FLAME RETARDANTS. Brominated Flame Retardants. Phosphorus Flame Retardants. Magnesium Flame Retardants. Nitrogen Flame Retardants. Mg

Size: px
Start display at page:

Download "FLAME RETARDANTS. Brominated Flame Retardants. Phosphorus Flame Retardants. Magnesium Flame Retardants. Nitrogen Flame Retardants. Mg"

Transcription

1 FLAME RETARDANTS P Mg N ominated Flame Retardants Phosphorus Flame Retardants Magnesium Flame Retardants Nitrogen Flame Retardants

2 Caring For Your Future Today ICL INDUSTRIAL PRDUCTS Manufacturing products to enhance safety and human well-being, ICL Industrial Products (ICL IP), the industrial chemicals sector of Israel Chemicals Limited (ICL), is the world s largest producer of elemental bromine, and a leader in the production and marketing of bromine and bromine compounds, supplying over 33% of global demand. ICL-IP also has a leading position in the manufacturing of phosphorus based compounds for fire safety. Resources and Quality The Dead Sea has the world s highest concentration of bromine and supply is virtually unlimited. These rich natural resources combined with the most sophisticated workforce, enable ICL IP to produce bromine, bromine based chemicals and minerals of the highest quality and in the most efficient way. Cutting-edge technology tamed by talented, knowledgeable and dedicated teams of individuals has inspired ICL-IP to integrate the complementary chemistry of phosphorus. It has resulted in diverse eco-friendly uses in industries such as flame retardants, plasticizers, hydraulic fluids, organic intermediates, water treatment and pharmaceutical chemicals, stabilizers, curing activators, viscosity enhancers, refractory materials, etc. Unique Customer Service ICL IP offers its customers the advantage of geographic proximity to major markets, internationally based subsidiaries coordinating the supply of finished products to the customer s doorstep, experienced technical backup, and a workforce fully committed to quality and protection of the environment. Global Production and Marketing Facilities ICL IP operates the world s largest elemental bromine production plant at the Dead Sea. The company s bromine compounds plants in Israel and the Netherlands, as well as Sinobrom, a JV in China, offer customer oriented manufacturing facilities based on their long standing technological expertise. ICL-IP is the industry leader in the manufacture, distribution and service of phosphorus based flame retardants, plasticizers, lubricants and hydraulic fluids, with production plants in the US, Germany and China in The company s worldwide marketing subsidiaries are: ICL-IP Europe B.V., The Netherlands; ICL-IP Israel Sales ffice; ICL-IP America Inc., USA; ICL-IP Japan Ltd., Japan; ICL Asia Ltd., Hong-Kong, ICL China, PR China and ICL asil, azil. Safety, Ecology and Quality Assurance Strict adherence to international regulations on safety and environmental issues are core policies at ICL- IP. ICL-IP s major plants have been granted IS and HSAS accreditations for Environmental and Safety Management Systems. ICL-IP utilizes Total Quality Management, Lean and Six Sigma methodologies across its plants worldwide to ensure consistent quality and to achieve improvements in its processes. ICL-IP supports the goals of the new EU regulation Registration, Evaluation, Authorization and Restriction of Chemicals (REACH Regulation, EC 1907/2006) which came into force on June 1st This regulation ensures the protection of human health and the environment, while minimizing animal testing and maintaining the competitiveness of the European chemical industry. ICL-IP will fully comply with the requirements of REACH, and all other regulatory systems world-wide, for all its existing and new flame retardants. ICL-IP is very active in the initiation and development of a programme to reduce waste production and environmental emissions through a code of good practice known as the Voluntary Emission Control Action Programme VECAP.

