MATERIAL SAFETY DATA SHEET Sakrete Flo-Coat Concrete Resurfacer

Transcription

1 Product Name: Product Number: Product Use: Manufacturer/Supplier: MATERIAL SAFETY DATA SHEET N/A Various. Phone Number: Basalite Concrete Products Vancouver, ULC th Street Surrey, BC Emergency Phone: CHEMTREC (800) CHEMTREC International +1 (703) hr Date of Preparation: EMERGENCY OVERVIEW DANGER CORROSIVE MATERIAL - MAY CAUSE BURNS. MAY CAUSE CANCER. Potential Health Effects: See Section 11 for more information. Likely Routes of Exposure: Skin contact, eye contact, inhalation, and ingestion. Eye: Skin: Ingestion: Inhalation: Section 1: PRODUCT AND COMPANY IDENTIFICATION Section 2: HAZARDS IDENTIFICATION Irritating to eyes. May cause burns in the presence of moisture. Irritating to skin. May cause burns in the presence of moisture. Skin contact during hydration may slowly develop sufficient heat that may cause severe burns possibly resulting in permanent injury. Do not allow product to harden around any body part or allow continuous, prolonged contact with skin. Handling can cause dry skin. May cause burns. May be harmful if swallowed. May cause stomach distress, nausea or vomiting. Irritating to respiratory tract. May cause burns in the presence of moisture. Chronic Effects: Contains ingredients known or suspected to be carcinogenic. Causes damage to lungs through prolonged or repeated exposure. Signs and Symptoms: Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness and swelling. Symptoms may include redness, drying, defatting and cracking of the skin. May cause burns in the presence of moisture. Medical Conditions Aggravated By Exposure: Asthma. Allergies. Target Organs: Skin, eyes, gastrointestinal tract, respiratory system. Potential Environmental Effects: No ecological consideration when used according to directions. Normal dilution of this product to drains, sewers, septic systems and treatment plants is not considered environmentally harmful. See Section 12 for more information. 1 / 7

2 CAS # Wt. % Portland cement Calcium oxide Ferric oxide Aluminum oxide Aluminum sulfate Calcium carbonate Magnesium oxide Eye Contact: Skin Contact: Inhalation: Ingestion: Section 4: FIRST AID MEASURES In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. Get medical attention immediately. In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Call a physician if irritation develops and persists. If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Seek medical attention or call poison control immediately. General Advice: In case of accident or if you feel unwell, seek medical advice immediately (show the label or MSDS where possible). Note to Physicians: Symptoms may not appear immediately. Flammability: Not flammable by WHMIS criteria. Means of Extinction: Suitable Extinguishing Media: Treat for surrounding material. Unsuitable Extinguishing Media: Products of Combustion: May include, and are not limited to: oxides of carbon. Explosion Data: Section 3: COMPOSITION / INFORMATION ON INGREDIENTS Section 5: FIRE FIGHTING MEASURES Sensitivity to Mechanical Impact: Sensitivity to Static Discharge: Protection of Firefighters: Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). Section 6: ACCIDENTAL RELEASE MEASURES Personal Precautions: Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental Precautions: Keep out of drains, sewers, ditches, and waterways. Minimize use of water to prevent environmental contamination. Methods for Containment: Contain spill, then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). 2 / 7

3 Methods for Clean-Up: Vacuum or sweep material and place in a disposal container. Other Information: Handling: Avoid contact with skin and eyes. Do not swallow. Do not breathe dust. Good housekeeping is important to prevent accumulation of dust. Avoid generating dust. The use of compressed air for cleaning clothing, equipment, etc, is not recommended. Handle and open container with care. Launder contaminated clothing before reuse. When using do not eat or drink. Wash hands before eating, drinking, or smoking. Storage: Keep out of the reach of children. Keep container tightly closed. Store in dust-tight, dry, labelled containers. Keep containers closed when not in use. Avoid any dust buildup by frequent cleaning and suitable construction of the storage area. Do not store in an area equipped with emergency water sprinklers. Exposure Guidelines Exposure Limits ACGIH-TLV mg/m³ 1 mg/m³ (no asbestos and <1% crystalline Portland cement silica, respirable fraction) Calcium oxide 2 mg/m 3 Ferric oxide 5 mg/m 3 (iron oxide fume; dust as Fe) Aluminum oxide 10 mg/m 3 Aluminum sulfate Calcium carbonate 10 mg/m³ Magnesium oxide 10 mg/m 3 Engineering Controls: Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits. Personal Protective Equipment: Section 7: HANDLING AND STORAGE Section 8: EXPOSURE CONTROLS / PERSONAL PROTECTION Eye/Face Protection: Wear approved eye (properly fitted dust- or splash-proof chemical safety goggles) / face (face shield) protection. Hand Protection: Wear suitable gloves. Skin and Body Protection: Wear suitable protective clothing. Respiratory Protection: A NIOSH approved dust mask or filtering facepiece is recommended in poorly ventilated areas or when permissible exposure limits may be exceeded. Respirators should be selected by and used under the direction of a trained health and safety professional following requirements found in ANSI s standard for respiratory protection (Z88.2). General Hygiene Considerations: Handle according to established industrial hygiene and safety practices. Section 9: PHYSICAL AND CHEMICAL PROPERTIES Appearance: Colour: Powder. 3 / 7

