Material Safety Data Sheet

Transcription

1 Conforms to ANSI Z Standard (United States, Canada, Mexico). 1. Material Safety Data Sheet Product and company identification Common name Material uses Supplier/Manufacturer Uncured rubber compound. Fenner Dunlop 146 South Westwood P. O. Box 441 Toledo, OH Tel (419) ext. 324 Fax (419) In case of emergency CHEMTREC, U.S. (800) International (703) MSDS authored by Kemika XXI Inc /15/ Physical state Odor Color Hazard status Hazards identification Routes of entry Potential acute health effects Eyes Skin Ingestion Potential chronic health effects Medical conditions aggravated by overexposure See toxicological information (section 11) Solid. (Rubber.) Characteristic. Black. This material is classified hazardous under OSHA regulations in the United States, the WHMIS Controlled Product Regulation in Canada and the NOM-018-STPS-2000 in Mexico. Emergency overview WARNING! HARMFUL IF ABSORBED THROUGH SKIN. CAUSES EYE AND SKIN IRRITATION. CONTAINS MATERIAL WHICH CAUSES DAMAGE TO THE FOLLOWING ORGANS LUNGS, RESPIRATORY TRACT, EYE, LENS OR CORNEA. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Dermal contact. Eye contact.. Ingestion. Irritating to eyes. Harmful in contact with skin. Irritating to skin. No known significant effects or critical hazards. No known significant effects or critical hazards. Carcinogenic effects Classified + (Proven.) by NIOSH [Carbon Black]. Classified 2B (Possible for humans.) by IARC [Carbon Black]. Classified A4 (Not classifiable for humans or animals.) by ACGIH [Carbon Black]. Classified 3 (Not classifiable for humans.) by IARC [Synthetic amorphous silica, precipitated]. Classified A4 (Not classifiable for humans or animals.) by ACGIH [Zinc oxide]. Mutagenic effects Not available. Teratogenic effects Not available. Carbon black contained in this material is totally bounded, so cannot be inhaled under any normal circumstances of uses. Repeated skin exposure can produce local skin destruction or dermatitis. Repeated exposure of the eyes to a low level of dust can produce eye irritation. Repeated or prolonged exposure to the substance can produce target organ damage. Date of issue 09/15/2006 Page 1/7

2 3. Composition/information on ingredients Name United States Canada Name CAS number % Carbon Black Synthetic amorphous silica, precipitated Propylidynetrimethyl trimethacrylate Mexico Classification CAS number Carbon Black Synthetic amorphous silica, precipitated Propylidynetrimethyl trimethacrylate Name UN number IDLH H F R Special CAS number % Carbon Black Not 1750 mg/m regulated. Propylidynetrimethyl Not trimethacrylate regulated. Synthetic amorphous silica, Not precipitated regulated. Zinc oxide UN mg/m Eye contact Skin contact Ingestion First aid measures Notes to physician 5. Fire-fighting measures Flammability of the product Products of combustion Extinguishing media Suitable Not suitable Special exposure hazards Special protective equipment for fire-fighters Check for and remove any contact lenses. In case of contact with eyes, rinse immediately with plenty of water. Get medical attention. In case of contact, immediately flush skin with plenty of water for at least 20 minutes. Get medical attention. If inhaled, remove to fresh air. If not breathing, give artificial respiration. Get medical attention. Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention. No specific antidote. Medical staff must contact Poison Control Center. May be combustible at high temperature. These products are carbon oxides. Some metallic oxides. Use an extinguishing agent suitable for the surrounding fire. None known. No specific hazard. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. % Date of issue 09/15/2006 Page 2/7

