Inorganic Reactions and Methods Volume 2

Transcription

1 Inorganic Reactions and Methods Volume 2 The Formation of the Bond to Hydrogen (Part 2) Editor J.J. Zuckerman Subject Index Editor A.P. Hagen

2 Contents of Volume 2 How to Use this Book Preface to the Series Editorial Consultants to the Series Contributors to Volume 2 xin xix xxiii xxv 1. The Formation of the Bond to Hydrogen (Part 2) Formation of Bonds between Hydrogen and Elements of Group VB (N, P, As, Sb, Bi) by Reaction of Hydrogen with Nitrogen from the Elements. from Compounds. with Phosphorus. with Arsenic. with Antimony. with Bismuth. by Protonation of Nitrogen in Aqueous Systems. in Other Protonic Solvents. with Protonic Acids in Nonprotonic Solvents. of Phosphorus and Phosphorous Compounds in Aqueous Systems. in Other Protonic Solvents. with Protonic Acids in Nonprotonic Solvents. of Arsenic and Arsenic Compounds in Aqueous Systems. in Other Protonic Solvents. with Protonic Acids in Nonprotonic Solvents V

3 vi Contents of Volume 2 Formation of Bonds between Hydrogen and Elements of Group VB (N, P, As, Sb, Bi) of Antimony. of Bismuth. by Reactions of Hydrides with Compounds of Nitrogen Invoiving Binary lonic Hydrides. Involving Binary Covalent Hydrides. Invoiving Exchange-Cleavage. Involving Redistribution- Disproportionation. with Compounds of Phosphorus Involving lonic Hydrides. Involving Covalent Hydrides. Involving Exchange. Involving Redistribution- Disproportionation. with Compounds of Arsenic. with Compounds of Antimony. with Compounds of Bismuth. by Reaction of Complex Hydrides with Compounds of Nitrogen. with Compounds of Phosphorus Involving Halides. Involving Oxygen Compounds. Involving Other Derivatives. with Compounds of Arsenic Involving Halides. Involving Oxygen Compounds. with Compounds of Antimony. with Compounds of Bismuth. by Industrial Processes with Compounds of Nitrogen. with Compounds of Phosphorus. with Compounds of Arsenic. with Compounds of Antimony. The Synthesis of Deuterium Derivatives by Interconversion of Deuterated Compounds Involving Nitrogen. Involving Phosphorus. Involving Arsenic. Involving Antimony. Involving Bismuth. by Isotopic Enrichment Using Chemical Reactions of Nitrogen Compounds

4 Contents of Volume 2 VII of Phosphorous Compounds of Arsenic Compounds Formation of Bonds between Hydrogen and Elements of Group IVB (C, Si, Ge, Sn, Pb) from the Elements Giving Hydrides of Carbon from Elemental Carbon. from Elemental Hydrogen. Giving Hydrides of Silicon. Giving Hydrides of Germanium. Giving Hydrides of Tin. Giving Hydrides of Lead. by Reactions of Group IVB Anionic Derivatives Giving Carbides from Protonic Species in Water. from Protonic Species in Liquid Ammonia. from Protonic Species in Other Solvents. Giving Silicides from Protonic Species in Water. from Protonic Species in Liquid Ammonia. from Protonic Species in Other Solvents. Giving Germanides from Protonic Species in Water. from Protonic Species in Liquid Ammonia. from Protonic Acids in Other Solvents. Giving Stannides from Protonic Species in Water. from Protonic Species in Liquid Ammonia. from Protonic Species in Other Solvents. Giving Plumbides. by Reactions of Hydrides with Compounds of Carbon Giving Nitrogen Compounds. Giving Compounds with Carbon-Carbon Multiple Bonds. with Compounds of Silicon

5 Contents of Volume 2 Formation of Bonds between Hydrogen and Elements of Group IVB (C, Si, Ge, Sn, Pb) with Compounds of Germanium with Compounds of Tin Giving Oxygen Compounds with Compounds of Lead by Reactions of Complex Hydrides with Carbon Compounds Giving Nitrogen Compounds. Giving Compounds with Carbon-Carbon Multiple Bonds. with Silicon Compounds with Germanium Compounds with Tin Compounds with Lead Compounds. by Industrial Processes with Compounds of Carbon. with Compounds of Silicon. with Compounds of Germanium. with Compounds of Tin. The Synthesis of Deuterium Derivatives by Interconversion of Deuterated Compounds Involving Carbon. Involving Silanes. Involving Germanes. Involving Stannanes. Involving Plumbanes

