RCR Production France PROROC NT. RCR Production France

Transcription

1 SECTION First Exposure Transport Other aid information. measures. controls/personal... / >>... / >> protection.... / >> Information Sheet Comply 1. Most Regulation Transport important with the (EU) in bulk safety sympms 1907/2006 according measures (REACH) usually effects, Annex of applied the both II of European MARPOL73/78 acute when hling Parliament delayed. chemical the IBC substances. Code. No HAND 2. Regulation episodes PROTECTION of (EU) damage 1272/2008 health (CLP) ascribable of the European the product Parliament have been reported. SECTION None Information 3. Regulation required. not 11. (EU) relevant. Toxicological 790/2009 (I Atp. CLP) information. of the European Parliament 4.3. SECTION SKIN 4. Indication Regulation PROTECTION 1. of (EU) Identification any 2015/830 immediate of the medical European of the attention substance/mixture Parliament special treatment needed. of the company/undertaking Information None 5. Regulation Information required. not (EU) SECTION 15. on Regulary xicological 286/2011 (II Atp. effects. CLP) of the European Parliament information. Page n / EYE 6. Product Regulation PROTECTION identifier (EU) 618/2012 (III Atp. CLP) of the European Parliament None SECTION Information 7. Regulation required. not (EU) /2013 (IV Atp. CLP) of the European Parliament Firefighting measures RESPIRATORY 8. Product Regulation name Safety, health (EU) PROTECTION 944/2013 environmental (V Atp. CLP) regulations/legislation of the European PROROC Parliament NT specific for the substance or mixture Use 9. Extinguishing Regulation a type (EU) P media. filtering 605/2014 facemask (VI Atp. (see CLP) stard of the European 149) Parliament or equivalent device, whose class (1, 2 or 3) effective need, must be defined 1.2. SECTION Seveso SUITABLE according Relevant category. identified EXTINGUISHING 12. the outcome Ecological uses of risk of the EQUIPMT assessment. information. substance mixture uses advised against VIRONMTAL - extinguishing Merck Index. equipment - EXPOSURE 10th Edition should CONTROLS. be of the conventional kind: carbon dioxide, foam, powder water spray. UNSUITABLE Use emissions this product EXTINGUISHING generated according by manufacturing good working EQUIPMT processes, practices. including Avoid littering. those Inform generated the competent by ventilation authorities, equipment, should the should product be reach checked waterways ensure or Restrictions - Intended Hling use Chemical relating Safety the product or contained substances POLYPROPYLE pursuant Annex FIBRE XVII EC Regulation 1907/2006. compliance contaminate in particular. with soil or environmental vegetation. - INRS - Fiche Toxicologique (xicological stards. sheet) Patty Details - Industrial of the supplier Hygiene of the Toxicology safety data sheet 5.2. Substances - Special N.I. Sax hazards - in Dangerous Cidate arising List properties from (Art. 59 the of REACH). Industrial substance Materials-7, or mixture Edition SECTION Toxicity. 9. Physical chemical properties. HAZARDS - Name ECHA website CAUSED BY EXPOSURE IN THE EVT OF FIRE 9.1. Substances Information Full address Do Information not breathe subject not on basic combustion authorisarion physical products. (Annex chemical XIV REACH). ZA Les Monts du Matin - 63, Rue des Lauriers product properties. is combustible, when the powder is released in the air in sufficient concentrations in Appearance District Country La Baume d'hostun the presence of a source of ignition, it can solid create powder explosive mixtures with air. Fires may start or get worse by leakage of the solid product Substances from Colour e Persistence for the users: subject degradability. exportation reporting pursuant (EC) Reg. France 649/2012: Information container, when it reaches high temperatures white or through contact with sources of ignition. Odour information not contained in the present sheet are Tel. odourless based +33 on (0)4 our 75 own knowledge 50 on the date of the last version. Users must verify the 5.3. Odour suitability Advice threshold. for firefighters. thoroughness of provided information according Fax +33 each (0)4 75 specific use 03 of the product Substances GERAL ph. This Bioaccumulative document address subject of INFORMATION must the potential. the competent not Rotterdam be regarded person Convention: as a guarantee on any specific product property. Information Use Melting responsible jets use point of of not for water / freezing this the