MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET 1 PRODUCT AND COMPANY IDENTIFICATION Product Name: Metallic Friction Material No copper Product No.: BX850, BX 860, 317 Suppliers Name: BCVS / BSFB 901 Cleveland Street Elyria, Ohio Emergency Telephone: Non-emergency Telephone: Intended Use: Lining Friction Material, Drum Brake Contact Person: HSE Leader HAZARDS IDENTIFICATION Emergency Overview Physical State: Solid (brake product) Color: Brownish Grey Odor: Resin Low hazard for usual industrial or commercial handling by trained personnel. Dust can be created by the machining of finished products. Contains crystalline silica. May cause cancer. Potential Health Effects Inhalation: The ingredients may be released as general dust from the product by operations such as overheating, burning, machining, abrading, or riveting. Dust may irritate respiratory system. Inhalation may lead to deposition in lung and in sufficient quantities produce baritosis. Eye Contact: Dust in the eyes: discomfort. Exposed individuals may experience eye tearing, redness, and Skin Contact: The ingredients may be released as general dust from the product by operations such as overheating, burning, machining, abrading, or riveting. Dust may irritate skin. Ingestion: The ingredients may be released as general dust from the product by operations such as overheating, burning, machining, abrading, or riveting. May cause discomfort if swallowed. Chronic Health Effects: May cause lung damage. Contains crystalline silica. May cause cancer. V#909112/ / 8

2 Target Organ(s): Lung Potential Physical / Chemical Effects: This product is not flammable or combustible. OSHA Regulatory Status: This product is hazardous according to OSHA 29CFR Environment: The product components are not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. 3 COMPOSITION / INFORMATION ON INGREDIENTS General Information: This product contains a variety of ingredients all of which have become part of a bound system both physically and chemically and do not necessarily exhibit the properties of the individual components. The ingredients may be released as general dust from the product by operations such as overheating, burning, machining, abrading, or riveting. Chemical Name CAS-No. Concentration* Acrylic Fibers > 1% Aluminium oxide, Unfused > 1% Barium sulphate > 1% Calcined petroleum coke > 1% Calcium hydroxide > 1% Magnesium oxide > 1% Poly (p-phenylenediamine terephthalamide) > 1% Synthetic graphite > 1% Crystalline silica % This chemical is hazardous according to OSHA/WHMIS criteria. 4 FIRST AID MEASURES Inhalation: Move injured person into fresh air and keep person calm under observation. seek hospital and take along these instructions. Get medical attention if symptoms persist. If necessary, Eye Contact: Flush thoroughly with water for at least 15 minutes. Dust in the eyes: Make sure to remove any contact lenses from the eyes before rinsing. Get medical attention if irritation persists after washing. Skin Contact: Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention if irritation develops and persists. Ingestion: If swallowed, rinse mouth with water (only if the person is conscious). Get medical attention if any discomfort continues. 5 FIRE-FIGHTING MEASURES Extinguishing Media: This product is not flammable. Use fire-extinguishing media appropriate for surrounding materials. V#909112/ / 8

3 Unsuitable Extinguishing Media: Special Fire Fighting Procedures: other involved materials. Unusual Fire & Explosion Hazards: be formed. Hazardous Combustion Products: None. Use standard firefighting procedures and consider the hazards of The product is non-combustible. If heated, toxic vapors may Calcium oxides, Sulfur Oxides Protective Measures: Selection of respiratory protection for fire fighting: follow the general fire precautions indicated in the workplace. Flammability Class: Dust: NFPA Rating Fire = 1. Materials that must be preheated before ignition can occur. 6 ACCIDENTAL RELEASE MEASURES Personal Precautions: Use explosion-proof electrical equipment if airborne dust levels are high. Avoid dust formation. Avoid inhalation of dust and contact with skin and eyes. Wear necessary protective equipment. See Section 8 of the MSDS for Personal Protective Equipment. Spill Cleanup Methods: Collect powder using special dust vacuum cleaner with particle filter or carefully sweep into closed container. Do not vacuum clean unless vacuum cleaners are equipped with HEPA filter. For waste disposal, see section 13 of the MSDS. Environmental Precautions: Do not discharge into drains, water courses or onto the ground. Collect and dispose of spillage as indicated in section 13 of the MSDS. Notification Procedures: In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. 7 HANDLING AND STORAGE Handling: Should be handled in closed systems, if possible. Avoid dust formation. Avoid inhalation of dust and contact with skin and eyes. Use work methods which minimize dust production. See Section 8 of the MSDS for Personal Protective Equipment. Observe good industrial hygiene practices. Storage: Store in tightly closed original container. Avoid conditions which create dust. Protect against direct sunlight. Store away from incompatible materials. 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Limits: Chemical Name Source Type Exposure Limits Notes Aluminium oxide, Unfused US. OSHA Z-1 PEL TWA 5 mg/m³ (Respirable Barium sulphate US. ACGIH TLV TWA 10 mg/m³ Barium sulphate (Respirable US. OSHA Z-1 PEL TWA 5 mg/m³ V#909112/ / 8