6 Contents of Volume 2 IX by Isotopic Enrichment Using Chemical Reactions of Carbon Compounds ofsilanes of Germanes Formation of Bonds between Hydrogen and Elements of Group HIB (B, AI, Ga, In, Tl) from the Elements. from Group HIB Derivatives, Excluding Reactions of Hydrides and Complex Hydrides Involving the Borides. Involving the Reduction of Group HIB Derivatives with Covalent Hydrides. Involving Other Reactions. from the Hydride Ion with Compounds of Boron Involving Halides. Involving Oxygen Compounds. Involving Nitrogen Compounds. Involving Other Compounds. with Compounds of Aluminum. with Compounds of Gallium. with Compounds of Indium. with Compounds of Thallium. from Complex Hydrides with Compounds of Boron. with Compounds of Aluminum, Gallium, Indium and Thallium. by Industrial Processes. The Synthesis of Deuterium Derivatives by Isotopic Exchange. by Isotope Enrichment Using Chemical Reactions Formation of Bonds between Hydrogen and Metals of Group IA (Li, Na, K, Rb, Cs, Fr) or IIA (Be, Mg, Ca, Sn, Ba, Ra) Alkali-Metal Hydrides Lithium Hydride

7 X Contents of Volume 2 Formation of Bonds between Hydrogen and Metals of Group IA (Li, Na, K, Rb, Cs, Fr) or IIA (Be, Mg, Ca, Sn, Ba, Ra) Sodium, Potassium, Rubidium and Cesium Hydrides Alkaline-Earth Metal Hydrides Beryllium Hydride Magnesium Hydride Calcium, Strontium and Barium Hydrides Formation of Bonds between Hydrogen and Metals of Group IB (Cu, Ag, Au) or IIB (Zn, Cd, Hg) from the Elements. by Reactions with Hydrogen Atoms and Ions with Compounds of Group IB. by Reactions of Hydride Ion with Compounds of Group IB. with Compounds of Group IIB. by Reactions with Neutral and Anionic Metal Hydrides with Compounds of Group IB. with Compounds of Group IIB. by Other Methods for Group IB and IIB Metal Hydrides Formation of Bonds between Hydrogen and Transition and Inner-Transition Metals from the Elements. by Hydrogenation of Metal Oxides. of Metal Salts. of Metal Carbonyls. by Oxidative Addition of Hydrogen to Neutral, Coordinatively Unsaturated Species Involving Iridium. Involving Platinum

8 Contents of Volume 2 xi Involving Rhodium Involving Fe Ir and Ta Ta Clusters to Cationic, Coordinatively and Unsaturated Species of Rhodium, Ruthenium and Iridium to Neutral Species with Replacement of Coordinated Ligands Involving Niobium, Tantalum and Zirconium Involving Molybdenum and Rhenium Involving Ruthenium and Mixed Metal- Ruthenium Clusters Involving Iron, Osmium, Rhodium, Iridium and Platinum to Cationic Species of Iridium, Rhodium and Platinum with Replacement of Coordinated Ligands by Oxidative Addition to Metal Complexes of Hydrogen Halides of Hydrogen-Boron Bonds of Hydrogen-Carbon Bonds of Hydrogen-Other Group IVB Element Bonds of Hydrogen-Group VB Element Bonds Involving Hydrogen-Nitrogen Bonds Involving Hydrogen-Phosphorus Bonds of Hydrogen-Group VIB Element Bonds Involving Hydrogen-Oxygen Bonds Involving Hydrogen-Sulfur Bonds by Protonation of Neutral and Cationic Complexes in Acid with Mononuclear Complexes: Scope with Mononuclear Complexes: Position of the Protonation Equilibria with Mononuclear Complexes: Rates with Polynuclear Complexes of Metal Anions with Mononuclear Anions: Scope with Mononuclear Anions: Position of the Protonation Equilibira with Mononuclear Anions: Rates with Polynuclear Anions by Reduction of Metal Complexes with Borohydride with Trialkylborohydride and Other Substituted Borohydrides with Tetrahydroaluminate with Alkoxyaluminum Hydrides by Hydrogen Transfer to the Metal from Alcohols in Basic Media. 226

9 xii Contents of Volume 2 Formation of Bonds between Hydrogen and Transition and Inner-Transition Metals from Hydrazine. from Aluminum Alkyls. from Alkyimagnesium Halides. by Decarboxylation of Hydroxycarbonyl or Formate Complexes Formation of Bonds between Hydrogen and Elements of Group 0 Formation of Reversible Metal Hydrides by Direct Reaction of Hydrogen with Alkali Metals. with Alkaline-Earth Metals. with Group IIIA Transition Metals Involving Lanthanides. Involving Actinides. with Group IVA Transition Metals Involving Titanium. Involving Zirconium. Involving Hafnium. with Group VA Transition Metals. with Groups VIA, VIIA and VIII Transition Metals Involving Chromium and Molybdenum. Involving Manganese and Technetium. Involving Nickel, Rhodium and Palladium. to Form Ternary Hydrides from Intermetallics Giving AM 5 Compounds. Giving AB 2 Compounds. Giving Hydrides of Other Intermetallics. from Metal-Nonmetal Systems Involving Carbides. Involving Oxides and Sulfides. Involving Nitrides and Phosphides. Involving Halides List of Abbreviations Author Index Compound Index Subject Index