3 6. Accidental release measures Personal precautions Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable protective equipment. Environmental precautions Avoid dispersal of spilled material, runoff and contact with soil, waterways, drains and sewers. Methods for cleaning up If emergency personnel are unavailable, vacuum or carefully scoop up spilled material and place in an appropriate container for disposal by incineration. Avoid creating dusty conditions and prevent wind dispersal. 7. Handling Storage 8. Handling and storage Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Keep container tightly closed. Keep material in a cool well ventilated area. Exposure controls/personal protection United States Product name Exposure limits Carbon Black ACGIH TLV (United States, 1/2005). TWA 3.5 mg/m 3 8 hour(s). Form All forms. NIOSH REL (United States, 12/2001). TWA 3.5 mg/m 3 10 hour(s). Form All forms. OSHA PEL (United States, 8/1997). TWA 3.5 mg/m 3 8 hour(s). Form All forms. Synthetic amorphous silica, precipitated ACGIH TLV (United States, 1/2005). TWA 10 mg/m 3 8 hour(s). Form Gel TWA 10 mg/m 3 8 hour(s). Form All forms. OSHA PEL 1989 (United States, 3/1989). TWA 6 mg/m 3 8 hour(s). Form All forms. Zinc oxide ACGIH TLV (United States, 1/2005). STEL 10 mg/m 3 15 minute(s). Form All forms. TWA 2 mg/m 3 8 hour(s). Form All forms. NIOSH REL (United States, 12/2001). CEIL 15 mg/m 3 Form Dust STEL 10 mg/m 3 15 minute(s). Form Fume TWA 5 mg/m 3 10 hour(s). Form Dust and fumes OSHA PEL (United States, 8/1997). TWA 5 mg/m 3 8 hour(s). Form Fume TWA 5 mg/m 3 8 hour(s). Form Respirable fraction TWA 15 mg/m 3 8 hour(s). Form Total dust Propylidynetrimethyl trimethacrylate AIHA WEEL (United States, 1/2005). Skin TWA 1 mg/m 3 8 hour(s). Form All forms Canada Product name Exposure limits Carbon Black ACGIH TLV (United States, 1/2005). TWA 3.5 mg/m 3 8 hour(s). Form All forms. Synthetic amorphous silica, precipitated ACGIH TLV (Canada, 1/2005). TWA 10 mg/m 3 8 hour(s). Form Gel TWA 10 mg/m 3 8 hour(s). Form All forms. Zinc oxide ACGIH TLV (United States, 1/2005). STEL 10 mg/m 3 15 minute(s). Form All forms. TWA 2 mg/m 3 8 hour(s). Form All forms. Date of issue 09/15/2006 Page 3/7

4 Product name Exposure limits Carbon Black NOM-010-STPS (Mexico, 9/2000). CCT 7 mg/m 3 15 minute(s). Form Smoke CPT 3.5 mg/m 3 8 hour(s). Form Smoke Synthetic amorphous silica, precipitated NOM-010-STPS (Mexico, 9/2000). CPT 10 mg/m 3 8 hour(s). Form All forms. CPT 10 mg/m 3 8 hour(s). Form Inhalable fraction Zinc oxide NOM-010-STPS (Mexico, 9/2000). CCT 10 mg/m 3 15 minute(s). Form Smoke CPT 10 mg/m 3 8 hour(s). Form Powder CPT 5 mg/m 3 8 hour(s). Form Smoke Engineering measures Personal protection Eyes Skin Respiratory Hands Mexico Use only with adequate ventilation. If user operations generate dust, fumes, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Safety glasses. Lab coat. A respirator is not needed under normal and intended conditions of use. Natural rubber (latex). HMIS Code/Personal protective equipment B Personal protection in case Safety glasses, goggles or face shield. Impervious gloves. Full suit. Boots. Wear NIOSHapproved of a large spill self-contained breathing apparatus or equivalent and full protective gear. Hygiene measures Wash hands, forearms and face thoroughly after handling compounds and before eating, smoking and using the lavatory and at the end of the day. Follow good industrial hygiene practice. 9. Physical state Physical and chemical properties Auto-ignition temperature Color Odor ph Relative density Solubility 10. Solid. (Rubber.) Stability and reactivity The lowest known value is >140 C (284 F) (Carbon Black). Black. Characteristic. Neutral to (Water = 1) Insoluble in cold water, hot water. Stability and reactivity Incompatibility with various substances The product is stable. Reactive with oxidizing materials. Hazardous polymerization Will not occur. Conditions of reactivity Not available. Date of issue 09/15/2006 Page 4/7

5 11. Toxicological information Toxicity data Product/ingredient name Test Result Route Species Carbon Black LD50 >15400 mg/kg Oral Rat Zinc oxide LD50 LC mg/kg 2500 mg/m 3 (4 hour(s)) Oral Mouse Mouse Propylidynetrimethyl trimethacrylate LD mg/kg Dermal Rabbit Acute Effects Eyes Skin Ingestion Potential chronic health effects Target organs Irritating to eyes. Harmful in contact with skin. Irritating to skin. No known significant effects or critical hazards. No known significant effects or critical hazards. Carcinogenic effects Classified + (Proven.) by NIOSH [Carbon Black]. Classified 2B (Possible for humans.) by IARC [Carbon Black]. Classified A4 (Not classifiable for humans or animals.) by ACGIH [Carbon Black]. Classified 3 (Not classifiable for humans.) by IARC [Synthetic amorphous silica, precipitated]. Classified A4 (Not classifiable for humans or animals.) by ACGIH [Zinc oxide]. Mutagenic effects Not available. Teratogenic effects Not available. Carbon black contained in this material is totally bounded, so cannot be inhaled under any normal circumstances of uses. Contains material which causes damage to the following organs lungs, upper respiratory tract, eye, lens or cornea. 12. Ecological information Product/ingredient name Zinc oxide Environmental precautions Ecotoxicity data Species Period Result Daphnia magna (EC50) Oncorhynchus mykiss (LC50) Lepomis macrochirus (LC50) Pimephales promelas (LC50) 48 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) This material is not expected to be harmful to aquatic organisms. >1000 mg/l 1.1 mg/l >320 mg/l 2246 mg/l Products of degradation Toxicity of the products of biodegradation 13. Disposal considerations Waste disposal Zinc oxide contained in this material is totally bounded, so cannot be release in the environment under any normalcircumstances of uses. These products are carbon oxides and water. Some metallic oxides. The products of degradation are less toxic than the product itself. The generation of waste should be avoided or minimized wherever possible. Avoid dispersal of spilled material, runoff and contact with soil, waterways, drains and sewers. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional and local authority requirements. Date of issue 09/15/2006 Page 5/7