4 Calcined petroleum coke US. ACGIH TLV TWA 3 mg/m³ (Respirable Calcined petroleum coke (Total US. ACGIH TLV TWA 10 mg/m³ dust.) Calcined petroleum coke (Total US. OSHA Z-1 PEL TWA 15 mg/m³ dust.) Calcined petroleum coke US. OSHA Z-1 PEL TWA 5 mg/m³ (Respirable Calcium hydroxide US. ACGIH TLV TWA 5 mg/m³ Calcium hydroxide (Respirable US. OSHA Z-1 PEL TWA 5 mg/m³ Crystalline silica (Respirable US. ACGIH TLV TWA 0.1 mg/m³ as quartz Magnesium oxide (Inhalable US. ACGIH TLV TWA 10 mg/m³ Magnesium oxide US. NIOSH Guide IDLH 750 mg/m³ Magnesium oxide (Total US. OSHA Z-1 PEL TWA 15 mg/m³ particulate.) Synthetic graphite (Respirable US. ACGIH TLV TWA 2 mg/m³ Synthetic graphite (Respirable US. OSHA Z-1 PEL TWA 5 mg/m³ Synthetic graphite (Total dust.) US. OSHA Z-1 PEL TWA 15 mg/m³ Consult Canadian Provincial Regulations and/or Mexican Regulations on exposure limits, if applicable. Engineering Controls: Use explosion-proof electrical equipment if airborne dust levels are high. Should be handled in closed systems, if possible. Observe occupational exposure limits and minimize the risk of inhalation of dust. Respiratory Protection: During dust-raising work: In the United States of America, if respirators are used, a program should be instituted to assure compliance with OSHA Standard 63 FR 1152, January 8, Respirator type: Air-purifying respirator with a high efficiency particulate filter. Eye Protection: Wear approved safety goggles. Hand Protection: Gloves are recommended for prolonged use. Suitable gloves can be recommended by the glove supplier. Skin Protection: Wear suitable protective clothing. Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Observe any medical surveillance requirements. Environmental Exposure Controls: Environmental manager must be informed of all major spillages. 9 PHYSICAL AND CHEMICAL PROPERTIES Color: Brownish Grey Odor: Resin Odor Threshold: No data available. Physical State: Solid (brake product) V#909112/ / 8

5 ph: No data available Melting Point: No data available. Freezing Point: Not applicable. Boiling Point: No data available. Flash Point: No data available. Evaporation Rate: No data available. Flammability Limit - Upper (%): No data available. Flammability Limit - Lower (%): No data available. Vapor Pressure: No data available. Vapor Density (Air=1): No data available. Specific Gravity: 3-4 (20 C) Solubility in Water: No data available. Solubility (Other): No data available. Partition Coefficient (n-octanol/water): No data available. Autoignition Temperature: No data available. Decomposition Temperature: No data available. Volatile Organic Compounds (VOC): Not applicable. Viscosity: Not applicable. 10 STABILITY AND REACTIVITY Stability: Material is stable under normal conditions. Conditions to Avoid: None known. Incompatible Materials: Acids. Hazardous Decomposition Products: At Elevated Temperatures: Calcium oxides, Sulfur Oxides Possibility of Hazardous Reactions: Will not occur. 11 TOXICOLOGICAL INFORMATION Specified Substance(s) Acute Toxicity: Chemical Name Test Results Aluminium oxide, Unfused Intraperitoneal LD50 (Mouse): >3600 mg/kg Calcium hydroxide Oral LD50 (Rat): 7340 mg/kg Listed Carcinogens: Chemical Name IARC NTP OSHA ACGIH Magnesium oxide Not Listed Not Listed Not Listed A4 Crystalline silica 1 Listed Not Listed Not Listed Poly (p-phenylenediamine terephthalamide) 3 Not Listed Not Listed Not Listed IARC: 1 = Carcinogenic to Humans; 2A = Probably Carcinogenic to Humans; 2B = Possibly Carcinogenic to Humans; 3 = Not classifiable as to carcinogenicity to humans; 4 = Probably not carcinogenic to humans; Not listed = Not evaluated by IARC. ACGIH: A1 = Confirmed Human Carcinogen; A2 = Suspected Human Carcinogen; A3 = Confirmed Animal Carcinogen; A4 = Not classifiable as a human carcinogen; A5 = Not suspected to be a human carcinogen; Not listed = Not evaluated by V#909112/ / 8

