Iron Oxide Orange 960, light

Transcription

1 Revised edition: Version: 5 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Iron Oxide Orange 960, light Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Coloring agent (pigment and dyes), inorganic Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: info@kremer-pigmente.de Importer: -- Emergency No. Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 Classification according to EC Regulation No. 67/548 or No. 1999/45 This product does not require classification and labelling as hazardous according to CLP/GHS. The material is not subject to classification according to EC lists. Safety Phrases: Possible Environmental Effects: Label Elements Classification according to EC Regulation 1272/2008 Hazard designation: Signal word: Hazard designation: Safety designation: Hazardous components for labelling: Other Hazards Dust may be produced when working with this material, which can cause a mechanical irritation of eyes, nose and respiratory tract. Composition/Information on Ingredients 2

2 Substance Mixture Page 2 Chemical Characterization: Mixture of Pigment Yellow (FeO(OH); CAS No ) and Pigment Red (Fe2O3; CAS No ) Hazardous Ingredients: Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Take affected persons out into the fresh air. Supply fresh air and keep patient calm. If breathing is difficult call a physician. Wash off immediately with plenty of soap and water and rinse thoroughly. Remove contact lens. Rinse open eyes with plenty of water (10-15 min). Should irritation continue, seek medical advice After ingestion: Most important Symptoms and Effects, both Acute and Delayed No special measures required. Symptoms: No further information available Effects: Indication of any Immediate Medical Attention and special Treatment needed Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: Treat symptomatically. Foam, carbon dioxide (CO2), extinguishing powder, water spray Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture None known Special hazards: Advice for Firefighters No special hazards. Protective equipment: 3

3 Page 3 Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Personal precautions: Environmental Precautions Ensure adequate ventilation. Wear protective clothing. Keep unprotected persons out of danger zone. Floor may be slippery; use care to avoid falling Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soils, drains and surface water. Contact local authorities if product pollutes soil or vegetation Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Take up mechanically and collect in suitable containers for disposal. Avoid dust formation. See Section 13 for information on disposal. Protective clothing, see Section 8. No special measures required Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Wash thoroughly after handling. Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Storage class (VCI): Store in tightly sealed containers in a dry and cool room. Keep container tightly closed. No special measures necessary. 13; Non combustible solids Further Information: Specific End Use(s) Further information: 4

4 Page Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): TRGS 900 (D 1/06): FeO(OH) TLV: 10 mg/m3 inhalable fraction (general dust limit) TLV: 3 mg/m3 air-borne fraction (general dust limit) Parameters to be controlled (EC): Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): Additional Information: Exposure Controls Technical protective measures: Provide adequate ventilation. Facilities storing or utilizing this material should be equipped with an eyewash and shower facility. Personal Protection General protective measures: Respiratory protection: Hand protection: Do not inhale dust. Do not eat, drink or smoke while working. Wash hands before breaks and at the end of work. Avoid contact with eyes and skin. Dust mask. Protective gloves (EN 374) Protective glove material: Eye protection: Body protection: Safety glasses (EN 166) Protective clothing Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Form: Color: Odor: Odor threshold: powder orange odorless ph-value: 4-8 (5 %) Melting temperature: > 1000 C (> 1832 F) 5

5 Boiling temperature: Page 5 Flash point: Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: This product is a non-volatile solid. no information available no information available This product is a non-volatile solid. 4.5 g/cm3 (20 C) insoluble not determined Decomposition temperature: ca. 180 C Viscosity, dynamic: Explosive properties: Oxidizing properties: Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Product does not present an explosion hazard. none kg/m3 Other information: 6

6 Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid No further information. The product is chemically stable. Page 6 None if handled and stored according to specifications Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Mutagenicity: > 180 C. Conversion to Fe2O3. None if stored and handled according to specifications. > 5000 mg/kg (rat) Non irritating Non-irritating to eyes Chronic effects : Repeated or prolonged inhalation of dust can cause a chronic irritation of the respiratory tract. No irritant effect known. Reproductive toxicity: 7

7 Page Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: AOX Value: Disposal Considerations Waste Treatment Methods Product: European Waste Code (EWC): By analogy with a product of similar composition. LC50: > 1000 mg/l (96h, Leuciscus idus) Methods for the evaluation of the biological degradability are not applicable for inorganic substances. Not hazardous. When used properly, no ecological problems expected. If product cannot be reused or recycled, it has to be disposed of according to current local regulations. Uncleaned packaging: 8

8 Dispose of according to official local regulations. Page Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: No hazardous goods according to ADR (land transportation) IMDG/IATA: Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel no.: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: IATA: Environmental Hazards None Special Precautions for User Not classified as a dangerous good under transport regulations. Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Do not store together with foodstuffs. Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 0, not hazardous 9

9 Local regulations on chemical accidents: Page 9 Employment restrictions: Restriction and prohibition of application: EC. REACH, Section XVII, Restrictions on the Manufacture, Placing on the Market and Use of Certain Dangerous Substances, Preparations and Articles: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information A Chemical Safety Assessment is not necessary for this product. Seveso Directive: not regulated / This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.