4 Odour: Odour Threshold: Physical State: MATERIAL SAFETY DATA SHEET Solid. ph: Viscosity: Freezing Point: Boiling Point: Flash Point: Evaporation Rate: Lower Flammability Limit: Upper Flammability Limit: Vapor Pressure: Vapor Density: Specific Gravity: Solubility in Water: Coefficient of Water/Oil Distribution: Auto-ignition Temperature: Percent Volatile, wt. %: VOC content, wt. %: 0%, Not applicable. Stability: Stable under normal storage conditions. Keep dry in storage. Conditions of Reactivity: Incompatible materials. Moisture. Incompatible Materials: Wet cement is alkaline and incompatible with acid, ammonium salts and aluminum metal. Hazardous Decomposition Products: May include, and are not limited to: oxides of carbon. Possibility of Hazardous Reactions: No dangerous reaction known under conditions of normal use. EFFECTS OF ACUTE EXPOSURE Component Analysis Section 10: STABILITY AND REACTIVITY Section 11: TOXICOLOGY INFORMATION LD 50 (oral) 500 mg/kg, rat LC 50 Portland cement Calcium oxide 500 mg/kg, rat Ferric oxide > mg/kg, rat Aluminum oxide > 5000 mg/kg, rat Aluminum sulfate 1930 mg/kg, rat Calcium carbonate 6450 mg/kg, rat Magnesium oxide 4 / 7

5 Eye: Skin: Ingestion: Inhalation: MATERIAL SAFETY DATA SHEET Irritating to eyes. May cause burns in the presence of moisture. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness and swelling. Irritating to skin. May cause burns in the presence of moisture. Symptoms may include redness, drying, defatting and cracking of the skin. Skin contact during hydration may slowly develop sufficient heat that may cause severe burns possibly resulting in permanent injury. Do not allow product to harden around any body part or allow continuous, prolonged contact with skin. Handling can cause dry skin. May cause burns. May be harmful if swallowed. May cause stomach distress, nausea or vomiting. Irritating to respiratory tract. May cause burns in the presence of moisture. EFFECTS OF CHRONIC EXPOSURE Target Organs: Chronic Effects: Hazardous by WHMIS criteria. Carcinogenicity: Hazardous by WHMIS criteria. Chemical Listed as Carcinogen or Potential Carcinogen * G-A2, I-1, N-1 Portland cement G-A4 Calcium oxide Ferric oxide G-A4, I-3 Aluminum oxide Aluminum sulfate Calcium carbonate Magnesium oxide G-A4 * See Section 15 for more information. Mutagenicity: Not hazardous by WHMIS criteria. Reproductive Effects: Not hazardous by WHMIS criteria. Developmental Effects: Teratogenicity: Not hazardous by WHMIS criteria. Embryotoxicity: Not hazardous by WHMIS criteria. Respiratory Sensitization: Not hazardous by WHMIS criteria. Skin Sensitization: Not hazardous by WHMIS criteria. Toxicologically Synergistic Materials: Ecotoxicity: No ecological consideration when used according to directions. Normal dilution of this product to drains, sewers, septic systems and treatment plants is not considered environmentally harmful. Persistence / Degradability: Bioaccumulation / Accumulation: Mobility in Environment: Section 12: ECOLOGICAL INFORMATION 5 / 7

6 Disposal Instructions: This material must be disposed of in accordance with all local, state, provincial, and federal regulations. TDG Classification Not regulated Federal Regulations Canada: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Global Inventories Portland cement Calcium oxide Ferric oxide Aluminum oxide Aluminum sulfate Calcium carbonate Magnesium oxide HMIS - Hazardous Materials Identification System Health - 3* Flammability - 1 Physical Hazard - 0 PPE B NFPA - National Fire Protection Association: Health - 3 Fire - 1 Reactivity - 0 Hazard Rating: 0 = minimal, 1 = slight, 2 = moderate, 3 = severe, 4 = extreme WHMIS Classification(s): Class D2A - Carcinogenicity Class D2A - Chronic Toxic Effects Class E - Corrosive Material WHMIS Hazard Symbols: Section 13: DISPOSAL CONSIDERATIONS Section 14: TRANSPORTATION INFORMATION Section 15: REGULATORY INFORMATION Canada /N N SOURCE AGENCY CARCINOGEN CLASSIFICATIONS: ACGIH (G) IARC (I) American Conference of Governmental Industrial Hygienists. A1 - Confirmed human carcinogen. A2 - Suspected human carcinogen. A3 - Animal carcinogen. A4 - Not classifiable as a human carcinogen. A5 - Not suspected as a human carcinogen. International Agency for Research on Cancer. 6 / 7

7 NTP (N) 1 - The agent (mixture) is carcinogenic to humans. 2A - The agent (mixture) is probably carcinogenic to humans; there is limited evidence of carcinogenicity in humans and sufficient evidence of carcinogenicity in experimental animals. 2B - The agent (mixture) is possibly carcinogenic to humans; there is limited evidence of carcinogenicity in humans in the absence of sufficient evidence of carcinogenicity in experimental animals. 3 - The agent (mixture, exposure circumstance) is not classifiable as to its carcinogenicity to humans. 4 - The agent (mixture, exposure circumstance) is probably not carcinogenic to humans. National Toxicology Program. 1 - Known to be carcinogens. 2 - Reasonably anticipated to be carcinogens. Disclaimer: The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user s responsibility to satisfy oneself as to the suitability and completeness of this information for the user s own particular use. Expiry Date: March 19, 2018 Version #: 1.0 Basalite contact information added Prepared by: Section 16: OTHER INFORMATION Nexreg Compliance Inc. Phone: (519) / 7