NXT* Z 100. Technical Data Sheet NXT* Z 100

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1 Technical Data Sheet NXT* Z 100 NXT* Z 100 Description The most recent groundbreaking advancement in NXT* s for silica tires is, which is expected to raise the tire-performance bar with improved dynamic and physical properties. Momentive Performance Materials' newest NXT coupling agent for silica tires is essentially ethanol-free and features the one-pass mixing and shelf-stable compounds for which NXT s are known. Compared with traditional s, this new will virtually eliminate (1) the ethanol that is released during manufacturing and use of silica tires. (1) Contains less than 1% by weight total releasable ethanol. Key Features and Benefits is designed for improved dynamic and physical properties, with reduced overall manufacturing costs through improved processing, lower use levels and, virtual elimination of ethanol emissions. Superior performance property set at lower loading level Ethanol (VOC) emissions essentially eliminated Single non-productive mixing step & faster processing High temperature mixing without viscosity increase or scorch Long shelf life for uncured compounds Improved reinforcement properties Improved dynamic properties at low temperatures (+5 to -20 C) Very low maximum in tanδ over the 0 to 25% strain range Substantial reduction in small strain non-linearity, ΔG' Excellent silica dispersion & low reagglomeration Chemical Structure Generalized Structure of Silane Page 1 of 7

2 The schematic above shows a generalized structure of s. The silicon end of the molecule consists of silicon atoms bridged through non-volatile diols. These diols remain in the compound after mixing. The mercapto and blocked mercapto groups of the offer different coupling reactivity with the polymer. The mercapto group reacts with the polymer during the non-productive mixing stage, while the blocked-mercapto group aids in the dispersion of the silica. When the octanoyl-blocking group is removed during the productive mixing stage and curing step, additional mercapto is formed. Proton-donors, that include the vulcanization ingredients, assist in the removal of the octanoyl-blocking group. These newly generated mercapto groups react with the polymer during vulcanization and increase the coupling between silica and polymer. Patent Status is the subject of multiple pending U.S. patent applications. Nothing contained herein shall be construed to imply the nonexistence of any relevant patents or to constitute the permission, inducement or recommendation to practice any invention covered by any patent, without authority from the owner of the patent. Product Safety, Handling and Storage Customers should review the latest Safety Data Sheet (SDS) and label for product safety information, safe handling instructions, personal protective equipment if necessary, emergency service contact information, and any special storage conditions required for safety. Momentive Performance Materials (MPM) maintains an around-the-clock emergency service for its products. SDS are available at or, upon request, from any MPM representative. For product storage and handling procedures to maintain the product quality within our stated specifications, please review Certificates of Analysis, which are available in the Order Center. Use of other materials in conjunction with MPM products (for example, primers) may require additional precautions. Please review and follow the safety information provided by the manufacturer of such other materials. Processing Recommendations Testing Procedures: was evaluated in a typical silica-filled tread compound. The formulation is given in Table 1. The control compound containing a traditional tetrasulfide coupling agent, Silquest* A-1289, was mixed at 160 C in two non-productive mix steps. Compounds containing NXT and s Page 2 of 7

3 were mixed at 170 C in a single non-productive mix step. The total mixing time for both NXT* and the new was 12 minutes. The control compound containing Silquest A-1289 required 18 minutes and a cool down step between the two non-productive mix steps. exhibits excellent processing characteristics similar to those of NXT. Table 1. Typical Silica-Reinforced Tire Tread Formulation Used to Evaluate NXT and s PHR Ingredient ssbr - (~50% vinyl content) 25 BR - (high cis butadiene rubber) 80 Silica (precipitated) Variable Silquest A-1289, NXT, - (Momentive Performance Materials) 4.5 Oil - (Aromatic or non-aromatic) 2.5 Zinc Oxide 1.0 Stearic Acid PPD - (antioxidant/antiozonant) 3.0 N-330 Carbon Black 1.5 Wax Final Mix Ingredients 1.4 Sulfur 1.7 CBS - (primary accelerator) 2.0 DPG - (secondary accelerator) Table 2 shows a comparison of performance characteristics with rubber compounds made with Silquest* A-1289, NXT*, and s. Based on this data, shows a 7% reduction in Mooney viscosity, and a reduction of approximately 50% in cure times, when compared to the control. Non-linearity under small strains (ΔG') and tanδ values are substantially reduced with. These dynamic properties predict a rubber compound with reduced rolling resistance. The reinforcement index of is 15% higher than Silquest A-1289, which suggests better wear characteristics. The higher tanδ values at low temperatures indicate a strong potential to improve wet traction properties of tire treads made with. Table 2: Comparison of Performance Characteristics: Silquest A-1289, NXT and s Page 3 of 7

4 Ingredient (phr) Silquest A-1289 NXT solution SBR Butadiene rubber Silica Silquest A NXT No. Mixing Steps Mixing Temperature 160ºC 170ºC 170ºC Thermal Step (min) Compound Properties Processing Mooney Viscosity Scorch Time (min) Cure Time t90 (min) M L (dnm) M H (dnm) Non-linearity 60ºC G initial (MPa) ΔG (MPa) G max (MPa) tanδ max Wet-skid Indicator, 10 Hz, 1% DSA tanδ 0ºC Reinforcement Hardness (Shore A) M 25% (MPa) M100% (MPa) M300% (MPa) M300%/ M100% Elongation at rupture (%) Stress at rupture (MPa) A loading optimization study was conducted with using the formulation in Table 1. The performance of the rubber compounds using at different loading levels is presented in Table 3. Lower loading levels provided better scorch safety with a modest change in dynamic properties. Table 3. Comparison of Loading on Performance Characteristics Page 4 of 7

