Potential Health Effects: Inhalation-Can cause respiratory irritation by prolonged drilling without ventilation Skin-none Eyes-none Ingestion-none

Transcription

1 Guhring Coating Services P.O. Box 643 Brookfield, WI Phone: Fax: GUHRING SAFETY DATA SHEET 1. Guhring specialty coatings represent less than 1% of the total tool by weight. The Ingredients list below includes typical weight ranges for cutting tools to which the coatings are applied. The coating identified below is applied to the tool by Guhring. 1. IDENTIFICATION PRODUCT ME: Chemical Description: Carbide Cutting Tool Cemented Carbide Product with Cobalt Binder EMERGENCY TELEPHONE NUMBER: HAZARD IDENTIFICATION Emergency Overview: Hazard Classification- Respiratory Tract irritant GHS Label Elements: none Pictogram: Signal Word = warning Hazard Statement -Avoid prolonged breathing of fumes during cutting Precautionary Statement-Use general or mechanical ventilation during cutting HMIS Health Hazard 1 Chronic Health Hazard *(pg-2) Flammability 0 Physical Hazard 0 NFPA Rating Potential Health Effects: Inhalation-Can cause respiratory irritation by prolonged drilling without ventilation Skin-none Eyes-none Ingestion-none = Not Applicable Cemented Carbide w/cobalt Binder Page 1 of 5

2 3. COMPOSITION/INFORMATION ON INGREDIENTS Coated mixture on steel tooling (Coating is approximately 1-2% of base tooling weight) INGREDIENT ME CAS # % TLV/TWA Tungsten Carbide mg/m3 (as Tungsten) Cobalt mg/m3 Tantalum Carbide mg/m3 (as Tantalum) Chromium Carbide mg/m3 (as Cr+3) Chromium mg/m3 (as Cr+3) Base steel tooling None None *Source: OSHA 29 CFR Table Z-1, 2 or FIRST AID INFORMATION EMERGENCY FIRST AID PROCEDURES: Inhalation: Remove individual from immediate work area to a supply of fresh air. At a minimum, use standard ventilation practices around operating machine tools. Consult physician if condition persists.. Eye: Wear approved eye protection whenever using machining tools. Use good practices when securing tooling in a machine. 5. FIRE FIGHTING MEASURES FLASH POINT: LOWER (LEL): FLAMMABLE LIMITS IN AIR (%): UPPER (UEL): EXTINGUISHING MEDIA: AUTO-IGNITION: Tools and coating are not flammable. Fight fire normally based upon other materials involved. SPECIAL FIRE FIGHTING PROCEDURES: As with any fire, wear self-contained breathing apparatus to avoid inhalation of hazardous decomposition products from other materials that may be involved. SPECIAL FIRE EXPLOSION HAZARDS: None. 6. ACCIDENTAL RELEASE MEASURES PROCEDURES TO CONTAIN AND CLEAN UP LEAKS OR SPILLS: Coating is applied to metal tooling and will not be released if tooling is spilled. Pick up and properly store tooling to avoid trip hazard. REPORTING PROCEDURE: Report all spills in accordance with Federal, State and Local reporting requirements. Guhring is not aware of any environmental reporting requirements for spilled tooling. = Not Applicable Cemented Carbide w/cobalt Binder Page 2 of 5

3 7. HANDLING AND STORAGE HANDLING AND STORAGE: tooling. Store tooling in a dry place. Observe proper lifting techniques for bulk 8. EXPOSURE CONTROL/PERSOL PROTECTION RESPIRATORY PROTECTION: General respiratory protection for dust/fumes VENTILATION: Local Exhaust: General ventilation Mechanical (General): May control or enclose work area if appropriate Special: Other: PROTECTIVE GLOVES: EYE PROTECTION: OTHER PROTECTIVE CLOTHING: As needed for heat or metal slivers on tooling Use safety eye wear around operating machines 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling 760 mm Hg ( C): Vapor Pressure (mm 25 C): Vapor Density (Air = 1): Density (grams/cc): Percent Volatile by Volume (%): Evaporation Rate (Butyl Acetate = 1): Physical State: Solubility in Water (% by Weight): ph: Appearance and Odor: Dark grey colored coating on all Guhring tools = Not Applicable Cemented Carbide w/cobalt Binder Page 3 of 5

