Enclosure: 1. Product Detail

Transcription

1 Sr. No. Product Name Enclosure: 1 Product Detail Existing (MT/Month) Proposed (MT/Month) Total After expansion (MT/Month) 1 NORMAL BUTYL BROMIDE NORMAL PROPYL BROMIDE ETHYL BROMIDE ISO PROPYL BROMIDE :3 DI BROMO 5:5 DI METHYL HYDENTOIN 6 TETRA BUTYL AMMOMIUM TRI BROMIDE CETYL BROMIDE OCTYL BROMIDE SODIUM BROMIDE POWDER SODIUM BROMIDE SOLN POTTASIUM BROMIDE POWDER LIQUID BROMINE TOTAL

2 Enclosure: 02 Packing & Final Use of Products Sr. No. Name of proposed products 1 NORMAL BUTYL BROMIDE 2 NORMAL PROPYL BROMIDE 3 ETHYL BROMIDE 4 ISO PROPYL BROMIDE 5 6 1:3 BROMO 5:5 DI METHYL HYDENTOIN TETRA BUTYL AMMOMIUM TRI BROMIDE 7 CETYL BROMIDE Final application of products Production of phase transfer catalyst and other Pharmaceutical industry Production of phase transfer catalyst and other Pharmaceutical industry Production of phase transfer catalyst and other Pharmaceutical industry Production of phase transfer catalyst and other Pharmaceutical industry Pharmaceutical industry as green brominating agent Pharmaceutical industry as green brominating agent Production of phase transfer catalyst Type of packing HDPE barrel HDPE barrel HDPE barrel HDPE barrel HDPE Carboys Fibre drum HDPE barrel

3 8 OCTYL BROMIDE 9 SODIUM BROMIDE POWDER 10 SODIUM BROMIDE SOLN. 11 POTTASIUM BROMIDE POWDER Production of phase transfer catalyst For the pharmaceutical industries For the pharmaceutical industries For the pharmaceutical industries As above 12 LIQUID BROMINE Self consumption HDPE barrel HDPE bags HDPE barrel HDPE bags Glass bottles in set of six in plastic or wooden crates

4 Enclosure: 3 Product Wise Raw Material Sr.No. Product Name Quantity (MT/Month) 1. NORMAL BUTYL BROMIDE NORMAL PROPYL BROMIDE ETHYL BROMIDE ISO-PROPYL BROMIDE :3 DI BROMO 5:5 DI METHYL HYDENTOINE TETRA BUTYL AMMOMIUM TRI BROMIDE 7. CETYL BROMIDE OCTYL BROMIDE SODIUM BROMIDE (POWDER) SODIUM BROMIDE (SOLUTION) Raw Material Total Quantity Name MT/Batch MT/Month N. Butanol Liq. Bromine Sulfur N. Propanol Liq. Bromine Sulfur Ethanol HBr Sulfuric Acid Iso-Propanol HBr Sulfuric Acid DMH Liq. Bromine Chlorine Gas Soda Ash TBAB Liq. Bromine HBr Cetyl Alcohol Liq. Bromine Red Phosphorous Sulfuric Acid Octyl Alcohol Liq. Bromine Red Phosphorous Sulfuric Acid NaOH Soln HBr Soln Charcoal NaOH Soln HBr Soln Charcoal

5 11. POTTASIUM BROMIDE (POWDER) LIQUID BROMINE 25 KOH/H 2 O HBr Solution Charcoal NaBr/KBr/NH 4 Br/ HBr Chorine Gas Overall list of Raw Material: Sr. No. Raw Material Name Quantity Total (MT/Month) (MT/Month) Existing Proposed 1 Normal Butanol Normal Propanol Iso Propanol Ethanol ,5 Di Methyl Hydantoin Liquid Bromine Hydrobromic Acid Octyl Alcohol Cetyl Alcohol Charcoal Solution of NaBr / KBr / NH 4 Br Chlorine Soda Ash Sulfuric Acid Sodium Hydroxide Sulfur Red Phosphorous Tetra Butyl Ammonium Bromide Potassium Hydroxide Flakes