3 Dear customer! This brochure is designed as a working tool for your needs in flame retardancy. We, at the Flame Retardant Business Unit (FR BU) of ICL IP, offer the plastics industry the most effective Flame Retardants that help in enhancing consumer safety, while being committed to environmental concerns. We invite you to make use of this brochure, benefit from our wide range of Flame Retardant solutions and contact us for current activities and future developments. Response to needs of Markets and Industries The FR BU takes an in-depth view of the plastic industry s supply chain, so that its products and solutions are directly responsive to each market segment s special needs and challenges. We are continuously studying and monitoring the requirements and trends of these market segments, including their supporting industries. This enables us to offer a valuable contribution to our customers, in meeting their current needs and future requirements. Flame Retardants for most Applications Using the vast natural resource of omine and Minerals in the Dead Sea, ICL-IP produces a series of high quality Flame Retardant products, applicable to a wide range of plastics, polymers and polymer alloys. ICL-IP also offers the world s most comprehensive range of phosphorus-based flame retardants, fire resistant plasticizers and hydraulic fluids for high demanding applications. omine and Phosphorus based Flame Retardants are considered as the two most efficient FR families and in fact, they constitute approximately 55% (in value) of the total FR usage. ICL IP s portfolio also includes few additional Non-Halogen and Non-Phosphorus based FRs such as high purity grades of Magnesium Hydroxide and Melamine Cyanurate. Polyquel, and series As a part of the FR BU s focus on market needs, we have initiated a unique approach of developing tailor made solutions: Polyquel is a new fully active and dust-free polymeric flame retardant series, as a step forward to comply with the industry s most stringent environmental guidelines such as European REACH and US TSCA legislations. SaFRon series for high demanding thermoplastic and polyurethane foam applications. TexFRon series for high quality textile back coating applications. Polymeric Flame Retardants for Sustainability Polymeric flame retardants are sustainable products in the view of many national and international human health and environmental regulations. They have long been recognized as the safest and most elegant way to flame retard high molecular weight man made materials. Non leaching With their low solubility in water, polymeric flame retardants, once they are incorporated into the end-product plastic matrix, become integrated with the plastic and leaching is not expected to occur. Non bio-accumulative Their high molecular weight makes them unlikely to penetrate through the cell membranes of living tissue. Non-blooming Furthermore, they do not migrate to the surface of the plastic during aging, thus eliminating any potential blooming in the finished product. ICL-IP is promoting several ranges of brominated polymeric flame retardants for most applications: FR-1025: brominated polyacrylate F-2000 series: brominated epoxy polymers with a wide range of molecular weight F-3000 series: end-capped brominated epoxy polymers with various molecular weight FR-803P: brominated polystyrene

4 SELECTIN TABLE APPLICATINS BRMINATED FLAME RETARDANTS HIPS EPS / XPS ABS Polyethylene Polypropylene PBT / PET Nylon = Polyamide PC / PC ABS Alloys PVC / Flexible Rubbers / Elastomers Epoxy Resins Phenolic Resins Unsaturated Polyesters Flexible PUF Rigid PUF Chip / Particle Boards Textiles / Fibers Latex / Adhesives FR Intermediates FR-11 FR-245 FR-370 FR-513 FR-522 FR-613 FR-720 FR-803P FR-1025M FR-1025 FR-1206 FR-1210 FR-1524 BRMINATED EPXY FLAME RETARDANTS F-2001 F-2200 F-2016, F-2300 F-2100, F-2100L, F-2300H, F-2400, F-2400H F-3014, F-3020, F-3516 F-3100 TAILR MADE FR SLUTINS Polyquel TM 240, Polyquel TM P series, 9020, 9025

5 PHSPHRUS FLAME RETARDANTS FYRL SERIES HIPS / PP EPS / XPS ABS Polyethylene Polypropylene PBT / PET Nylon = Polyamide PC / PC ABS Alloys PVC / Flexible Rubbers / Elastomers Epoxy Resins Phenolic Resins Unsaturated Polyesters Flexible PUF Rigid PUF Chip / Particle Boards Textiles / Fibers Latex / Adhesives Cellulosic Plastic Composite Fyrol FR-2 Fyrol HF-4 Fyrol 6 Fyrol FR-7 Fyrol 38 Fyrol A300TB Fyrol PCF Fyrol PMP Fyrol PNX Fyrol PNX-LE FYRLFLEX Fyrolflex BDP Fyrolflex RDP Fyrolflex Sol-DP PHSFLEX Phosflex 4 Phosflex 31L/41L Phosflex 71B Phosflex 362 Phosflex 390 Phosflex 418 Phosflex T-BEP LINDL Lindol Lindol XP Plus MAGNESIUM & NITRGEN FLAME RETARDANTS FR-20 FR-6120 FR MRE INFRMATIN VISIT UR WEBSITE:

6 PRDUCTS & PRPERTIES BRMINATED FLAME RETARDANTS M.W. SPECIFIC GRAVITY BRMINE CNTENT MELTING RANGE/PINT TGA %WT. TEMP. FR-11 Ammonium bromide APPLICATINS: Chipboard, Wood Paper, Textile NH % M.P. 452 C CAS No FR-245 Tris(tribromophenoxy) triazine APPLICATINS: HIPS, ABS ADVANTAGES: combination of good flow and impact, UV and thermal stability, non-blooming N N N % M.P. 230 C 360 C 385 C 400 C CAS No FR-370 Tris(tribromoneopentyl) phosphate APPLICATINS: PP, HIPS, ABS, XPS, Alloys, Adhesives ADVANTAGES: UV and light stability, non-blooming CH 2 =P CH 2 C CH 2 CH 2 3 CAS No % (3% P) M.P. 181 C 282 C 309 C 319 C FR-513 Tribromoneopentyl alcohol APPLICATINS: PU rigid and flexible foams, FR intermediate ADVANTAGES: meets high FR standards, high thermal stability, non-leaching CH 2 H CH 2 C CH 2 CH 2 CAS No % M.P. 65 C 135 C 152 C 166 C FR-522 Dibromoneopentyl glycol APPLICATINS: UPE, PU rigid foams ADVANTAGES: high level of flame retardancy, light stability, transparency CH 2 H CH 2 C CH 2 H CH 2 CAS No % M.P C 200 C 225 C 245 C FR-613 Tribromophenol APPLICATIN: FR Intermediate ADVANTAGE: end capping of brominated epoxies H % M.P. 93 C 120 C 132 C CAS No FR-720 Tetrabromobisphenol A - bis(2,3 dibromopropyl ether) APPLICATINS: PP, HIPS, ABS ADVANTAGES: good FR efficiency and thermal stability CH3 CH 2 CHCH 2 C CH 2 CHCH 2 CH3 CAS No % M.R C 291 C 306 C 313 C FR-803P (polymer) ominated polystyrene APPLICATINS: Nylon, PBT, PET ADVANTAGES: good CTI, thermal stability, non-blooming CH CH 2 n \ x x= % min. S.R C 340 C 358 C 374 C CAS No

7 BRMINATED AND BRMINATED EPXY FLAME RETARDANTS M.W. SPECIFIC GRAVITY BRMINE CNTENT MELTING RANGE/PINT TGA %WT. TEMP. FR-1025M ominated acrylate monomer APPLICATINS: Latex, Rubbers ADVANTAGES: reactive monomer, thermal stability, improves compatibility in polymer matrix H 2 C=CH C= \ / CH 2 / \ CAS No % M.P. 117 C 295 C 319 C 327 C FR-1025 (polymer) ominated polyacrylate APPLICATINS: PBT, Nylon, Alloys ADVANTAGES: excellent thermal aging, CTI, good impact, compatibility with fiber reinforcement and recycling CH 2 CH n C= \ / CH 2 / \ CAS No oligomer % M.R C 320 C 330 C 335 C FR-1206 Hexabromocyclododecane APPLICATINS: EPS, XPS ADVANTAGES: high purity, low loading and good FR efficiency \ / / / \ \ % M.R C 243 C 247 C 249 C CAS No FR-1210 Decabromodiphenyl oxide APPLICATINS: HIPS, PE, PP, ABS, PBT, UPE, Epoxy, Nylon 6, Textiles ADVANTAGES: FR efficiency, exceptional thermal stability and multi-purpose. \ / \ / / \ / \ CAS No % M.P. 305 C 322 C 362 C 385 C FR-1524 Tetrabromobisphenol-A APPLICATINS: Epoxy, Polycarbonate Resins, ABS ADVANTAGES: high reactivity, low color, high clarity, good FR efficiency good solubility \ CH 3 H C / CH 3 / H \ CAS No % M.P. 181 C 262 C 284 C 301 C F-2000 SERIES - ominated Epoxy - Low molecular weight F-2001 APPLICATINS: Unsaturated polyester and vinyl ester resins ADVANTAGES: UV stability, solubilty in styrene \ CH 3 C / CH 3 / H CH \ / \ \ CH 2 CH 2 n % M.R C 280 C 320 C 340 C CAS No F-2200 HM (Proprietary) APPLICATINS: XPS, HIPS, Polyolefins ADVANTAGES: Thermal stabilizer, corrosion resistant, processing aid \ CH 3 C / CH 3 / H CH \ / \ \ CH 2 CH 2 n % M.R C 289 C 326 C 343 C CAS No FR MRE INFRMATIN VISIT UR WEBSITE:

8 PRDUCTS & PRPERTIES BRMINATED EPXY FLAME RETARDANTS M.W. SPECIFIC GRAVITY BRMINE CNTENT SFTENING RANGE/TG TGA %WT. TEMP. F-2000 SERIES - ominated Epoxy polymer \ CH 3 C / CH 3 / H CH \ / \ \ CH 2 CH 2 n CAS No F-2016 (polymer) APPLICATIN: ABS ADVANTAGES: good processability, high thermal and UV stability, non-blooming % S.R C 318 C 340 C 358 C F-2100L (polymer) APPLICATINS: PBT, PC/ABS ADVANTAGES: high thermal and UV stability, non-blooming, non corrosive, excellent processability F-2100 (polymer) APPLICATINS: PBT, PC/ABS ADVANTAGES: high thermal and UV stability, non-blooming, non-corrosive, excellent processability F-2300H (polymer) APPLICATINS: PBT, PET, Alloys (PC/ABS) ADVANTAGES: good mechanical, physical and flow properties, high thermal and UV stability % C 332 C 338 C 353 C % S.R C % Tg C 332 C 339 C 353 C 337 C 344 C 349 C F-2400 (polymer) APPLICATINS: PBT, PET, Nylon, TPU, Alloys, ABS ADVANTAGES: high thermal and UV stability, non-blooming, excellent processability F-3000 SERIES - End capped ominated Epoxy % Tg C 339 C 347 C 353 C H CH / \ CH CH 2 2 / / \ \ H CH / \ CH CH 2 2 / / \ \ / \ / \ C / \ H 3 C CH 3 / \ / \ F-3014 APPLICATINS: HIPS, ABS ADVANTAGES: good processability, nonblooming, high thermal and UV stability, good HDT impact strength, low metal adhesion CAS No F-3020 (polymer) APPLICATINS: HIPS, ABS ADVANTAGES: good processability, nonblooming, hight thermal and UV stability, good HDT impact strength, low metal adhesion CAS No F-3516 APPLICATINS: HIPS, ABS ADVANTAGES: high thermal and UV stability, excellent flow properties, non-blooming low metal adhesion CAS No F-3100 (polymer) APPLICATINS: PBT, Nylon, Alloys, ABS ADVANTAGES: processing - aid, excellent flow properties, non-blooming low metal adhesion and good thermal and UV stability CAS No n % S.R C % S.R C % S.R C % S.R C 338 C 354 C 356 C 348 C 360 C 366 C 326 C 355 C 365 C 338 C 340 C 354 C

9 PHSPHRUS FLAME RETARDANTS SPECIFIC GRAVITY PHSPHRUS CNTENT CHLRINE CNTENT VISCSITY mpa.s - 25 C TGA %WT. TEMP. FYRL SERIES Fyrol FR-2 Tris (1,3-dichloroisopropyl) phosphate APPLICATINS: Flexible PU foam, epoxy resin and phenolics, unsaturated polyesters ADVANTAGES: Excellent processing, good thermal and hydrolytic stability, low fogging CH 2 Cl / P CH \ CH2 Cl CAS No % 49.0% C 225 C 240 C Fyrol HF-4 Proprietary halogen-free flame retardant APPLICATINS: Flexible PU foam ADVANTAGES: Excellent processing, low viscosity, low scorch. Proprietary stabilized flame retardant % C 235 C 250 C Fyrol 6 Diethyl N,N bis (2-hydroxyethyl) aminomethylphosphonate APPLICATINS: Reactive non halogen FR for rigid PU foam and urethane elastomers ADVANTAGES: Excellent for spray, pour-inplace systems and slab foams Fyrol FR-7 Proprietary chlorinated phosphate ester blend APPLICATINS: Flexible PU foam ADVANTAGES: Good compression set and IFD, low scorch C 2 H 4 H / C 2 H 5 P CH 2 N \ C 2 H 4 H C 2 H 5 CAS No Proprietary chlorinated phosphate ester blend % C 195 C 1.31 Prop. Prop C 230 C 240 C Fyrol 38 Modified tris(1,3-dichloro-2-propyl) phosphate APPLICATINS: Flexible PU foam ADVANTAGE: Low scorch version of Fyrol FR % 49.0% C 225 C 240 C Fyrol A300TB Proprietary chloralkyl phosphate blend APPLICATINS: Flexible PU foam for automotive applications ADVANTAGES: Easy processing, meeting the fogging requirement of the automotive industry Fyrol PCF Tris (1-chloroisopropyl) phosphate. APPLICATINS: Isocyanurate and rigid PU foams, flexible PU foam (BS5852), unsaturated polyesters and phenolics ADVANTAGES: Excellent thermal and hydrolytic stability, low viscosity CAS No Proprietary chloroalkyl phosphate ester blend CH 2 Cl / P CH \ CH3 CAS No % C 215 C 235 C % 32.5% C 165 C 180 C Fyrol PMP Poly-(m-phenylene methylphosphonate) APPLICATINS: Curing agent for epoxy resin ADVANTAGES: High glass transition, excellent thermal stability (H) n P / \ \ CH 3 P (H) m / \ / CH 3 p m,n=0 or % C 340 C 385 C 425 C CAS No FR MRE INFRMATIN VISIT UR WEBSITE:

10 PRDUCTS & PRPERTIES PHSPHRUS FLAME RETARDANTS SPECIFIC GRAVITY PHSPHRUS CNTENT CHLRINE CNTENT VISCSITY mpa.s - 25 C MELTING RANGE TGA %WT. TEMP. FYRL SERIES Fyrol PNX ligomeric ethyl ethylene phosphate APPLICATINS: Flexible PU foam, paper treatment ADVANTAGES: very high efficiency, low VC/ FG Fyrol PNX-LE Modified oligomeric ethyl ethylene phosphate APPLICATINS: Flexible PU foam, ADVANTAGE: Low scorch version of Fyrol PNX, low fogging/vc for automotive FYRLFLEX SERIES C 2 H 5 P (CH 2 ) 2 P C 2 H n C 2 H 5 C 2 H 5 CAS No CAS No % C 215 C 235 C % C 215 C 235 C Fyrolflex BDP Bisphenol A bis(diphenyl phosphate) APPLICATINS: Polycarbonate and its alloys, polyphenylene ether blends, styrenics ADVANTAGES: High thermal stability, good hydrolytic stability CH 3 P C CH 3 P n % C 275 C 330 C 395 C Fyrolflex RDP Resorcinol bis(diphenyl phosphate) APPLICATINS: Polycarbonate and its alloys, polyphenylene ether blends, styrenics, phenolic laminates ADVANTAGES: High efficiency, high thermal stability CAS No P \ / P n CAS No % 55 C 290 C 325 C 360 C Fyrolflex Sol-DP Proprietary aromatic phosphate APPLICATINS: Polycarbonate and its alloys, polyphenylene ether blends, UL94/V-2 ABS, processing aid for engineering resins ADVANTAGES: Easy to handle solid freeflowing powder, high efficiency and good hydrolytic stability Proprietary aromatic phosphate, solid powder % M.R C 300 C 335 C 350 C PHSFLEX SERIES Phosflex 4 Tributyl phosphate APPLICATINS: De-airing additive, extraction agent in metal and phosphoric acid production, high-boiling solvent for inks and paints. ADVANTAGE: Low viscosity Phosflex 31L/41L Isopropylated triphenyl phosphate mixture APPLICATINS: PVC film and sheeting compounds, PVC plastisols. ADVANTAGES: High thermal stability, good solvating properties P C 4 H 9 3 CAS No P CH 3 \ / n CH / H 3 C CAS No n % C 135 C 150 C % C 230 C 245 C

11 PHSPHRUS FLAME RETARDANTS SPECIFIC GRAVITY PHSPHRUS CNTENT CHLRINE CNTENT VISCSITY mpas - 25 C TGA %WT. TEMP. Phosflex 71B t-butylated triphenyl phosphate mixture APPLICATINS: Plasticizer for PVC and PVC foams, polyvinyl acetate emulsion, FR for modified HIPS, functional fluid ADVANTAGE: High thermal stability Phosflex ethylhexyl diphenyl phosphate APPLICATINS: Plasticizer for PVC (plastisols, textile coatings), and vinyl/nitrile rubber foamed alloys, cellulosic polymers, PMMA, PS ADVANTAGES: Good performance at low temperature, low smoke, FDA approved in coatings for food packaging. Phosflex 390 Isodecyl diphenyl phosphate APPLICATINS: Plasticizer for PVC sheeting, foamed vinyl/nitrile rubber alloys, wire insulation, coatings for apparel and upholstery, polyvinyl acetate adhesives ADVANTAGES: Good performance at low temperature, low smoke Phosflex 418 Linear alkyl diphenyl phosphate APPLICATINS: Plasticizer for PVC sheeting and wire insulation ADVANTAGES: Excellent plasticizing efficiency at low temperature, low smoke and low volatility P CH 3 n \ / C / \ H 3 C CH 3 3-n CAS No and and C 2 H 5 P CH 2 CH (CH 2 ) 3 CH 3 2 CAS No P C 10 H 21 2 CAS No CAS No and % C 235 C 250 C % C 200 C 210 C % C 220 C 235 C % C 235 C Phosflex T-BEP Tris(butoxyethyl) phosphate APPLICATINS: Emulsions of floor finishes, leveling agent in latex paints, processing aid for acrylonitrile rubber, antiblock agent for cast polyurethanes ADVANTAGE: Low viscosity LINDL SERIES Lindol & Lindol XP Plus Tri(m,p-cresyl) phosphate mixture APPLICATINS: Plasticizer for PVC, synthetic rubber, cellulosic films, FR for phenolic laminates ADVANTAGE: High efficiency PHS-CHEK SERIES P (CH 2 ) 2 C 4 H 9 3 CAS No P \ CH3 CAS No % C 200 C 225 C % C 235 C 250 C Phos-Chek product line are efficient intumescent Flame Retardants for application in paints, coatings, polyolefins, polyurethanes and thermosets. Selected ICL-IP Subsidiaries have distribution agreements with ICL - Performance Products LP, the producer of Phos-Chek. For more information, visit the website: or contact one of the following addresses: bekaphos@bk-giulini.com, frinfo@icl-industrial.com FR MRE INFRMATIN VISIT UR WEBSITE:

12 PRDUCTS & PRPERTIES MINERAL AND NITRGEN FLAME RETARDANTS M.W. SPECIFIC GRAVITY AVG. PARTICLE SIZE BULK DENSITY g/m 3 TGA %WT. TEMP. MAGNESIUM AND NITRGEN BASED FLAME RETARDANTS FR-20 Magnesium Hydroxide GRADES: S5 (BET 5 m 2 /g) uncoated or coated S7 (BET 7 m 2 /g) uncoated or coated S10 (BET 10 m 2 /g) uncoated or coated APPLICATINS: Wire and Cables, Electrical connectors, TP for roofing, Foils and sheets, LD and HDPE, PP, Nylon, Soft PVC ADVANTAGES: excellent smoke suppressant, acid scavenger, thermal stability Mg(H) 2 CAS No µm µm µm C 385 C 402 C FR-6120 Powder (Granules as an option) Melamine Cyanurate APPLICATINS: Nylon, PBT, TPU ADVANTAGES: CTI, good FR efficiency H 2 N N NH 2 N N NH 2 HN N H NH µm ( mm) (0.6) 300 C 340 C 360 C CAS No PLYQUEL, AND SERIES TAILR-MADE SLUTINS Polyquel series, fully active and dust-free polymeric FR systems, is a step forward to more Eco-reliable and Sustainable Fire Safety. The range of and Series is a milestone offering continuously innovative solutions to the identified needs of customers. These tailor-made solutions address specific targets related to fire safety, easier handling, low corrosion, high flow, light and UV stability and/or antimony trioxide free products. The FR BU s solutions are opening up new fields of application. The following table shows some of our new commercial Polyquel, and : Strengths: U - UV stability A - Antimony oxide free E - FR efficiency T - Thermal stability PLYQUEL, AND SERIES PLYQUEL 145 PLYQUEL 240 & 241 U 5371 A E 5531 Antidrip Series E E E E U 6605 D - Dust-free P - Polymer & Non-blooming HIPS / PP D P U EPS / XPS ABS D P U Polyethylene D P Polypropylene PBT / PET Nylon = Polyamide PC / PC ABS A U T Alloys A T PVC / Flexible Rubbers / Elastomers Epoxy Resins Phenolic Resins Unsaturated Polyesters Flexible PUF Rigid PUF E Chip / Particle Boards Textiles / Fibers Latex / Adhesives Cellulosic Plastic Composite 7700 E P Series E T E T P P

13 APPLICATINS THERMPLASTICS AND STYRENIC ALLYS HIPS V-1/V-0 FR-1210* FR-245 F-3000 Polyquel TM 240 Polyquel TM 241 PRPERTIES THERMAL STABILITY MELT FLW FR EFFICIENCY IMPACT UV / LIGHT STABILITY HEAT DISTRTIN TEMP. NN-BLMING CST EFFICIENCY RECYCLING DUST-FREE HIPS V-2 FR-720 FR-1210* FR-245 FR-370 PRPERTIES THERMAL STABILITY MELT FLW FR EFFICIENCY IMPACT UV / LIGHT STABILITY HEAT DISTRTIN TEMP. NN-BLMING CST EFFICIENCY * Not RoHS compliant and restricted applications in the US. FR MRE INFRMATIN VISIT UR WEBSITE:

14 APPLICATINS THERMPLASTICS AND STYRENIC ALLYS ABS V-1/V-0 FR-1524 FR-245 F-2000 Low MW F-2000 High MW F-3000 Polyquel TM 240 Polyquel TM 241 PRPERTIES THERMAL STABILITY MELT FLW FR EFFICIENCY IMPACT UV / LIGHT STABILITY HEAT DISTRTIN TEMP. NN-BLMING CST EFFICIENCY RECYCLING DUST-FREE PC/ABS and HIPS/PP alloys V-1/V-0 Fyrolflex RDP Fyrolflex BDP Fyrolflex Sol-DP Phosflex 71B 5531 PRPERTIES PHSPHRUS (P)/BRMINE () BASED P P P P THERMAL STABILITY MELT FLW FR EFFICIENCY IMPACT UV / LIGHT STABILITY HYDRLYTIC STABILITY HEAT DISTRTIN TEMP. NN-PLATE-UT CST EFFICIENCY LIQUID/SLID HANDLING Liquid Liquid Solid Liquid Solid good very good excellent

15 THERMPLASTICS AND STYRENIC ALLYS PP FR-370 FR FR-1210 FR-1025 FR-20 PRPERTIES THERMAL STABILITY PRCESSABILITY FR EFFICIENCY IMPACT UV / LIGHT STABILITY NN-BLMING CST EFFICIENCY RATING V - 2 V - 0 / V - 2 V - 0 / V - 2 V - 0 V - 0 V - 0 PE FR-720 FR-1210 FR-1025 FR-20 Polyquel TM 145 PRPERTIES THERMAL STABILITY MELT FLW FR EFFICIENCY IMPACT UV / LIGHT STABILITY NN-BLMING CST EFFICIENCY DUST-FREE FR MRE INFRMATIN VISIT UR WEBSITE:

16 APPLICATINS ENGINEERING PLASTICS PLYAMIDE Non reinforced PA 6 and 6,6 V- FR-803P FR-1025 FR-1210* F-2400 FR-6120 FR-20 PRPERTIES THERMAL STABILITY MELT FLW FR EFFICIENCY IMPACT CMPARATIVE TRACKING INDEX THERMAL AGING RECYCLING UV / LIGHT STABILITY HEAT DISTRTIN TEMP. NN-BLMING CST EFFICIENCY * only for Polyamide 6 / Not RoHS compliant and restricted applications in the US. PLYAMIDE Glass reinforced PA 6 and 6,6 V-0 FR-803P FR-1025 FR-1210* F-2400 F-3100 PRPERTIES THERMAL STABILITY MELT FLW FR EFFICIENCY IMPACT CMPARATIVE TRACKING INDEX THERMAL AGING RECYCLING UV / LIGHT STABILITY HEAT DISTRTIN TEMP. NN-BLMING CST EFFICIENCY * only for Polyamide 6 / Not RoHS compliant and restricted applications in the US. good very good excellent

17 ENGINEERING PLASTICS PBT V-0 PRPERTIES FR-1025 F-3100 F-2000 series FR-803P FR-1210* THERMAL STABILITY MELT FLW to FR EFFICIENCY IMPACT CMPARATIVE TRACKING INDEX THERMAL AGING RECYCLING UV / LIGHT STABILITY HEAT DISTRTIN TEMP. NN-BLMING CST EFFICIENCY 5531 FLEXIBLE PVC PVC & TEXTILE ADHESIVES CATING (TAC) PRPERTIES Phosflex 31L/41L Phosflex 71B Phosflex 362 Phosflex 390 Lindol FR EFFICIENCY PLASTICIZING PERFRMANCE LW TEMPERATURE FLEXIBILITY LW SMKE LW VLATILITY/SURFACE MIGRATIN LW SMELL CHEMICAL RESISTANCE (IL FATS) FD APPRVAL ** CST EFFICIENCY * Not RoHS compliant and restricted applications in the US. ** FDA Contact in coatings for confectionary applications FR MRE INFRMATIN VISIT UR WEBSITE:

18 APPLICATINS PVC & TEXTILE ADHESIVES CATING (TAC) TAC BACK CATING PRPERTIES FR-1210* Fyrolflex BDP/RDP PHSPHRUS (P)/BRMINE () BASED /P P P+Cl FR EFFICIENCY TRANSPARENCY LW MELTING TEMPERATURE WATER BASED DISPERSIN SLID (S)/LIQUID (L) S L L L L LW FGGING CST EFFICIENCY * Restricted applications in the US Fyrol FR-2 CATING/PADDING liquid FR systems P P+ SELECTIN MATRIX CTTN + + PLYESTER PLYESTER/CTTN PRPERTIES FR EFFICIENCY TRANSPARENCY WASH DURABILITY SFT HAND LW FGGING LW MELTING TEMPERATURE PLYMERIC WATER BASED DISPERSIN CST EFFICIENCY ADHESIVES AND FIBERS FR-720, with a unique combination of 68% of aromatic and aliphatic bromine on the same molecule, is a FR of choice for hotmelt adhesives applications. FR-370, has unique combination of both high aliphatic bromine (70%) and phosphorus (3%) on the same molecule that contributes to fire retardant efficiency with excellent UV and light stability. It is recommended for adhesives applications and for production of inherently flame retarded PP multifilament for textile applications good very good excellent

