Guhring Twist Drills & Taps-Regrinding

Transcription

1 Guhring Coating Services P.O. Box 643 Brookfield, WI Phone: Fax: GUHRING SAFETY DATA SHEET 1. Guhring specialty coatings represent less than 1% of the total tool by weight. The Ingredients list below includes typical weight ranges for cutting tools to which the coatings are applied. The coating identified below is applied to the tool by Guhring. 1. IDENTIFICATION PRODUCT ME: Chemical Description: Guhring Twist Drills & Taps-Regrinding H.S.S.-H.S.Co. Cutting Tool EMERGENCY TELEPHONE NUMBER: HAZARD IDENTIFICATION Emergency Overview: Hazard Classification- Respiratory Tract irritant GHS Label Elements: none Pictogram: Signal Word = warning Hazard Statement -Avoid prolonged breathing of cutting fumes Precautionary Statement-Use general or mechanical ventilation during cutting HMIS Health Hazard 1 Chronic Health Hazard *(pg-2) Flammability 0 Physical Hazard 0 NFPA Rating Potential Health Effects: Inhalation-May cause respiratory tract irritation during drilling Skin-none Eyes-none Ingestion-none = Not Applicable Drills & Taps Page 1 of 4

2 3. COMPOSITION/INFORMATION ON INGREDIENTS Coated mixture on steel tooling INGREDIENT ME CAS # % TLV/TWA Molybdenum (in coating) mg/m3 (as metal) Vanadium (in coating) <1.0 ( c ) 0.5 mg/m3 Cobalt (in coating) mg/m3 Base steel tooling None None *Source: OSHA 29 CFR Table Z-1, 2 or FIRST AID INFORMATION EMERGENCY FIRST AID PROCEDURES: Inhalation: Remove individual from immediate work area to a supply of fresh air. At a minimum, use standard ventilation practices around operating machine tools. Eye: Wear approved eye protection whenever using machining tools. Use good practices when securing tooling in a machine. 5. FIRE FIGHTING MEASURES FLASH POINT: LOWER (LEL): FLAMMABLE LIMITS IN AIR (%): UPPER (UEL): EXTINGUISHING MEDIA: AUTO-IGNITION: Tools and coating are not flammable. Fight fire normally based upon other materials involved. SPECIAL FIRE FIGHTING PROCEDURES: As with any fire, wear self-contained breathing apparatus to avoid inhalation of hazardous decomposition products from other materials that may be involved. SPECIAL FIRE EXPLOSION HAZARDS: None. 6. ACCIDENTAL RELEASE MEASURES PROCEDURES TO CONTAIN AND CLEAN UP LEAKS OR SPILLS: Coating is applied to metal tooling. Pick up and properly store tooling to avoid trip hazard. REPORTING PROCEDURE: Report all spills in accordance with Federal, State and Local reporting requirements. Guhring is not aware of any environmental reporting requirements for spilled tooling. = Not Applicable Drills & Taps Page 2 of 4

3 7. HANDLING AND STORAGE HANDLING AND STORAGE: tooling. Store tooling in a dry place. Observe proper lifting techniques for bulk 8. EXPOSURE CONTROL/PERSOL PROTECTION RESPIRATORY PROTECTION: General respiratory protection for dust/fumes VENTILATION: Local Exhaust: General ventilation Mechanical (General): May control or enclose work area if appropriate Special: Other: PROTECTIVE GLOVES: EYE PROTECTION: OTHER PROTECTIVE CLOTHING: As needed for heat or metal slivers on tooling Use safety eye wear around operating machines 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling 760 mm Hg ( C): Vapor Pressure (mm 25 C): Vapor Density (Air = 1): Density (grams/cc): Percent Volatile by Volume (%): Evaporation Rate (Butyl Acetate = 1): Physical State: Solubility in Water (% by Weight): ph: Appearance and Odor: Black/grey colored on heat treated metal tool 10. STABILITY AND REACTIVITY Stable or Unstable: Incompatibility (materials to avoid): Hazardous Decomposition Products: Decomposition Temperature: Hazardous Polymerization: Conditions to Avoid: Stable Exposure to strong mineral acids Will not occur = Not Applicable Drills & Taps Page 3 of 4

