4-2-5 Examples of chemical substances which constitute a group of substances

Transcription

1 4-2-5 Examples of chemical s which constitute a group of s Refer to the following table to see into what kind of individual metallic elements, etc. should s be converted. Number in Name of CAS No. Example of individual Composition formula Molecular weight Total of atomic weights Conversion coefficient M/ Not applecable Reason why it is not applicable Other Cabinet of metals molecular water Order and the weight solubility or 1 Zinc (water-solub le) 25 Antimony and its 60 Cadmium and its Zinc chloride Zinc acetate (anhydrite) Zinc acetate (2 hydride) Zinc nitrate (6 hydrate) Zinc sulfate (7 hydrate) like ZnCl Zn(CH 3 CO O) 2 Zn(CH 3 CO O) 2 2H 2 O Zn(NO 3 ) 2 6H 2 O ZnSO 4 7H 2 O the like Zinc chromtate ZnCrO Refractory Subject as chrometes Zinc oxide ZnO Insoluble Zinc cyanide Zn(CN) Zinc stearate [CH 3 (CH 2 ) 16 COO] 2 Zn g/l Insoluble Zinc sulfide ZnS Zinc phosphate Zn 3 (PO 4 ) Almost insoluble (K sp = ) Antimony Sb Antimony chloride Antimony pentoxide Antimony (III) oxide Antimony potassium tartrage SbCl Sb 2 O Sb 2 O C 4 H 4 KO 7 Sb 0.5H 2 O Stibine SbH Cadmium Cd Cadmium chloride (anhydride) Cadmium chloride (1 hydrate) CdCl CdCl 2 H 2 O g/l Subject as inorganic syanides III - 218

2 Number in Name of CAS No. Example of individual Composition formula Molecular weight Total of atomic weights Conversion coefficient M/ Not applecable Reason why it is not applicable Other Cabinet of metals molecular water Order and the weight solubility or 64 Silver and its water-solubl e compunds 68 Chromium and chromium (III) compunds 69 Chromium (IV) compuonds Cadmium nitrate (anhydride) Cadmium nitrate (4 hydrate) Cadmium sulfide Cadmium sulfate (anhydrate) Cadmium sulfate (8/3 hydrate) like Cd(NO 3 ) Cd(NO 3 ) 2 4H 2 O CdS CdSO CdSO 4 8/3H 2 O Silver Ag Silver chlorate (I) Silver nitrate (I) Silver chloride (I) Silver (I) oxide Silver cyanide (I) Silver sulfate (I) AgClO AgNO the like AgCl mg /100mL Ag 2 O g/L AgCN g/l Ag 2 SO % Chromium Cr Chromium oxide (III) Chromium subsulfate (III) Zinc chromate Potassium chromate Calcium chromate (2 hydrate) Strontium chromate Lead chromate Cr 2 O Cr(OH) (SO 4 ) Subject as inorganic syanides ZnCrO Out of object as zinc since this is not wate-solu ble K 2 CrO CaCrO 4 2H 2 O SrCrO PbCrO Object as lead III - 219

3 Number in Name of CAS No. Example of individual Composition formula Molecular weight Total of atomic weights Conversion coefficient M/ Not applecable Reason why it is not applicable Other Cabinet of metals molecular water Order and the weight solubility or 100 Cobalt and its 108 Inorganic cyanide (except complex salts and cyanates) 108 Inorganic cyanide (except complex salts and cyanates) Barium chromate Chromium trioxide Potassium dichromate Sodium dichromate (2 hydrate) like the like BaCrO Out of object as barium since this is not wate-solu ble CrO K 2 Cr 2 O Na 2 Cr 2 O 7 2H 2 O Cobalt Co Cobalt acetate (II) (4 hydrate) Tricobalt tetraoxide Cabalt (II) oxide Cobalt nitrate (II) (6 hydrate) Cobalt carbonate (II) Cobalt sulfate (II) (7 hydrate) Hydrogen cyanide Co(CH 3 CO O) 2 4H 2 O Co 3 O CoO Co(NO 3 ) 2 6H 2 O CoCO CoSO 4 7H 2 O HCN Zinc cyanide Zn(CN) Out of object as zinc since this is not wate-solu ble Potassium cyanide KCN Silver cyanide (I) AgCN Out of object as silver since this is not wate-solu ble III - 220

