MATERIAL SAFETY DATA SHEET

Transcription

1 Publishing date: Revision date: - MATERIAL SAFETY DATA SHEET [According to Regulation (EC) No 1907/2006 of the European Parliament] 1. I d e n t i f i c a t i o n o f t h e p r e p a r a t i o n a n d t h e c o m p a n y Trade Name: Gelike Gel Polish Product characteristic: Soak Off Gel Product description: Fingernail colorant Website: abg-nail@ .cz Emergency tel: [working hours 10-18] 2. H a z a r d i d e n t i f i c a t i o n This substance is considered to be non-hazardous for transport. EMERGENCY OVERVIEW Physical state: Liquid Color: Color Odor: Light characteristic acrylate odor Personal Protection: See Section 8 Warning: Harmful If Swallowed, Absorbed Through Skin Or Inhaled. Do Not Spray. Do Not Heat. May Cause Allergic Skin Reaction. Irritating To Eyes, Respiratory System And Skin. Relevant Routes Of Exposure: Skin, Inhalation, Eyes. Potential Health Effects Skin contact: Contact skin will cause Irritation. Eye contact: Contact with eyes will cause irritation. 3. C o m p o s i t i o n, i n f o r m a t i o n o n i n g r e d i e n t s Substances name, concentration Polyurethane Acrylate 50-60% Oligomer Ethylene Glycol 10-20% Methacrylate Polymer Acrylate 20-30% Oligomer 1-Hydroxycyclohexyl 1-8% Phenyl Ketone CAS Number EINECS/ ELINCS INCI name: Di Hema Trimethylhexyl Dicarbamate HEMA Hydroxycyclohexyl Phenyl Ketone Hazard Symbols, R phrases R:36/37/38 R:36/38-43 R:36/37/38 EU-INDEX: X R: 36 - GHS/CLP: Eye Irrit. 2 H315; STOT SE 3 H319; Skin Irrit. 2 H335; Eye Irrit.2 H319 Skin Irrit. 2 H315 Skin Sens.1 H Eye Irrit. 2 H315; STOT SE 3 H319; Skin Irrit. 2 H335; Pigment 1-2%

2 MAY CONTAIN THE FOLLOWING CHEMICALS: COMPONENTS CAS EINECS/ELINCS INCI name: CONCENTRATION Classified: R-phrase: ACID RED CI (3) 0-1% - - D&C Red CI % - - D&C Red No CI % - - Red Iron Oxide CI % - - Black Oxide of Iron CI % - - Pigment Yellow CI % - - Ferric ferrocyanide; CI % - - Prussian blue C-Violett CI % - - Titanium dioxide CI % - - Chromium Hydroxide CI % - - Green C.I. Food Yellow CI 15985:1 0-1% - - Aluminum Lake Aquamarine Blue CI % - - Inhalation: 4. F i r s t a i d m e a s u r e s Remove to fresh air. If symptoms develop and persist, get medical attention. Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing and shoes. Wash clothing before reuse. Get immediate medical attention if symptoms occur. Eye contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get immediate medical attention. Ingestion: Do not induce vomiting. Keep individual calm. Get medical attention immediately. C Autoignition temperature: Not available Flammable/Exposive limits-lower %: Not available Flammable/Exposive limits-upper %: Not available Extinguishing media: Foam, dry chemical or carbon dioxide. 5. F i r e f i g h t i n g m e a s u r e s Special fire fighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Unusual fire or explosing hazards: Uncontrolled polymerization may occur at high temperatures resulting in explosions or rupture of storage containers. Hazardous combustion products: Oxides of carbon. Oxides of nitrogen. Irritating organic vapors. Toxic fumes.

3 Environmental precautions: 6. A c c i d e n t a l r e l e a s e m e a s u r e s Remove sources of ingition. Prevent product from entering drains or open waters. Clean-up methods: Refer to Section 8 Exposure Controls/Personal Protection prior to clean up. Soak up with inert absorbent. Store in a partly filled, closed container until disposal. Handling: 7. H a n d l i n g a n d s t o r a g e Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. DO NOT heat or spray. Use only with adequate ventilation. Refer to Section 8. Use only in area provided with appropriate exhaust ventilation. Storage: or safe storage, store at or below 2 C 80 F). Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use. Incompatible products: Refer to Section 10. Engineering controls: 8. E x p o s u r e controls and personal protection Local exhaust ventilation is recomended when general ventilation is not sufficient to control airborne contamination below occupational exposure limits. Respiratory protection: Use COSHA approved respirator if there is potential to exceed exposure limit(s). If this material is handled at elevated temperatures or under mist forming conditions, without engineering controls, a COSHA approved respirator must be used. Skin protection: Use impermeable gloves and protective clothing as necessary to prevent skin contact. Neoprene gloves. Eye/face protection: Safety goggles or safety glasses with side shields. In a splash hazard environment, chemical googles should be used in combination with a full face shield. Physical state: Liquid Odor: Light characteristic acrylate odor Color: Color ph: Not applicable Vapor pressure: Not available Boiling point/range: reater than 3 C 200 F) Melting point/range: Not available Specific gravity: P h y s i c a l a n d c h e m i c a l p r o p e r t i e s