4 11. TOXICOLOGICAL INFORMATION THRESHOLD LIMIT VALUE (TLV) AND SOURCE: Twist Drills & Taps are cobalt - molybdenum - vanadium coated, machined, and heat treated metal tools. An extremely small amount of particulate containing cobalt, molybdenum or vanadium from the contact surface may be released during intermittent tool use. The low amount of coating released and the small wear surface make short term exposure at the TLV highly unlikely. 12. ECOLOGICAL INFORMATION Used tooling may be re-coated several times before it reaches end of life. Guhring recommends returning the tooling for recoating as many times as practical and then recycling the metal tool appropriately at end-of-useful-life. No potential ecological hazards are known. 13. DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: Used tooling may be re-coated several times before it reaches end of life. Guhring recommends returning the tooling for recoating as many times as practical and then recycling the metal tool appropriately at end-of-useful-life. 14. TRANSPORTATION INFORMATION TRANSPORTATION-SHIPPING: The coating on twist drills and taps does not classify the tooling for any hazard class per USDOT regulations. To our knowledge the tooling to which this coating is applied is not a hazardous material. Always ship tools in accordance with 49 CFR, IATA, ICAO, UN regulation, or other local regulation that may be required for the base tool material. 15. REGULATORY INFORMATION SARA 313 Notification is not required because the cobalt, vanadium and molybdenum content of the coating are below the threshold reporting value. Reporting requirements may vary based upon other facility requirements. 16. SDS INFORMATION Environmental Health & Safety Information: EDITION DATE: APPROVED BY: Don Rancic NOTICE: The information and recommendations set forth are made in good faith and are believed to be accurate at the date of preparation. Guhring Corporation makes no warranty expressed or implied. = Not Applicable Drills & Taps Page 4 of 4

5 MATERIAL SAFETY DATA SHEET ************************* I. PRODUCT IDENTIFICATION ************************* MANUFACTURER'S ME: Balzers Tool Coating Inc. TELEPHONE NO: (716) ADDRESS: 495 Commerce Drive DATE PREPARED: November, 1985 Amherst, New York REVISION DATE: March 2000 TRADE ME (Label Identity): TITANIUM NITRIDE COATING ************************* II. HAZARDOUS INGREDIENTS ************************* The terms 'hazardous' and 'hazardous materials as used within this MSDS should be interpreted as defined by, and in accordance with, the OSHA Hazard Communications Standard (29 CFR Part 1910, 1200) including cited Appendices, Lists, References, etc., all of which are hereby incorporated by reference. OSHA ACGIH MATERIAL OR COMPONENT CAS NO. Wt % PEL (Mg/M 3 ) TLV ( Mg/M 3 ) Titanium Nitride (TiN) N/A N/A ************************* III. PHYSICAL DATA FOR TITANIUM NITRIDE ************************* BOILING POINT: N/A MELTING POINT: 5306 F SPECIFIC GRAVITY (H 2 O=1) Approx. 5,2 (60 F) VAPOR PRESSURE: N/A VAPOR DENSITY (AIR=1): N/A SOLUBILITY IN H 2 0: Insoluble % VOLATILES BY VOLUME: N/A EVAPORATION (BUTYL ACETATE=1): N/A APPEARANCE & ODOR: Golden colored coating about.0001" thick, odorless. This extremely thin film of Titanium Nitride coating is applied to cutting tools, forming tools, molds, and wear parts to extend part life. ************************* IV. FIRE AND EXPLOSION DATA ************************* FLASH POINT: None FIRE POINT: None ************************* V. HEALTH HAZARD INFORMATION ************************* WE DO NOT CONSIDER THE COATING IN THE FORM IT IS SOLD TO CONSTITUTE A PHYSICAL HAZARD OR A HEALTH HAZARD. SUBSEQUENT OPERATIONS SUCH AS ABRADING, MELTING, WELDING, CUTTING OR PROCESSING IN ANY OTHER FASHION, A TITANIUM NITRIDE COATED OBJECT, MAY PRODUCE POTENTIALLY HAZARDOUS DUST OR FUMES WHICH CAN BE INHALED, SWALLOWED, OR COME IN CONTACT WITH THE SKIN OR EYES. THE DUST OR FUME CREATED BY THIS SUBSEQUENT PROCESSING WILL CONSIST OF EXTREMELY MINUTE PARTICLES OF TITANIUM NITRIDE TOGETHER WITH ARTICLES OF MATERIAL FROM THE COATED OBJECT (SUBSTRATE MATERIAL). USERS OF COATED TOOLS SHOULD CHECK MSDS SHEETS FOR SUBSTRATE MATERIAL FOR POSSIBLE HEALTH HAZARD EFFECTS FROM MATERIAL OF COATED OBJECT. PRIMARY ROUTES OF ENTRY: Inhalation EMERGENCY FIRST AID: Remove to fresh air, if condition continues, consult physician. Eye Contact Flush well with running water to remove particulate. Get medical attention. Skin Contact Brush off excess dust. Wash area well with soap & water. Ingestion Seek medical help if large quantities of material have been ingested. EFFECTS OF EXPOSURE: No toxic effects would be expected from exposure to the solid form of Titanium Nitride coated tools. Prolonged, repeated exposure to fumes or dusts generated during heating, cutting, brazing or welding may or may not cause adverse health effects associated with the listed constituents in excess of OSHA permissible exposure limits established in 29 CFR Subpart Z. (See Section II).