6 Enclosure: 4 Chemical Name & Physical form of raw material with his storage facility Sr. No. Name of raw material CAS NO. Physical form Type of Packing MOC Max. at a time storage in MT Max Consumption MT/ week 1 Normal Butanol Liquid HDPE barrel-165 kg HDPE barrel 10 MT 6 MT 2 Normal Propanol Liquid HDPE barrel-165 kg HDPE barrel 10 MT 4.5 MT 3 Iso Propanol Liquid HDPE barrel-165 kg HDPE barrel 5 MT 2 MT 4 Ethanol Liquid HDPE barrel-165 kg HDPE barrel 4.5 MT 1 MT 5 5,5 Di Methyl Hydantoin Solid HDPE bag 50 kgs HDPE bag 7.5 MT 0.7 MT 6 Liquid Bromine Liquid Glass bottle of 3 kg in pack 6 bottle in wooden or plastic boxes- 18 kgs Glass bottle 18 MT 8.8 MT 7 Hydrobromic Acid Liquid HDPE barrel 200 kgs HDPE barrel 10 MT 4MT

7 8 Octyl Alcohol Liquid HDPE or galvanized iron barrel-190 kgs HDPE or galvanised iron barrel 1 MT 0.87 MT / Month 9 Cetyl Alcohol Solid HDPE bag 25 kg HDPE bag 1 MT 0.81 MT 10 Charcoal Solid HDPE bag of 50 kgs HDPE bag 0.5 MT MT 11 Solution of NaBr / KBr / NH 4 Br Liquid HDPE barrel of 220 kgs HDPE barrel 25 MT 6 MT 12 Chlorine Liquid/Gas Steel toners of 900 kgs Steel Toners 3.6 MT 1 MT 13 Soda Ash Solid HDPE bag of 50 kgs HDPE bag 5 MT 0.5 MT 14 Sulfuric Acid Liquid MS tanker MS Tank 15 MT 3 MT 15 Sodium Hydroxide solution Liquid MS tanker MS tank 20 MT 4 MT 16 Sulfur Solid HDPE bag of 50 kgs HDPE bag 5 MT 0.8 MT 17 Red Phosphorous Solid Galvanised drum of 50 kgs Galvanised drum 0.75 MT 0.5 MT/ Month 18 Tetra Butyl Ammonium Bromide Solid Fiber drum of 50 kgs Fiber Drums 1 MT MT/ month 19 Potassium Hydroxide Flakes Solid HDPE bag of 50 kgs HDPE bag 1 MT 0.47 MT/ month

8 Sr. No Product Enclosure: 5 Properties of Raw Material Physical & Chemical Composition B.P. F.P. LEL TLV Chemical Formula State MW o C o C % ppm or mg/nm 3 LD 50 mg/kg Sp.Gr. (Water=1)at V.D. at (air=1) Odor Threshold ppm, mg/nm 3 Solubility in Water 1 Normal Butanol C 3 H 9 OH Liquid Soluble 2 Normal Propanol C 3 H 7 OH Liquid Soluble 3 Iso Propanol C 3 H 8 O Liquid Miscible 4 Ethanol C 2 H 5 OH Liquid NA Soluble 5 5,5 Di Methyl Hydantoin C 5 H 8 N 2 O 2 Solid NA NA NA ND Soluble 6 Liquid Bromine Br 2 Liquid NA NA Soluble 7 Hydrobromic - Br-H Liquid Acid 86.7 NA NA NA NA Soluble 8 Octyl Alcohol C 8 H 17 OH Liquid NA 1790 NA NA 9 Cetyl Alcohol C 16 H 33 OH Solid NA NA NA Negligible 10 Charcoal C Solid NA NA NA 3.5 NA 3.51 NA NA Insoluble 11 Solution of NaBr / KBr / NaBr Liquid NA NA NA NA NA Soluble NH 4 Br 12 Chlorine Cl Liquid/Gas 71 - NA NA NA Soluble