4 Vapor density: Not available Evaporation rate: Not available Solubility in water: Slight Partition coefficient (n-octanol/water): Not available. Voc content: Toatal volatiles: 0.80% Stability: Stable under normal conditions of storage and use. Hazardous polymerization: May occur S t a b i l i t y a n d r e a c t i v i t y Hazardous decomposition products: Oxides of carbon. Oxides of nitrogen. Irritating organic vapors. Incompability: Strong oxidizing agents. Bases. Conditions to avoid: eat, ames, sparks and other sources of igni on. o not heat above 2 C 80 F) T o x i c o l o g i c a l i n f o r m a t i o n Carcinogen Status Hazardous Components NTP Carcinogen IARC Carcinogen COSHA Carcinogen Polyurethane Acrylate Oligomer NO NO NO Ethylene Glycol Methacrylate NO NO NO Polymer Acrylate Oligomer NO NO NO 1-Hydroxycyclohexyl Phenyl Ketone NO NO NO Literature Referenced Target Organ & Other Health Effects Hazardous Components Health Effects/Target Organs Polyurethane Acrylate Oligomer Ethylene Glycol Methacrylate Polymer Acrylate Oligomer 1-Hydroxycyclohexyl Phenyl Ketone Ecological information: Not available Disposal methods for the product Disposal in accordance with the local legislation. Disposal methods for used packing 1 2. E c o l o g i c a l i n f o r m a t i o n 1 3. D i s p o s a l c o n s i d e r a t i o n s Empty containers give for appropriate rubbish dump or for disposal in accordance with the local legislation. Residual vapor may explode on ignition; do not cut, drill, or weld on or near the container.

5 The product 1 4. T r a n s p o r t i n f o rma t i o n C. 15. R e g u l a t o r y i n f o r m a t i o n Hazard symbols IRRITATING Substance name for labeling Contain: ethylene glycol dimethacrylate. Risk phrases R36/37/38 Irritating to eyes, respiratory system and skin. R43 May cause sensitization by skin contact. Safety phrases S2 Keep out of reach of children. S18 Handle and open container with care. S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S46 If swallowed, seek medical advice immediately and show the container or label. Full range of H-Phrases from Section 3. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H335 May cause respiratory irritation. Regulations Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorization and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC. Council Directive 67/548/EEC of 27 June 1967 on the approximation of laws, regulations and administrative provisions relating to the classification, packaging and labeling of dangerous substances. Commission Directive 2001/58/EC of 27 July 2001 amending for the second time Directive 91/155/EEC defining and laying down the detailed arrangements for the system of specific information relating to dangerous preparations in implementation of Article 14 of European Parliament and Council Directive 1999/45/EC and relating to dangerous substances in implementation of Article 27 of Council Directive 67/548/EEC (safety data sheets). Commission Directive 2001/59/EC of 6 August 2001 adapting to technical progress for the 28th time Council Directive 67/548/EEC on the approximation of the laws, regulations and administrative provisions relating to the classification, packaging and labeling of dangerous substances.

6 Commission Directive 2004/73/EC of 29 April 2004 adapting to technical progress for the twenty-ninth time Council Directive 67/548/EEC on the approximation of the laws, regulations and administrative provisions relating to the classification, packaging and labeling of dangerous substances O t h e r i n f o r m a t i o n Full text of indicated R-phrases mentioned in chapter 3 R36/37/38 Irritating to eyes, respiratory system and skin. R36 Irritating to eyes R:36/38-43 Irritating to eyes and skin. May cause sensitization by skin contact. Other data The product classification has been prepared according to real concentration of each component and identifies real danger caused by this product. Real concentration of a particular component is always within the proper range. Considering that the final product classification may vary from the classification calculated using upper values of concentration. The information above is based on a current available data concerning the product, but also on the experience and knowledge in this field of the producer. They are neither a quality description of the product nor a guarantee of particular features. They are to be treated as aid to safety in transport, storage and usage of the product. This does not free the user from the responsibility of improper usage of the information above and also of improper compliance with the law norms in the field. This Material Safety Data Sheet is annulling and replacing all the others made in the past.