6 14. Transport information Regulatory information UN/ IMDG/ IATA DOT/ TDG Not regulated. Zinc oxide contained in this material is totally bounded, so cannot be release in the environment under any normalcircumstances of uses. 15. United States SARA 313 Canada Regulatory information HCS Classification U.S. Federal regulations Form R - Reporting requirements Supplier notification Irritating material Target organ effects TSCA All components listed. SARA 302/304/311/312 extremely hazardous substances No products were found. SARA 302/304 emergency planning and notification No products were found. SARA 302/304/311/312 hazardous chemicals Carbon Black; Propylidynetrimethyl trimethacrylate; Zinc oxide SARA 311/312 MSDS distribution - chemical inventory - hazard identification Carbon Black Immediate (acute) health hazard, Delayed (chronic) health hazard; Propylidynetrimethyl trimethacrylate Immediate (acute) health hazard; Zinc oxide Immediate (acute) health hazard, Delayed (chronic) health hazard Clean Water Act (CWA) 307 Zinc oxide Clean Water Act (CWA) 311 No products were found. Clean Air Act (CAA) 112 accidental release prevention No products were found. Clean Air Act (CAA) 112 regulated flammable substances No products were found. Clean Air Act (CAA) 112 regulated toxic substances No products were found. Product name CAS number Concentration SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed. State regulations Pennsylvania RTK Carbon Black (generic environmental hazard); Zinc oxide (environmental hazard, generic environmental hazard) Massachusetts RTK Carbon Black; Synthetic amorphous silica, precipitated; Zinc oxide New Jersey Carbon Black; Zinc oxide California prop. 65 No products were found. When bonded in the material, carbon black is exempted from California proposition 65 warning statement. Ingredient name Cancer Reproductive No significant risk level Maximum acceptable dosage level Carbon Black Yes. No. No. No. WHMIS (Canada) Class D-2B Material causing other toxic effects (Toxic). DSL All components listed. Date of issue 09/15/2006 Page 6/7

7 Mexico Classification HAZARD RATINGS 1 Flammability 4- Extreme Health 2 0 Reactivity 3- Serious 2- Moderate Special 1- Slight 0- Minimal This product has been classified in accordance with the hazard criteria of the Canadian CPR, the United States OSHA and the Mexican NOM -018-STPS This MSDS contains all the information required by the CPR, OSHA, the American National Standard Institute (ANSI) Z400.1 and NOM -018-STPS International lists 16. Other information Label requirements (U.S.A.) This product, (and its ingredients) is (are) listed on national inventories, or is (are) exempted from being listed, Australia (AICS), in Europe (EINECS/ELINCS), in Korea (TCCL), in Japan (METI), in the Philippines (RA6969). HARMFUL IF ABSORBED THROUGH SKIN. CAUSES EYE AND SKIN IRRITATION. CONTAINS MATERIAL WHICH CAUSES DAMAGE TO THE FOLLOWING ORGANS LUNGS, RESPIRATORY TRACT, EYE, LENS OR CORNEA. Hazardous Material Information System (U.S.A.) HMIS RATING Health * 2 Fire hazard Physical Hazard 1 0 Personal protection B HAZARD RATINGS 4- Extreme 3- Serious 2- Moderate 1- Slight 0- Minimal See section 8 for more detailed information on personal protection. National Fire Protection Association (U.S.A.) Health Flammability Reactivity Special References Date of issue Version ANSI Z400.1, MSDS Standard, Manufacturer's Material Safety Data Sheet. - 29CFR Part OSHA MSDS Requirements. - 49CFR Table List of Hazardous Materials, UN#, Proper Shipping Names, PG. - Canada Gazette Part II, Vol. 122, No. 2. Registration SOR/88-64, 31 December Hazardous Products Act "Ingredient Disclosure List" - Canadian Transport of Dangerous Goods, Regulations and Schedules, Clear Language version Official Mexican Standards NOM-018-STPS-2000 and NOM-004-SCT /15/ Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue 09/15/2006 Page 7/7