9 Soda Ash Na 2 CO 3 Solid 106 NA NA NA NA NA NA Soluble 14 Sulfuric Acid H 2 SO 4 Liquid NA NA NA Soluble 15 Sodium Hydroxide NAOH Liquid NA NA 2 NA 2.12 NA NA Soluble 16 Sulfur S Solid NA 8437 NA 8.8 NA Insoluble 17 Red Phosphorous P Solid NA NA 0.02 NA 2.36 NA NA Insoluble 18 Tetra Butyl Ammonium C 16 H 36 NBr Solid NA NA NA NA NA NA Soluble Bromide 19 Potassium Hydroxide Flakes KOH Solid NA NA NA Soluble

10 Enclosure: 6 Details of Hazardous Chemicals The Raw materials, which are termed as hazardous Chemicals as per the Manufacturing, Storage and Import of Hazardous Chemicals (MSIHC) Rules, 1989 are as listed below Table: Sr. No. Name of Hazardous chemicals Reference in MSIHC Threshold Quantity (MT) Maximum Storage Capacity (MT) Sc-2 Sc-3 1 Liquid Bromine Sr. No. 84 (Sch-1 of MSIHC, 1989) Chlorine Sr. No. 119 (Sch-1 of MSIHC, 1989) Ethanol Sr. No. 248 (Sch-1 of MSIHC, 1989) Iso Propanol Sr. No. 334 (Sch-1 of MSIHC, 1989) Normal Butanol Sr. No. 412 (Sch-1 of MSIHC, 1989) Potassium Hydroxide Flask Sr. No. 522 (Sch-1 of MSIHC, 1989) Sodium Hydroxide Sr. No. 571 (Sch-1 of MSIHC, 1989) Sulphuric Acid Sr. No. 591 (Sch-1 of MSIHC, 1989)

11 Enclosure: 7 Manufacturing Prosess & Chemical Reaction & Mass Balance NORMAL BUTYL BROMIDE MANUFACTURING PROCESS: In reaction vessel take Normal Butanol+Sulfur+Water. Stir it. Than start addition of Liquid Bromine slowly. After complete addition of Liq. Bromine reflux it for 4½ hour then distill the product on next day. Normal Butyl Bromide and Residue transfer to reactor Regenerated Spent Sulphuric Acid. Takes in HDPE drums and packed it. CHEMICAL REACTION: C 4 H 9 OH + S + H 2 O + Br 2 C 4 H 9 Br + Dil. H 2 SO 4 + H 2 O FLOW SHEET OF NORMAL BUTYL BROMIDE: n-butyl Bromide Normal Butanol-625 kgs Sulfur-45 kg Water-675 Kg Liq. Bromine-675kgs R1 Normal Butyl Bromide-1000 kgs Spent Sulphuric Acid treated & Processing sent to Novel Spent -710 kgs

12 MANUFACTURING PROCESS: Normal Propyl Bromide: In a reactor take, Normal Propanol+ Sulfur+ Water and add Liq. Bromine Slowly. After Complete addition of Liq. Bromine reflux it for 4½ hour then distill the product. Normal Propyl Bromide and Residue transfer to reactor Regenerated Spent Sulphuric Acid. Takes in HDPE drums and paked it. CHEMICAL REACTION: C 3 H 7 OH + S + H 2 O + Br 2 C 3 H 7 Br + Dil. H 2 SO 4 + H 2 O n-propyl Bromide FLOW SHEET OF NORMAL PROPYL BROMIDE: Normal Propanol-513 kgs Sulfur-50 kgs Water-700 kgs Liq. Bromine-750 kgs R1 Normal Propyl Bromide-1000 kgs Processing Spent Sulphuric Acid treated & sent to Novel Spent Acid Mgmt-513 kgs

13 Ethyl Bromide: MANUFACTURING PROCESS: In reaction vessel take, Hydro Bromine acid & ethyl alcohol Stir it. Than start addition of Sulphuric acid slowly with chilling. Complete the addition of acid. Then reflux up to complete the reaction then distilled it. Takes in HDPE drums and packed it. CHEMICAL REACTION: CH 3 -CH 2 -OH + HBr + H 2 SO 4 CH 3 -CH 2 -Br + Dil. H 2 SO 4 Ethyl Bromide FLOW DIAGRAM: Ethanol-510 kgs Hydro bromic acid-2060 kgs Sulphuric Acid-1400 kgs Reactor Reaction & Distillation Separation Spent Sulphuric Acid treated & sent to Novel Spent Acid Mgmt kgs Drying Ethyl Bromide-1000 kgs