4 10. STABILITY AND REACTIVITY Stable or Unstable: Incompatibility (materials to avoid): Hazardous Decomposition Products: Decomposition Temperature: Hazardous Polymerization: Conditions to Avoid: Stable Exposure to strong mineral acids Will not occur 11. TOXICOLOGICAL INFORMATION THRESHOLD LIMIT VALUE (TLV) AND SOURCE: Guhring cutting tools are a cobalt - molybdenum - vanadium coated, machined, heat treated metal tool. An extremely small amount of particulate containing cobalt, molybdenum or vanadium from the contact surface may be released during intermittent tool use. The low amount of coating released and the small wear surface make short term exposure at the TLV highly unlikely. Avoid prolonged exposure if ventilation is not present. 12. ECOLOGICAL INFORMATION Used tooling may be re-coated several times before it reaches end of life. Guhring recommends returning the tooling for recoating as many times as practical and then recycling the metal tool appropriately at end-of-useful-life. No potential ecological hazards are known. 13. DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: Used tooling may be re-coated several times before it reaches end of life. Guhring recommends returning the tooling for recoating as many times as practical and then recycling the metal tool appropriately at end-of-useful-life. 14. TRANSPORTATION INFORMATION TRANSPORTATION-SHIPPING: The coating on twist drills and taps does not classify the tooling for any hazard class per USDOT regulations. To our knowledge the tooling with coating applied is not a hazardous material. Always ship tools in accordance with 49 CFR, IATA, ICAO, UN regulations or other local regulations that may be required for the base tool material. = Not Applicable Cemented Carbide w/cobalt Binder Page 4 of 5

5 15. REGULATORY INFORMATION Cobalt metal powder is identified on the California Prop 65 list of potential carcinogens. SARA 313 Notification is not required because the cobalt, vanadium and molybdenum content of the coating are below the threshold reporting value. Reporting requirements may vary based upon your other facility requirements. 16. SDS INFORMATION Environmental Health & Safety Information: EDITION DATE: APPROVED BY: Don Rancic NOTICE: The information and recommendations set forth are made in good faith and are believed to be accurate at the date of preparation. Guhring Corporation makes no warranty expressed or implied. = Not Applicable Cemented Carbide w/cobalt Binder Page 5 of 5

6 DR Page 1/4 Material Safety Data Sheet acc. to ISO/DIS Printing date 11/30/2004 Reviewed on 03/25/ Identification of substance - Product details - Trade name: Titanium-Aluminium - Application of the substance / the preparation Coating material Initial product for chemical reactions - Manufacturer/Supplier: GfE Metalle und Materialien GmbH Höfener Str Nürnberg Tel.: +49/(0)911/ Fax.: +49/(0)911/ Information department: Environment Protection Department Tel.: +49 /(0)911/ FAX.: +49 /(0)911/ Mobile: +49 / (0)175/ heinz.roller@gfe.com - Emergency information: Tel.: +49 /(0)911/ Tel.: +49 /(0)171/ Composition/Data on components - Chemical characterization - Description: Mixture of the substances listed below with nonhazardous additions. - Dangerous components: Aluminium F; R % 3 Hazards identification - Hazard description: Not applicable. - Information pertaining to particular dangers for man and environment: Not applicable. - Classification system: The classification was made according to the latest editions of international substances lists, and expanded upon from company and literature data. - NFPA ratings (scale 0-4) Health = 0 Fire = 0 Reactivity = 0 4 First aid measures - After inhalation: Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist. - After skin contact: Immediately wash with water and soap and rinse thoroughly. Generally the product does not irritate the skin. - After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. - After swallowing: If symptoms persist consult doctor. 5 Fire fighting measures - Suitable extinguishing agents: Use fire fighting measures that suit the environment. (Contd. on page 2) USA