6 ************************* V. HEALTH HAZARD INFORMATION (CONT'D) ************************* EXPOSURE LIMITS: IMPORTANT: Section II lists specific ingredients and permissible exposure limits. Determine actual exposure by industrial hygiene monitoring. POSSIBLE SIGNS AND SYMPTOMS OF EXPOSURE TO DUST, WELDING, FUME AND GASES: SHORT TERM EXPOSURE: Metallic taste; nausea, tightness of chest; fever; irritation of eyes, nose, throat and skin; loss of consciousness/death due to welding gases or lack of oxygen. LONG TERM EXPOSURE: There are no adverse effects from Titanium Nitride coated products in their solid form. Adverse effects may or may not result from long-term (chronic) exposure to dust, fume, gases, etc. that occur by way of subsequent operations on the Titanium Nitride coated product. We believe there are no reliable scientific studies which show that workers exposed to operations upon Titanium Nitride coated products suffer increased incidence of lung cancer or other disease because of exposure to Titanium Nitride. Some studies would associate elements from various substrate materials (material the coated object is made of) with the potential for neurologic, pulmonary, respiratory, skin or other disease. Chromium, cobalt and nickel in various chemical compounds have been identified as suspect human carcinogens by the I.A.R.C., N.T.P. Annual Report. Users of Titanium Nitride coated products should check MSDS sheets of substrate material for possible health hazard effects from material of coated object. AGGRAVATION OF PREEXISTING RESPIRATORY OR ALLERGIC CONDITIONS MAY OCCUR IN SOME WORKERS. ************************* VI. REACTIVITY DATA ************************* STABILITY: INCOMPATIBILITY: HAZARDOUS DECOMPOSITION PRODUCTS: Chemically Stable Strong Acids, Strong Oxidizing Agents Metallic Oxides ************************* VII. SPILL OR LEAK PROCEDURES ************************* STEPS TO BE TAKEN IN CASE OF RELEASE OR SPILL: N/A WASTE DISPOSAL METHOD: Solids - Sale as Scrap for Reuse Dust, etc. - Follow Federal, State and Local Regulations Regarding Disposal ************************* VIII. SPECIAL PROTECTION INFORMATION ************************* VENTILATION REQUIREMENTS: General - Recommended (keeping airborne concentration of dust and fumes below ACGIH TLV'S) Local - As Required PERSOL PROTECTIVE EQUIPMENT: Respiratory Protection: If fumes, misting or dust condition occurs and TLV as indicated in Section II is exceeded, provide NIOSH approved respirators. Eye Protection: Recommend approved safety glasses or goggles when working with dusty material. Gloves: As Required Other Clothing or Equipment: As Required ************************* IX. SPECIAL PRECAUTIONS ************************* USE GOOD HOUSEKEEPING PRACTICES TO PREVENT ACCUMULATIONS OF DUSTS AND TO KEEP AIRBORNE DUST CONCENTRATIONS AT A MINIMUM. THIS MATERIAL IS POTENTIALLY CONTAMITED WITH COATINGS SUCH AS OILS FOR PRESERVATIVES AND OTHER CONTAMINTS. IF THE MATERIAL IS CONTAMITED, SPECIAL PRECAUTIONS (SUCH AS PROCESS CONTROL, AND PERSOL PROTECTIVE EQUIPMENT APPROPRIATE TO THE TURE OF THE SUSPECTED CONTAMINTS SHOULD BE TAKEN TO AVOID RESULTING EXPOSURES WHEN HANDLING, CUTTING (THERMAL OR MECHANICAL) AND/OR HEATING OR MELTING. While the information set forth on this material safety data sheet is believed to be accurate, as of the effective date, Balzers Tool Coating Inc. makes no representations regarding the accuracy or completeness of the information and assumes no liability for any loss, damage, or injury of any kind which may result from or arise out of the use or reliance on the information by any person. N/A = NOT APPLICABLE

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