14 MANUFACTURING PROCESS: Iso-Propyl Bromide: In reaction vessel take, Iso-Propyl alcohol. Stir it. Than start addition of Liquid Bromine slowly up to reflux it. Complete the reaction then distilled it. Takes in HDPE drums and paked it. CHEMICAL REACTION: CH 3 -CH-CH 3 + HBr+H 2 SO 4 CH 3 -CH-CH 3 +Dil. H 2 SO 4 OH Br Iso-propyl bromide FLOW DIAGRAM: Iso- Propanol-550 kgs Hydrobromic Acid-1725 kgs Sulphuric Acid-1175 kgs Reactor Reaction & Distillation Separation Spent Sulphuric Acid treated & sent to Novel Spent Acid Mgmt kgs Drying Iso-Propyl Bromide-1000 kgs

15 MANUFACTURING PROCESS: 1:3 Di Bromo Di Methyl Hydentoine: In reaction vessel take, water & add soda ash & cool it to 20 C. Then start addition of Di methyl Hydentoin and dissolve it. Then add bromine slowly then pass chlorine till the reaction complete, then centrifuge it. Wash with water and dry it. CHEMICAL REACTION: (CH 3 ) 2 C NH (CH 3 ) 2 C NBr H 2 O+ CO + Na 2 CO 3 + Br 2 + Cl 2 CO + 2 NaCl+ H 2 O + CO 2 OC NH CO NBr 1:3 Di Bromo Di Methyl Hydentoin FLOW DIAGRAM: Water kgs Soda Ash-420 kgs Liq Bromine -434 kgs Chlorine -200 kgs DMH -334 kgs Reactor CO 2 Liberate-174 kgs Water-1500 kgs Centrifuge NaCl To ETP-2800 kgs Vaccum Drying Moisture loss-414 kgs 1:3 Di Bromo 5:5 Di Methyl Hydentoine-1000 kgs

16 MANUFACTURING PROCESS: Tetra Butyl Ammonium Tri Bromide: In reaction vessel take, tetra butyl ammonium bromide and then add Methylene chloride and water to it. Add Hydrobromic acid and liquid bromine slowly within 20 hr at C. Then centrifuge it and dried in a Vaccum dryer pack it. CHEMICAL REACTION: ( C 4 H 9 ) 4 NBr + Br 2 ( C 4 H 9 ) 4 NBr 3 Tetra Butyl Ammonium Tri bromide FLOW DIAGRAM: Water-900 kgs TBAB-675 kgs Liq Bromine-350 kgs HBr-100 kgs DMH-50 kgs Reactor Centrifuge Bromine Recovery Plant-975 kgs Vaccum Drying Moisture loss-100 kgs Tetra Butyl ammonium tri bromide kgs

17 Cetyl Bromide: MANUFACTURING PROCESS: In reaction vessel take, Cetyl alcohol & red Phosphorous than add Liquid Bromine slowly, stir it. Then separate the layer and wash with sulphuric acid and dry it. Pack it. CHEMICAL REACTION: C 16 H 33 OH + Br 2 + Red Phosphorous+Water C 16 H 33 Br+Dil. H 3 PO 3 FLOW DIAGRAM: Cetyl bromide Cetyl Alcohol-810 kgs Liq. Bromine-295 kgs Red Phosphorus-22 kgs Reactor Reg. H 3 PO 3-80 kgs Sulphuric Acid-130 kgs Separation Spent Acid treated & sent to Novel Spent Acid Mgmt -150 kgs Drying & Packing Moisture loss-27 kgs Cetyl Bromide-1000 kgs