7 DR Page 2/4 Material Safety Data Sheet acc. to ISO/DIS Printing date 11/30/2004 Reviewed on 03/25/2003 Trade name: Titanium-Aluminium (Contd. of page 1) - Protective equipment: No special measures required. - Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. 6 Accidental release measures - Person-related safety precautions: Use respiratory protective device against the effects of fumes/dust/aerosol. - Measures for environmental protection: Do not allow to enter sewers/ surface or ground water. - Measures for cleaning/collecting: Pick up mechanically. Send for recovery or disposal in suitable receptacles. - Additional information: No dangerous substances are released. 7 Handling and storage - Handling: - Information for safe handling: No special measures required. Keep receptacles tightly sealed. Ensure good ventilation/exhaustion at the workplace. Prevent formation of dust. - Information about protection against explosions and fires: Dust can combine with air to form an explosive mixture. - Storage: - Requirements to be met by storerooms and receptacles: No special requirements. - Information about storage in one common storage facility: Do not store together with acids. - Further information about storage conditions: Keep receptacle tightly sealed. 8 Exposure controls and personal protection - Additional information about design of technical systems: No further data; see item 7. - Components with limit values that require monitoring at the workplace: Aluminium ACGIH TLV 10 mg/m³ Metal dust NIOSH REL 10*; 5** mg/m³ Metal dust; *Total dust **Respirable fraction OSHA PEL 15*; 5** mg/m³ *Total dust **Respirable fraction - Additional Occupational Exposure Limit Values for possible hazards during processing: titanium dioxide ACGIH TLV 10 mg/m³ NIOSH REL Lowest feasible conc.; (LOQ 0.2 mg/m3) OSHA PEL 15* mg/m³ *Total dust - Personal protective equipment: - General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Store protective clothing separately. Avoid contact with the eyes. - Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. - Protection of hands: - Material of gloves Void - Penetration time of glove material Void (Contd. on page 3) USA

8 DR Page 3/4 Material Safety Data Sheet acc. to ISO/DIS Printing date 11/30/2004 Reviewed on 03/25/2003 Trade name: Titanium-Aluminium - Eye protection: (Contd. of page 2) Tightly sealed goggles 9 Physical and chemical properties - General Information Form: particulate Color: Silver grey Odor: Odorless - Change in condition Melting point/melting range: C ( F) Boiling point/boiling range: Undetermined. - Flash point: Not applicable. - Auto igniting: Product is not selfigniting. - Danger of explosion: Product does not present an explosion hazard. - Density at 20 C (68 F): g/cm3 - Solubility in / Miscibility with Water: Insoluble. - Solvent content: Organic solvents: 0.0 % - Solids content: % 10 Stability and reactivity - Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. - Dangerous reactions As the product is supplied it is not capable of dust explosion; however enrichment with fine dust causes risk of dust explosion. Contact with acids releases flammable gases. - Dangerous products of decomposition: No dangerous decomposition products known. 11 Toxicological information - Acute toxicity: - Primary irritant effect: - on the skin: No irritant effect. - on the eye: No irritating effect. - Sensitization: No sensitizing effects known. - Additional toxicological information: The product is not subject to classification according to internally approved calculation methods for preparations: When used and handled according to specifications, the product does not have any harmful effects according to our experience and the information provided to us. 12 Ecological information - General notes: Generally not hazardous for water 13 Disposal considerations - Product: - Recommendation: Contact manufacturer for recycling information. (Contd. on page 4) USA

9 DR Page 4/4 Material Safety Data Sheet acc. to ISO/DIS Printing date 11/30/2004 Reviewed on 03/25/2003 Trade name: Titanium-Aluminium - Uncleaned packagings: - Recommendation: Packaging can be reused or recycled after cleaning. (Contd. of page 3) 14 Transport information - Maritime transport IMDG: - Marine pollutant: No - Transport/Additional information: Not dangerous according to the above specifications. 15 Regulations - Sara - Section 355 (extremely hazardous substances): None of the ingredient is listed. - Section 313 (Specific toxic chemical listings): Aluminium - TSCA (Toxic Substances Control Act): All ingredients are listed. - Proposition 65 - Chemicals known to cause cancer: - Chemicals known to cause reproductive toxicity: - Canadian Ingredient disclosure list - Canadian Ingredient disclosure list (limit 0,1%) - Canadian Ingredient disclosure list (limit 1%) Aluminium - Cancerogenity categories - EPA (Environmental Protection Agency) - IARC (International Agency for Research on Cancer) - NTP (National Toxicology Program) - TLV (Threshold Limit Value established by ACGIH) - MAK (German Maximum Workplace Concentration) - NIOSH-Ca (National Institute for Occupational Safety and Health) - OSHA-Ca (Occupational Safety & Health Administration) - Product related hazard informations: Observe the general safety regulations when handling chemicals. The product is not subject to identification regulations according to directives on hazardous materials. - National regulations: - Water hazard class: Generally not hazardous for water. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. - Department issuing MSDS: Environment protection department. - Contact: Dr. Roller USA