Japanese Iron and Steel Certified Reference Materials April 9, 2012

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1 I. CRMs for Chemical Analysis Japanese Iron and Steel Certified Reference Materials April 9, 2012 I-1. Pure iron series Mass content in % C Si Mn P S Ni Cr Mo Cu Co Al As Sn B N Na X High grade pure iron High grade pure iron (<0.0003) (<0.0001) ( ) (0.0006) Pure iron (III) oxide (0.02) (<0.004) ( ) (<0.0002) (0.0001) ( ) (<0.0001) (<0.0001) (0.0003) (<0.0001) (<0.0002) (<0.0001) Continued Mass content in % Mg Ca W V Ti Pb Zn Zr Se Te Sb Nb Bi K T.Fe X High grade pure iron High grade pure iron 3 (<0.0001) (<0.0001) (<0.0002) (< ) (< ) (<0.0001) (< ) (<0.0001) (< ) (< ) (< ) (< ) Pure iron (III) oxide ( ) (<0.0001) (<0.0001) (<0.0001) (<0.0001) (<0.0002) (<0.0001) (<0.0002) Continued Mass content in % Cd Ce La Ta Net weight X High grade pure iron High grade pure iron 3 (<0.0001) (< ) (< ) (< ) Pure iron (III) oxide C.W.: 0.16 Ig.Loss: (0.4) 50 I-2. Carbon steel series Mass content in % C Si Mn P S Cu Al N Net weight Carbon steel Carbon steel Carbon steel Carbon steel Carbon steel Carbon steel Carbon steel

2 I-3. Pig iron series Mass content in % C Si Mn P S Ni Cr Mo Cu V Ti As N Net weight Pig iron for steel making X Pig iron for casting Castiron: 3 C (0.007) *(This value means the carbon content in the metal with removal of contaminated carbon on the surface of test portion) ( ) Non-certified value In preparation New/Renewal CRMs X Sold out I-4. Low alloy steel series Mass content in % C Si Mn P S Ni Cr Mo Cu V Al Sol. Al Net weight Low alloy steel No (<0.003) Low alloy steel No Low alloy steel No Low alloy steel No Low alloy steel No Low alloy steel No I-5. Minor elements determination series B Mass content in % C Si Mn Ni Cr Mo V Co Ti Al Sol. Al As Sn B Zr Minor element No Minor element No X Minor element No.3 X Minor element No.4 X Minor element No.5 X Minor element No.6 X Minor element No Minor element No

3 Continued Mass content in % Sb Nb Ca Net weight Minor element No Minor element No X Minor element No.3 X Minor element No.4 X Minor element No.5 ( ) Non-certified value X Minor element No.6 In preparation X Minor element No.7 New/Renewal CRMs Minor element No X Sold out

4 I-6. One element determination series Mass content in % C Si P S Al B N O Net weight Steel for carbon Steel for carbon Steel for carbon Steel for carbon Steel for low carbon Steel for low carbon X Steel for low carbon X Steel for low carbon Steel for low carbon Steel for low carbon Steel for phosphorus X Steel for phosphorus X Steel for phosphorus Steel for sulfur Steel for sulfur Steel for sulfur Steel for sulfur Steel for sulfur Steel for sulfur Steel for carbon and sulfur Steel for silicon X Steel for aluminium X Steel for aluminium Steel for aluminium Steel for boron X Steel for boron Steel for boron Steel for nitrogen ( ) Non-certified value Steel for nitrogen In preparation Steel for nitrogen New/Renewal CRMs Steel for nitrogen X Sold out Steel for Oxygen (5mm dia. x 230mm x 8pcs: apprx. 300g) Steel for Oxygen (5mm dia. x 230mm x 8pcs: apprx. 300g) Steel for Oxygen (5mm dia. x 230mm x 8pcs: apprx. 300g) Steel for Oxygen (5mm dia. x 230mm x 8pcs: apprx. 300g) Steel for Oxygen (5mm dia. x 230mm x 8pcs: apprx. 300g)

5 I-7. High tensile structural steel series A Mass content in % C Si Mn P S Ni Cr Mo Cu V Ti Al N Net weight SCM SCM (0.004) I-8. High tensile structural steel series B Mass content in % C Si Mn P S Ni Cr Mo Cu Al N Net weight SCM (0.0079) I-9. Cace hardening steel series Mass content in % C Si Mn P S Ni Cr Mo Cu V Al N Pb Net weight S9CK (0.010) (0.001) (0.017) SCr (0.005) SCM SNCM (0.003) (0.006) X Lead free cutting steel I-10. Tool steel series Mass content in % C Si Mn P S Ni Cr Mo Cu W V N Net weight X SKS (0.0042) SKS SKD X SKT 4 I-11. High speed steel series Mass content in % C Si Mn P S Ni Cr Mo Cu W V Co N Net weight X SKH SKH SKH X SKH 51 ( ) Non-certified value In preparation New/Renewal CRMs X Sold out

6 I-12. Stainless steel series Mass content in % C Si Mn P S Ni Cr Mo Cu Co Al N V Net weight SUS (0.0013) SUS SUS 316 X SUS 309S SUS 310S X SUS 347 I-13. Heat resisting steel series Mass content in % C Si Mn P S Ni Cr Mo Cu Ti Al N Net weight SUH (0.0005) (0.055) I-14. Heat resisting super alloy series Mass content in % C Si Mn P S Ni Cr Cu Co Ti Al Fe Mg Net weight X NCF 2 X NCF 1 I-15. Ferroalloy series Mass content in % C Si Mn P S Ni Cr Mo Cu V Co Al Sn Ta Nb Net weight High carbon ferromanganese 6.94 (0.03) (0.002) 150 X Silicon manganese X Ferrosilicon X High carbon ferro chromium X Low carbon ferromolybdenum X Ferro vanadium X Ferro niobium Ferro nickel ( ) Non-certified value In preparation New/Renewal CRMs X Sold out