18 Octyl Bromide: MANUFACTURING PROCESS: In reaction vessel take, Octyl alcohol& red Phosphorous than add Liquid Bromine slowly, stir it. Then separate the layer and wash with sulphuric acid and dry it &Pack it. CHEMICAL REACTION: C 8 H 17 OH +Br 2 + Red Phosphorous C 8 H 17 Br+Dil. H 3 PO 3 FLOW DIAGRAM: Octyl Bromide Octyl Alcohol-870 kgs Liq. Bromine-560 kgs Red Phosphorus-43 kgs Reactor Reg. H 3 PO kgs Sulphuric Acid-150 kgs Separation Spent Acid treated & sent to Novel Spent Acid Mgmt.-400 kgs Drying Moisture loss-33 kgs Octyl Bromide-1000 kgs

19 MANUFACTURING PROCESS: Sodium Bromide (Powder): In reaction vessel take, Sodium Hydroxide or Sodium bromide solution than add Hydrobromic acid and till neutralization to obtain their salt and evaporate that solution to get dry salt. CHEMICAL REACTION: NaOH/H 2 O + HBr (Solution) NaBr + H 2 O Sodium Bromide FLOW DIAGRAM: NaOH Soln-786 kgs HBr Soln-1573 kgs Reactor NaBr Sodium Bromide Solution Charcoal-05 kgs Centrifuge Wet Charcoal to Solid waste-15 kgs Heated, Cooled & crystallised NaBr Solid-1000 kgs Evaporated water-1349 kgs (condensed & used) NOTE If we have making Sodium Bomide Solution we will use only first step of this process OR for further process we will get Sodium Bromide Powder.

20 MANUFACTURING PROCESS: Potassium Bromide (Powder): In reaction vessel take, Potassium Hydroxide or Potassium bromide solution than add Hydrobromic acid and till neutralization to obtain their salt and evaporate that solution to get dry salt. CHEMICAL REACTION: KOH/KBr + HBr (Solution) KBr + H 2 O Potassium Bromide FLOW DIAGRAM: KOH/H 2 O-945 kgs HBr Soln-1371 kgs Reactor Charcoal-06 kgs Centrifuge Wet Charcoal to Solid waste-18 kgs Heated, Cooled & crystallised KBr (Powder)-1000 kgs Evaporation-1304 kgs

21 Liquid Bromine: MANUFACTURING PROCESS: In a recovery glass tower, take Sodium bromide solution or Hydrobromic acid solution or Potassium bromide solution or Ammonium bromide solution than pass chlorine gas & steam to generate liquid Bromide. CHEMICAL REACTION: NaBr / KBr / HBr / NH 4 Br Soln. + Cl 2 Br 2 +NaCl / KCl / HCl / NH 4 Cl Soln. Liq. Bromine FLOW DIAGRAM: NaBr/ KBr / HBr /NH 4 Br kgs Chlorine Gas-500 kgs Bromine extraction tower Liquid Bromine-1000 kgs NaCl/KCl/NH 4 Cl to ETP & HCl to acidify the solution-4167 kgs NOTE: When we will use NaBr/KBr/NH 4 Br effluent goes to ETP for treatment & We will use HBr generate HCl to acidify solution which is use in our plant.

22 Enclosure-8 DETAILS OF WATER CONSUMPTION & WASTEWATER GENERATION Water Consumption (KL/Day) Waste Water Generation (KL/Day) Existing Proposed Total Existing Proposed Total Domestic Industrial Process Boiler Washing Gardening TOTAL Domestic Wastewater Consumption is 600 L/day & Industrial Water Consumption is L/Day. Domestic Wastewater is 500 L/day will be disposed off through Soak Pit/Septic Tank System. Industrial effluent 8126 L/day will be treated in Effluent treatment Plant and 2390 L/day send to CETP of Vatva 5736 L/Day send to MEE-Vatva to maintain our unit Zero Liquid Discharged. Source of Water:- GIDC Water Supply

23 Water Balance Diagram All the Figures are in L/Day Water Consumption Industrial Domestic 600 Domestic Effluent goes to septic tank 500 Process 7368 Gardening 2000 Washing 1500 Boiler 7400 Effluent 5736 Washing Effluent 1500 Blow Down 890 To ETP than Send to MEE 5736 To ETP than Send to CETP 2390