4 Number in Cabinet Order Name of 175 Mercury and its 176 Organic tin 178 Selenium and its CAS No. Example of individual Copper cyanide (I) Sodium cyanide Acetone cyanohydrin Ethylene cyanohydrin Calcium cyanamide Socium cyanate Composition Molecular formula weight Total of Conversion atomic coefficient weights M/ of metals molecular and the weight like Not applecable Reason why it is not applicable water solubility or the like Other CuCN Out of object as copper since this is not wate-solu ble NaCN (CH 3 ) 2 C (OH)CN 85.1 Organic cyanides C 3 H 5 NO 71.1 Organic cyanides CaNCN 80.1 Organic cyanides NaOCN 65.0 cyanates Mercury Hg Mercury chloride (II) Marcury acetate (II) Mercury oxide (II) Mercury bromide (II) Dibutyl tin oxide Tetrametyl tin Tributyl tin chloride Monobutyl tin hydroxydr oxide HgCl Hg(CH 3 CO O) 2 HgO HgBr (C 4 H 9 ) 2 SnO (CH 3 ) 4 Sn (C 4 H 9 ) 3 SnCl C 4 H 9 Sn(OH) O Selenium Se Selenium dioxide Hydrogen selenide SeO SeH Selenic acid H 2 SeO Selenious acid H 2 SeO Copper salts (water-solub le, except Copper chloride (II) (anhydride) CuCl III - 221

5 Number in Cabinet Order Name of complex salts) 207 Copper salts (water-solub le, except complex salts) 230 Lead and its CAS No. Example of individual Copper chloride (II) (2 hydrate) Copper fluoborate (II) Copper sulfate (II) (anhydride) Copper sulfate (II) (5 hydrate ) Copper cyanide (I) Copper carbonate hydroxide Copper thiocyanate (I) Composition Molecular formula weight CuCl 2 2H 2 O Total of Conversion atomic coefficient weights M/ of metals molecular and the weight like Not applecable Reason why it is not applicable water solubility or the like Other Cu(BF 4 ) Object as boron. Out of object as hydrogen salts since this is not wate-solu ble CuSO CuSO 4 5H 2 O CuCN g/l (18 ) Cu 2 (OH) 2 C Insoluble O 3 CuSCN g/l (18) Object as inorganic scyanides Oxine copper C 18 H 12 CuN 2 O insoluble Object as oxine copper class 1: Lead Pb Lead chromate (II) Lead acetate (II) (anhydride) Lead acetate (II) (3 hydrate) Trilead tetraoxide Plumbous oxide Lead cyanamide PbCrO Object as chromates Pb(CH 3 CO O) 2 Pb(CH 3 CO O) 2 3H 2 O Pb 3 O PbO PbCN III - 222

6 Number in Name of CAS No. Example of individual Composition formula Molecular weight Total of atomic weights Conversion coefficient M/ Not applecable Reason why it is not applicable Other Cabinet of metals molecular water Order and the weight solubility or Lead zirconate titanate Tetramethyl lead Lead phosphate (II) Pb(Ti,Zr) O 3 (Calculate d as PbTiO 3 ) like Pb(CH 3 ) Pb 3 (PO 4 ) Nickel Nickel Ni Nickel 243 Barium and its water-solubl e Nickel acetate (4 hydrate) Nickel (II) oxide Nickel (III) oxide Nickel nitrate (II) (anhydride) Nickel nitrate (II) (6 hydrate) Nickel carbonate (II) (anhydride) Nickel sulfate (II) (7 hydrate) Nickel phosphate (II) Ni(CH 3 CO O) 2 4H 2 O NiO Ni 2 O Ni(NO 3 ) Ni(NO 3 ) 2 6H 2 O NiCO NiSO 4 7H 2 O Ni 3 (PO 4 ) Barium Ba Barium chloride (anhydride) Barium chloride (2 hydrate) Barium nitrate Barium hydroxide Barium hydroxide (8 hydrate) Barium chromate Barium peroxide BaCl BaCl 2 2H 2 O Ba(NO 3 ) Ba(OH) Ba(OH) 2 8H 2 O the like BaCrO g/l BaO g /100g Object as chromates III - 223

