nano- to Macro-Scale. Springer, Berlin, [3] R. N. Rothon, Particle-filled Polymer Composites, second ed., Rapra technology, Shrewsbury, UK, [4] A. R. H. Fatimah, A. A. H. Ikmal, A. G. Supri, Effect of PEgMAH on tensile properties and swelling behavior of recycled high density polyethylene/ethylene vinyl acetate/waste tyre dust (r- HDPE/EVA/WTD) composites, Advance Mechanics and Materials 554 (2014) [5] D. N. Saheb, J. P. Jog, Natural fiber polymer composites: A review, Advances in Polymer Technology Vol. 18 No. 4 (1999) [6] N. Stevulova, E. Terpakova, J. Cigasova, J. Junak, L. Kidalova, Chemically treated hemp shives as a suitable organic filler for lightweight composites preparing, Procedia Enginnering 42 (2012) [7] R. M. Rowell, Challenges in biomass-thermoplastic composites, J Polym Environ 15 (2007) [8] N. Bakar, C. Y. Chee, L. C. Abdullah, C. T. Ratnam, N. Azowa, Effect of methyl methacrylate grafted kenaf on mechanical properties of polyvinyl chloride/ethylene vinyl acetate composites, Composites: Part A 63 (2014) [9] K. Ahmed, N. Z. Raza, F. Habib, M. Aijaz, M. H. Afridi, An investigation on the influence of filler loading and compatibilizer on the properties of polypropylene/marble sludge composites, Journal of Industrial and Engineering Chemistry 19 (2013) [10] N. Ayrilmis, A. Kaymakci, F. Ozdemir, Physical, mechanical, and thermal properties of polypropylene composites filled with walnut shell flour, Journal of Industrial and Engineering Chemistry 19 (2013)

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