6 ACGIH. Product Information Acute Toxicity: Test Results: No test data available for the product. Other Acute: The ingredients may be released as general dust from the product by operations such as overheating, burning, machining, abrading, or riveting. Dusts may irritate the respiratory tract, skin and eyes. Inhalation may lead to deposition in lung and in sufficient quantities produce baritosis. Chronic Toxicity: May cause lung damage. Contains crystalline silica. May cause cancer. 12 ECOLOGICAL INFORMATION Ecotoxicity: The product components are not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Specified Substance(s) Chemical Name Calcium hydroxide Test LC50 (96 hour(s), Fish): 33.9 mg/l Mobility: The product is insoluble in water and will sediment in water systems. Persistence and Degradability: No data available. Bioaccumulation Potential: No data available. Other Adverse Effects: No data available. 13 DISPOSAL CONSIDERATIONS General Information: Dispose of waste and residues in accordance with local authority requirements. Disposal Methods: Disposal recommendations are based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. Container: Since emptied containers retain product residue, follow label warnings even after container is emptied. 14 TRANSPORT INFORMATION DOT TDG IATA IMDG V#909112/ / 8

7 15 REGULATORY INFORMATION Canadian Controlled Products Regulations: This product has been classified according to the hazard criteria of the Canadian Controlled Products Regulations, Section 33, and the MSDS contains all required information. WHMIS Classification: D2A Mexican Dangerous Statement: This product is dangerous according to Mexican regulations. US Regulations CERCLA Hazardous Substance List (40 CFR 302.4): Chemical Name Barium sulphate RQ 1000 lbs SARA Title III Section 302 Extremely Hazardous Substances (40 CFR 355, Appendix A): Section 311/312 (40 CFR 370): Acute (Immediate) X Chronic (Delayed) Fire Reactive Pressure Generating Section 313 Toxic Release Inventory (40 CFR 372): Chemical Name CAS-No. Reporting threshold for other users Reporting threshold for manufacturing and processing Aluminium oxide, Unfused lbs lbs For reporting purposes: the De Minimis Concentration for a toxic chemical in a mixture is 0.1% for carcinogens as defined in 29 CFR (d)(4) or 1% for others. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ): Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3): Drug Enforcement Act: TSCA TSCA Section 4(a) Final Test Rules & Testing Consent Orders: TSCA Section 5(a)(2) Final Significant New Use Rules (SNURs) (40CFR 721, Subpt. E): regulated. Not TSCA Section 5(e) PMN-Substance Consent Orders: TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D): State Regulations California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): Crystalline V#909112/ / 8

8 silica Massachusetts Right-To-Know List: Aluminium oxide, Unfused; Barium sulphate; Calcium hydroxide; Magnesium oxide; Synthetic graphite Michigan Critical Materials List (Michigan Natural Resources and Environmental Protection Act (Act. 451 of 1994)): Minnesota Hazardous Substances List: Aluminium oxide, Unfused; Barium sulphate; Calcium hydroxide; Magnesium oxide; Synthetic graphite New Jersey Right-To-Know List: Magnesium oxide Aluminium oxide, Unfused; Barium sulphate; Calcium hydroxide; Pennsylvania Right-To-Know List: Aluminium oxide, Unfused; Barium sulphate; Calcium hydroxide; Magnesium oxide; Synthetic graphite Rhode Island Right-To-Know List: oxide; Synthetic graphite Aluminium oxide, Unfused; Calcium hydroxide; Magnesium 16 OTHER INFORMATION HAZARD RATINGS Health Hazard Fire Hazard Instability Special Hazard NFPA Hazard rating: 0 - Minimal; 1 - Slight; 2 - Moderate; 3 - Serious; 4 - Severe NFPA Label colored diamond code: Blue - Health; Red - Flammability; Yellow - Instability; White - Special Hazards Health Hazard Flammability Physical Hazard Personal Protection HMIS 1* 1 0 NONE Hazard rating: 0 - Minimal; 1 - Slight; 2 - Moderate; 3 - Serious; 4 - Severe *- Chronic Health Effect HMIS Label colored bar code: Blue - Health; Red - Flammability; Orange - Physical Hazards; White - Special Issue Date: 16-Oct-2011 Supercedes Date: 12-Oct-2011 SDS No.: #317_NA Revision: May 1, Description changed to Metallic Friction Material No copper Reviewed: May 1, 2015 Reviewed by: M. Wincek Disclaimer: The information provided on this data sheet was abstracted from supplier material safety data sheets and standard references in occupational health and toxicology. The manufacturer makes no representation or warranty with respect to the information obtained from such references. The information is however, as of the date provided, true and accurate to the best of the manufacturer s knowledge, and should be used to make an independent determination of the methods to safeguard workers and the environment. V#909112/ / 8