7 I-16. Iron ore series Mass content in % CW T.Fe FeO SiO2 Mn P S Cu TiO2 Al2O3 CaO MgO BaO As Ni Cr [Fe2+] [Si] [Ti] [Al] [Ca] [Mg] Indian hematite (0.002) (0.005) (1.0) (0.014) (0.032) Iscor hematite (0.29) [1.17] [0.023] [0.51] [0.0490] [0.0099] MBR hematite [0.552] [0.0409] [0.565] [0.0071] [0.0221] Australian Hematite [0.15] [1.55] [0.044] [0.96] [0.0197] [0.034] X Pure magnetite X Robe river limonite Taharoa iron sand (0.11) [21.82] [1.93] [4.51] [1.97] [1.05] [2.09] Marcona pellet (0.07) (0.30) (0.006) (0.003) [1.93] [0.033] [0.21] [0.30] [0.48] Sintered ore (0.04) [5.99] [2.48] [0.065] [0.89] [7.94] [0.48] X Savage river pellet X Algarrobo pellet

8 Continued Mass content in % V Pb Zn Na2O K2O Net weight [Na] [K] Indian hematite (0.003) Iscor hematite MBR hematite [0.0026] [0.012] Australian Hematite [0.0115] [0.0091] X Pure magnetite X Robe river limonite Taharoa iron sand [0.082] [0.061] Marcona pellet (0.007) [0.095] [0.062] Sintered ore X Savage river pellet X Algarrobo pellet I-17. Ore series Mass content in % Mn O (Active) Cr2O3 CW Fe SiO2 P S Al2O3 Ca MgO Cu Si Al Net weight Manganese ore (3.3) (5.7) X Chromium ore I-18. Fluorspar series Mass content in % CaF2 SiO2 CaCO3 P S As Net weight ( ) Non-certified value [ ] Metallic form X The people's republic of China In preparation New/Renewal CRMs X Sold out

9 I-19. Blast Furnace slag series Mass content in % SiO2 Al2O3 CaO MgO TiO2 MnO T.Fe P S Na K Ni Cr Cl Net weight Blast furnace slag II. CRMs for Instrumental Analysis II-1. Carbon steel series Mass content in % C Si Mn P S Ni Cr Cu Size X Carbon steel X Carbon steel X Carbon steel X Carbon steel X Carbon steel X Carbon steel II-2. Low alloy steel series Mass content in % C Si Mn P S Ni Cr Mo Cu V Size X Low alloy stee 1 X Low alloy stee 2 X Low alloy stee 3 X Low alloy stee 4 X Low alloy stee 5 X Low alloy stee 6 II-3. Case hardening steel series Mass content in % C Si Mn P S Ni Cr Mo Cu V Al Size X S9CK X SCr415 X SCM420 X SNC415 X SNCM24 ( ) Non-certified value X SNCM616 In preparation New/Renewal CRMs X Sold out

10 II-4. Tool steel series Mass content in % C Si Mn P S Ni Cr Mo Cu W V Size ( ) Non-certified value In preparation X SKS 3 New/Renewal CRMs X SKS 2 X Sold out X SKS 11 X SKD 4 X SKD 6 X SKT 4 II-5. High speed steel series Mass content in % C Si Mn P S Ni Cr Mo Cu W V Co N Size X SKH 2 X SKH 3 X SKH 4A X SKH 55 X SKH 57 X SKH 9 II-6. Stainless steel series Mass content in % C Si Mn P S Ni Cr Mo Cu Co Nb Size X SUS 430 X SUS 304 X SUS 316 X SUS 309S X SUS 310S X SUS 347 II-7. High Grade Pure Iron Disc Size: 32mm φx 25mm Mass content in μg/g C Si Mn P S Ni Cr Mo Cu Co Al Sn W B N As Pure iron 4.6* * 0.4 (1) (0.2) 7.8 (<2) Continued Mass content in % Bi Ca Cd Ce La Mg Nb Pb Sb Se Ta Te Ti V Zn Zr Pure iron (<0.1) (<3) (<0.1) (<0.1) (<0.1) (<0.3) (<0.5) (<0.1) (<0.2) (<1) (<0.1) (<0.5) (<1) (<0.3) (<0.5) (<0.2) *) This value means the carbon content in the metal with removal of contaminated carbon on the surface of test portion

11 III. Setting-up sample for determination of gaseous elements in steel Mass content in (μg/g) O N H Size (Uncertified) (Uncertified) GS-7a 6.0 (5mm dia. x 230mm x 8pcs: apprx. 280g) III. Steel sample of isolation and determination of nonmetallic inclusion III-1. Carbide isolation series Mass content in % Ti Fe Cr Mn Mo Size 221-1b M3C φx 50mm 222-1a (Cr, Fe)23C6 (0.20) φx 70mm 222-1b (Cr, Fe)23C6 (0.20) φx 70mm III-2. Sulfide isolation series Mass content in % S Size MnS φx 60mm MnS φx 60mm TiS φx 55mm ( ) Non-certified value Zr3S φx 55mm In preparation CaS φx 60mm New/Renewal CRMs CeS, MnS φx 60mm X Sold out