5 Ingredient Silquest A-1289 Silane phr Silica Loading No. Mixing Steps Mixing Temperature 160ºC 170ºC 170ºC 170ºC 170ºC Thermal Step (min) Compound Properties Processing Mooney Viscosity Scorch Time (min) Cure Time t90 (min) M L (dnm) M H (dnm) Non-linearity 60ºC G, initial (MPa) ΔG (MPa) G max (MPa) tanδ max Wet-skid Indicator, 10 Hz, 1% DSA tanδ 0ºC -Reinforcement Hardness (Shore A) M 25% (MPa) M100% (MPa) M300% (MPa) M300% / M100% Elongation at rupture (%) Stress at rupture (MPa) The large improvement in silica dispersion of compounds made with leads to a decrease in filler-filler interactions and results in lower G, ΔG and Shore A hardness when compared to the control. In order to take full advantage of improved silica dispersion, some compounds reformulation may be advisable to adjust hardness. Equal hardness may be important for tire handling and cornering. To raise hardness, we recommend increasing the amount of precipitated silica or carbon black, adding low levels of fumed silica or reducing the amount of processing oil. Table 4 shows the effect of these hardness adjustments in the formulation. The tread compound hardness was adjusted to the same level as the control compound, without sacrificing other properties, by the addition of 10 phr of precipitated silica or carbon black filler, or by reducing the processing oil. Table 4. Comparison of Performance Characteristics with and Hardness Adjustments Page 5 of 7

6 Ingredient Silquest A-1289 Silane phr Silica Loading Hardness Adjustment None +10phr N phr silica +5 phr N phr silica No. Mixing Steps phr oil Mixing Temperature 160ºC 170ºC 170ºC 170ºC 170ºC 170ºC Thermal Step (min) Compound Properties Processing Mooney Viscosity Scorch Time (min) Cure Time t90 (min) M L (dnm) M H (dnm) Non-linearity 60ºC G, initial (MPa) ΔG (MPa) G max (MPa) tanδ max Wet-skid Indicator, 10 Hz 1% DSA tanδ 0ºC -Reinforcement Hardness (Shore A) M 25% (MPa) M100% (MPa) M300% (MPa) M300% / M100% Elongation at rupture (%) Stress at rupture (MPa) Abrasion loss (mm 3 ) DIN Limitations Customers must evaluate Momentive Performance Materials products and make their own determination as to fitness of use in their particular applications. Contact Information Page 6 of 7

7 For product prices, availability, or order placement, contact our customer service at Momentive.com/CustomerService/ For literature and technical assistance, visit our website at: DISCLAIMER: THE MATERIALS, PRODUCTS AND SERVICES OF MOMENTIVE PERFORMANCE MATERIALS INC. AND ITS SUBSIDIARIES AND AFFILIATES (COLLECTIVELY SUPPLIER ), ARE SOLD SUBJECT TO SUPPLIER S STANDARD CONDITIONS OF SALE, WHICH ARE INCLUDED IN THE APPLICABLE DISTRIBUTOR OR OTHER SALES AGREEMENT, PRINTED ON THE BACK OF ORDER ACKNOWLEDGMENTS AND INVOICES, AND AVAILABLE UPON REQUEST. ALTHOUGH ANY INFORMATION, RECOMMENDATIONS, OR ADVICE CONTAINED HEREIN IS GIVEN IN GOOD FAITH, SUPPLIER MAKES NO WARRANTY OR GUARANTEE, EXPRESS OR IMPLIED, (i) THAT THE RESULTS DESCRIBED HEREIN WILL BE OBTAINED UNDER END-USE CONDITIONS, OR (ii) AS TO THE EFFECTIVENESS OR SAFETY OF ANY DESIGN INCORPORATING ITS PRODUCTS, MATERIALS, SERVICES, RECOMMENDATIONS OR ADVICE. EXCEPT AS PROVIDED IN SUPPLIER S STANDARD CONDITIONS OF SALE, SUPPLIER AND ITS REPRESENTATIVES SHALL IN NO EVENT BE RESPONSIBLE FOR ANY LOSS RESULTING FROM ANY USE OF ITS MATERIALS, PRODUCTS OR SERVICES DESCRIBED HEREIN. Each user bears full responsibility for making its own determination as to the suitability of Supplier s materials, services, recommendations, or advice for its own particular use. Each user must identify and perform all tests and analyses necessary to assure that its finished parts incorporating Supplier s products, materials, or services will be safe and suitable for use under end-use conditions. Nothing in this or any other document, nor any oral recommendation or advice, shall be deemed to alter, vary, supersede, or waive any provision of Supplier s standard Conditions of Sale or this Disclaimer, unless any such modification is specifically agreed to in a writing signed by Supplier. No statement contained herein concerning a possible or suggested use of any material, product, service or design is intended, or should be construed, to grant any license under any patent or other intellectual property right of Supplier covering such use or design, or as a recommendation for the use of such material, product, service or design in the infringement of any patent or other intellectual property right. Momentive and the Momentive logo are trademarks of Momentive Performance Materials Inc. HCD (Rev :47 AM) Page 7 of 7