24 Enclosure-9 Details of Effluent Treatment Plant Detail of Effluent Treatment Plant (After Proposed): Sr. No. Name of Unit Nos. Capacity (Liter) 1. Collection Cum Neutralization Tank Hopper Bottom Settling Tank Aeration Tank Secondary Settling Tank Sludge Drying Beds Final Collection Tank Holding Tank

25 Diagram of Effluent Treatment Plant (After Proposed): Collection Cum Neutralization Tank Hopper Bottom Settling Tank Aeration Tank Secondary Aeration Tank Filtration Sludge Drying Beds Overhead Holding Tank To CETP Vatva for Further Treatment And Disposal

26 Enclosure: 10 Details of Flue Gas Emission & process Gas Emission with APC system Flue Gas Emission Details: Sr. No. Stack Attached to Existing 1. IBR Boiler 2. NOTE: Hot Air Generator Proposed IBR Boiler (New as same quantity) Stack Height in Meter Parameter 11 Particulate Matter SO 2 NO x We Remove Our Old IBR Boiler After Obtaining Environment Clearance. Permissible Limit 150 mg/nm PPM 50 PPM Process Gas Emission Details: Sr. No. Stack Attached to Stack Height in Meter Air Pollution Control System Existing Proposed Parameter Permissible Limit 1. Reaction Vessel (9 Nos.) 15 Single Stage Alkali Scrubber Two Stage Alkali Scrubber HBR Bromine 30 mg/nm 3 02 mg/nm 3 NOTE: We will remove single stage alkali scrubber after obtaining Environment Clearance. Fuel Consumption details: Sr. No. Fuel Quantity (SCM/Month) Existing Proposed Total 1. Natural Gas

27 Enclosure-11 DETAILS OF HAZARDOUS WASTES GENERATION AND ITS MANAGEMENT No Type of waste Category 1 ETP Waste, Used oil Discarded Barrels Liners Discarded Drums/Barrels Spent Acid D2-sch-II Quantity Existing Proposed Total 0.4 MT/Month 10 Lit/Year Nos./Month 11 KL/Month 5 Spent Charcoal MT/Month 15 Lit/Year 450 Nos./Month 350 Nos./Month 104 KL/Month MT/Month 1.2 MT/Month 25 Lit/Year 450 Nos./Month 360 Nos./Month 115 KL/Month MT/Month Management Collection, Storage, Transportation, Disposal at TSDF approves by Board. Collection, Storage, Transportation, Disposal by selling to Registered reprocessor. Collection, Storage, Transportation, Disposal by selling to authorized recycler. Collection, Storage, Transportation, Disposal at NOVEL Collection, Storage, Transportation, Disposal at TSDF site.

28 Enclosure 12 LIST OF PARTNERS Sr.No NAME OF PARTNER ADDRESS 1. Mr. Ajaybhai Mukundbhai Parikh 2. Mr. Sureshbhai Pragjibhai Mangrolia(Patel) 3. Mr. Vasantbhai Ravjibhai Mangrolia 12,A-Vijay Colony, Nr. Sardar Patel Colony, Naranpura Ahmedabad Ph.No.:(R): Mo.No.: ,Sardar Patel Co.Op.Soc.Ltd. P.O. Thakkar Bapanagar, Nikolgam Road, B/h. Sardar Mall, Ahmedabad Ph.No.:(R): Mo. No.: ,Sardar Patel Co.Op.Soc.Ltd. P.O. Thakkar Bapanagar, Nikolgam Road, B/h. Sardar Mall, Ahmedabad Ph.No.:(R): Mo.No.: Mr. Bhanubhai Jinabhai Kothiya 7,Shahi Kutir Bunglows, Nr. Sardar Patel Ring Road, M.G. Road, Nikol, Ahmedabad Mo.No.:

29 Enclosure 13 Land Supporting Document

30 Enclosure 14 Site Plane & Plane Layout

31 Enclosure 15 CA Certificate

32 Enclosure 16 CETP & NOVEL Membership Certificate

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35 Enclosure: 17 SSI Certificate

36 Enclosure 18 Existing Consent Copy

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