7 Number in Cabinet Order Name of 252 Arsenic and its inorganic 283 Hydorogen and its water-solubl e salts CAS No. Example of individual Barium Barium sulfate Composition Molecular Total of Conversion formula weight atomic weights of metals and the like coefficient M/ molecular weight Not applecable Reason why Other it is not applicable water solubility or the like BaF g/L (25) Out of object as hydrogen salts since this is not wate-solu ble BaSO mg/L Arsenic As Arsine AsH Arsenic As 2 O pentoxide Arsenic trioxide As 2 O Arsenic acid H 3 AsO Hydrogen HF Tungsten WF hexa Ammonium NH 4 F Sodium NaF Beryllium Silicofluoric acid Sodium silico Nitrogen tri Boron tri Aluminum Barium BeF Subject as beryllium H 2 SiF Not salt of hydrogen Na 2 SiF NF BF Not salt of Subject hydrogen as boron AlF g in 100mL BaF g/L Out of (25) subject as barium since this is not water-sol uble. III - 224

8 Number in Cabinet Order Name of 294 Beryllium and its compunds CAS No. Example of Composition Molecular Total of Conversion individual formula weight atomic weights of metals and the like coefficient M/ molecular weight Not applecable Reason why it is not applicable water solubility or the like Fluorine F Not salt of hydrogen Potassium KBF Not salt of fluoborate hydrogen Fluoboric HBF acid Tin Sn(BF 4 ) fluoborate (II) Copper Cu(BF 4 ) Not salt of fluoborate hydrogen (II) Sodium NaBF Not salt of fluoborate hydrogen Sodium NaFO Not salt of fluoborate hydrogen Sulfur SF hexa Beryllium Be Beryllium BeO oxide Other Subject as boron Subject as boron and copper Subject as boron 304 Boron and its 304 Boron and its Beryllium BeF Subject as hydoroge n salts Boron B Boric oxide B 2 O Boron tri BF Out of subject as hydrogen salts since this is not salt of hydrogen Boric acid H 3 BO Sodium perborate Sodium perborate (1 hydrate) Sodium perborate (4 hydrate) Ammonium pentaborate NaBO NaBO 3 H 2 O NaBO 3 4H 2 O III NH 4 B 5 O

9 Number in Cabinet Order Name of 311 Manganse and its 346 Molybdenum and its CAS No. Example of individual Sodium tetraborate Sodium tetraborate (10 hydrate) Potassium fluoborate Fluoborate acid Tin fluoborate (II) Copper fluoborate (II) Composition Molecular formula weight III Total of Conversion atomic coefficient weights M/ of metals molecular and the weight like Na 2 B 4 O Na 2 B 4 O 7 10H 2 O KBF HBF Sn(BF 4 ) Cu(BF 4 ) Sodium fluoborate NaBF Manganse Mn Manganous MnCl 2 4H 2 O chloride (II) (4 hydrate) Potassium KMnO permanganate Manganse Mn(CH 3 COO (II) acetate ) Manganse Mn(CH 3 COO (II) acetate ) 2 4H 2 O (4 hydrate) Manganse dioxide Manganse nitrate (II) Manganse carbonate (II) Manganse sulfate (II) (7 hydrate) Manganse phosphate MnO Mn(NO 3 ) MnCO MnSO 4 7H 2 O MnxPO4 (Calculated as Mn 3 (PO 4 ) Molybdenum Mo Molybudenum MoO trioxide Ammonium molybdate (NH 4 ) 6 Mo 7 O Sodium Na 2 MoO molybdate Not applecable Reason why it is not applicable water solubility or the like "Water soluble" means that mass percentage of 1 % or more is dissolved in chemically neutral water (10g/L) at an ordinary temperature. Other Out of subject as hydrogen salts since this is not salt of hydrogen

10 4-2-6 Table of physical properties of s Refer to the following table that lists physical properties to make engineering calculations or judge to which medium, air or water, larger quantity is released. III - 227

11 III - 228

12 III - 229

13 III - 230

14 III - 231

15 III - 232

16 III - 233

17 III - 234

18 III - 235

19 III - 236

20 III - 237

21 III - 238

22 III - 239

23 III - 240

24 III - 241

25 III - 242

26 III - 243

27 III - 244

28 Note) Henry s constant is calculated value at temperture of 25 degree. (Henry s constant (Pam 3 /mol)=vapor pressure(pa)(water solubility (g/m 3 )molecular weight(g/mol))) Ssolid at ordinary temperature,lliquid at ordinary temperature,ggas at ordinary temperature III - 245