POTASSIUM FERROCYANIDE AR/ACS MSDS. CAS No: MSDS MATERIAL SAFETY DATA SHEET (MSDS)

Transcription

1 MSDS CAS No: MSDS MATERIAL SAFETY DATA SHEET (MSDS) SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Substance : CAS No : Product code : Synonyms : Potassium hexacyanoferrate(ii) trihydr / Yellow prussiateate 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use of the substance/mixture : Laboratory chemicals, Manufacture of substances Uses advised against 1.3. Details of the supplier of the safety data sheet LOBA CHEMIE PVT.LTD. 107 Wode House Road, Jehangir Villa, Colaba Mumbai - INDIA T F info@lobachemie.com Emergency telephone number Emergency number : (9:00am - 6:00 pm) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Hazardous to the aquatic environment Chronic Hazard, Category 3 H412 Full text of classification categories and H statements : see section 16 Classification according to Directive 67/548/EEC or 1999/45/EC R52/53 R32 Full text of R-phrases: see section /04/2015 1/8

2 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Signal word (CLP) : - Hazard statements (CLP) : H412 - Harmful to aquatic life with long lasting effects Precautionary statements (CLP) : P273 - Avoid release to the environment 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance Name : POTASSIUM FERROCYANIDE AR/ACS CAS No : Full text of R- and H-phrases: see section Mixture Not applicable SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion 4.2. Most important symptoms and effects, both acute and delayed : Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek medical advice. : Gently wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. : Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation persists: Get medical advice/attention. : Rinse mouth out with water. If you feel unwell, seek medical advice Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). : Do not use a heavy water stream Special hazards arising from the substance or mixture 09/04/2015 2/8

3 5.3. Advice for firefighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Use personal protective equipment as required. : Stop release Environmental precautions Harmful to aquatic life with long lasting effects Methods and material for containment and cleaning up Methods for cleaning up : Clear up rapidly by scoop or vacuum Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Do not get in eyes, on skin, or on clothing. : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work Conditions for safe storage, including any incompatibilities Storage conditions 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Store in original container. Keep container tightly closed. Store in a dry place. Protect from moisture Exposure controls Hand protection Eye protection Skin and body protection Respiratory protection : protective gloves : Chemical goggles or safety glasses : Wear suitable protective clothing : Wear respiratory protection SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid 09/04/2015 3/8

4 Colour Odour Odour threshold : Pale yellow crystalline. : odourless. ph : 8-10 at 211 g/l at 25 C Relative evaporation rate (butylacetate=1) Melting point : 70 C Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Density : 1.85 g/cm³ Solubility : Water: 211 g/l at 20 C Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Stable under normal conditions Possibility of hazardous reactions Highly reactive material. Contact with acids liberates very toxic gas Conditions to avoid Air contact. Moisture Incompatible materials 09/04/2015 4/8

5 10.6. Hazardous decomposition products SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity ph: 8-10 at 211 g/l at 25 C ph: 8-10 at 211 g/l at 25 C Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard SECTION 12: Ecological information Toxicity Ecology - water : Harmful to aquatic life with long lasting effects Persistence and degradability POTASSIUM FERROCYANIDE AR/ACS ( ) Persistence and degradability May cause long-term adverse effects in the environment Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment 09/04/2015 5/8

6 12.6. Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Product/Packaging disposal recommendations : Dispose of contents/container to... SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) UN-No. (IMDG) UN-No.(IATA) UN-No.(ADN) UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information : No : No : No supplementary information available 09/04/2015 6/8

7 14.6. Special precautions for user - Overland transport - Transport by sea - Air transport - Inland waterway transport - Rail transport Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions POTASSIUM FERROCYANIDE AR/ACS is not on the REACH Candidate List POTASSIUM FERROCYANIDE AR/ACS is not on the REACH Annex XIV List National regulations Germany AwSV/VwVwS Annex reference 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Water hazard class (WGK) 2, hazardous to water (Classification according to VwVwS, Annex 2; WGK No 489) : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Chemical safety assessment SECTION 16: Other information 09/04/2015 7/8

8 Full text of R-, H- and EUH-phrases: Aquatic Chronic 3 Hazardous to the aquatic environment Chronic Hazard, Category 3 H412 Harmful to aquatic life with long lasting effects R32 Contact with acids liberates very toxic gas R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 09/04/2015 8/8