19 PLASTIC FAMS FLEXIBLE PUF Fyrol FR-2 Fyrol HF-4 Fyrol FR-7 Fyrol 38 Fyrol A300TB Fyrol PCF Fyrol PNX 7700 FR-513* PRPERTIES LW VISCSITY Solid* FR EFFICIENCY LW SCRCH LW FGGING CMPRESSIN SET REACTIVE CST EFFICIENCY * Also supplied in heated isocontainer RIGID PUF Fyrol 6 Fyrol PCF 6605 FR-513* PRPERTIES LW VISCSITY Solid* FR EFFICIENCY SYSTEM STABILITY REACTIVE CST EFFICIENCY * Also supplied in heated isocontainer EPS / XPS Expanded and extruded polystyrene foams for building, construction and packaging industries are available in many forms: Sheets (thermal insulation), Profiles (decorative), Molded shapes (packaging). ICL-IP offers several flame retardants to match market needs in the various applications: FR-1206 ILM High purity Lower melting range Processing-aid during extrusion of profile or sheet FR-1206 IHM Designed primarily for flame-retarded EPS High purity Readily soluble in styrene monomer Enables good control of the particle size distribution of the beads FR-370 and 5371: Proprietary FR systems High thermal stability enables high processing temperatures Increases productivity Processing-aid effect FR MRE INFRMATIN VISIT UR WEBSITE:

20 ICL - INDUSTRIAL PRDUCTS Head ffice ICL-IP Ltd. Makleff House, 12 Kroitzer St., P..B. 180 Beer Sheva 84101, Israel Tel: Fax: frinfo@icl-ip.com Europe ICL-IP Europe B.V. Fosfaatweg 48, 1013 BM Amsterdam The Netherlands, or P.. Box AL Amsterdam, The Netherlands Tel: Fax: fr.europe@icl-ip.com North America and Mexico ICL-IP America Inc. 622 Emerson Road, Suite 500 St. Louis, Missouri 63141, USA Tel: Fax: fr.nam@icl-ip.com Asia Pacific China ICL CHINA Room 908 Times Square ffice Tower No 93 Middle Huai Hai Road Shanghai , China Tel: Fax: fr.china@icl-ip.com Japan ICL-IP Japan Ltd. Izumi Shinkawa Building, 7th floor, 5-18, 1-chome Shinkawa, Chuo-ku, Tokyo , Japan Tel: Fax: fr.japan@icl-ip.com ther Asia Pacific ICL Asia Ltd. Room 2301, 23/F, Allied Kajima Building, 138 Gloucester Road, Wanchai, Hong Kong Tel: Fax: fr.asia@icl-ip.com South America ICL asil Ltda. Av. Major Sylvio de Magalhaes Padilha, 5200 Ed. Dallas Cj.22, Sao Paulo SP, azil Tel: Fax: fr.sam@icl-ip.com ther parts of the World ICL-IP Israel Sales ffice Makleff House, 12 Kroitzer St., P..B. 180 Beer Sheva 84101, Israel Tel: Fax: fr.row@icl-ip.com Visit our Website: Additional links: GLBAL PRESENCE 8/2010 Although the information and recommendations set forth herein (hereinafter Information ) are presented in good faith and believed to be correct as of the date hereof, ICL INDUSTRIAL PRDUCTS. makes no representations as to the completeness, accuracy, quality or suitability of any information for any purpose. The use of the Information supplied herein shall be subject to and conditioned on that the persons receiving it and making use of it will make their own determination as to its safety and suitability for their purposes and applicable laws and other statutory demands prior to acquisitions, importations, exportations, transportations, implementations or uses of any kind. In no event will ICL INDUSTRIAL PRDUCTS. be responsible for damages of any nature whatsoever resulting, directly or indirectly, from the use or reliance upon Information. N REPRESENTATINS R WARRANTIES, EITHER EXPRESSED R IMPLIED F MERCHANTABILITY, FITNESS FR A PARTICULAR PURPSE R F ANY THER NATURE, ARE MADE HEREUNDER WITH RESPECT T INFRMATIN R THE PRDUCT T WHICH THE INFRMATIN REFERS.