Safety product Data cool point. the is Sheet containers not subject prevent our > direct production.labaume@rcrproductionfrance.com product 165 control; decomposition C. therefore, users the must, development under their of own substances responsibility, potentially comply hazardous with the current for health. health Always Initial safety boiling wear laws point. full fire regulations. prevention gear. producer Collect is relieved extinguishing applicable. from any water liability arising prevent from it from improper draining uses. in the sewer system. Dispose of contaminated Substances water Boiling Provide Emergency Mobility used range. appointed subject telephone soil. for extinction staff the with Sckholm number adequate Convention: the remains training of the on fire how according use chemical applicable products. Information regulations. not SPECIAL Flash point. PROTECTIVE EQUIPMT FOR FIRE-FIGHTERS applicable. For urgent inquiries refer INRS / ORFILA - Tel. +33 (0) Healthcare Normal Evaporation Results fire controls. of rate fighting PBT clothing vpvb assessment. i.e. fire kit (BS 469), gloves (BS 659) boots (HO specification A29 A30) in combination with self-contained Flammability (solid, open gas) circuit positive pressure compressed air breathing apparatus (BS 137). Information not SECTION Lower On the inflammability basis 2. of Hazards available limit. data, identification. the product does not contain any PBT or vpvb in percentage greater than 0,1%. Upper inflammability limit SECTION Chemical Lower explosive 6. safety Accidental assessment Classification limit. of the substance release or mixture. measures Other adverse effects Upper Personal explosive precautions, limit. protective equipment emergency No chemical safety assessment has been processed for the mixture procedures. the substances it contains. Use Vapour product breathing pressure. is not classified as hazardous pursuant equipment if fumes or powders are the released provisions set forth in EC Regulation 1272/2008 (CLP) ( subsequent Information not in the air. se indications apply for both processing staff those involved in emergency Vapour amendments density supplements). procedures. SECTION Relative density. 16. Other information. 0,910 Kg/l 6.2. SECTION Solubility Hazard classification Environmental 13. Disposal indication: precautions. considerations. -- insoluble Partition product coefficient: must not n-octanol/water penetrate in the sewer system or come in contact with surface water or ground water Au-ignition LEGD: Label Waste elements. treatment temperature. methods Decomposition Reuse, - ADR: European when possible. Methods temperature. Agreement Neat product concerning residues the carriage should material for containment cleaning of be Dangerous considered goods special by non-hazardous Road waste. up. Confine Viscosity Disposal - Hazard CAS NUMBER: picgrams: must be Chemical performed Abstract through --Service an authorised Number waste using earth or inert material. Collect as much management firm, in compliance with national local regulations. material as possible eliminate the rest using jets of water. Contaminated material should Explosive Solid - CE50: residues Effective be properties may concentration be suitable for (required disposal induce an authorised a disposed of in compliance with the provisions 50% set effect) lfill site. forth in point 13. Oxidising CONTAMINATED - Signal CE NUMBER: words: properties Identifier PACKAGING in ESIS (European -- archive of existing substances) Contaminated - CLP: Reference Other EC information. Regulation packaging 1272/2008 must be recovered or disposed of in compliance with national waste management regulations. other sections. Any Information - Hazard DNEL: statements: Derived information not No Effect Level -- on personal protection disposal is given in sections EmS: Emergency Schedule SECTION 14. Transport information. - Precautionary GHS: Globally statements: Harmonized System -- of classification labeling of chemicals SECTION Hling Stability srage. reactivity IATA UN number. DGR: International Air Transport Association Dangerous Goods Regulation - This IC50: product Immobilization is not subject Concentration hazard 50% labeling pursuant EC Regulation 1272/2008 (CLP) subsequent amendments supplements Precautions Reactivity. for safe hling. Before re - IMDG: applicable. International Maritime Code for dangerous goods are hling no particular the risks product, of reaction consult with all other the substances other sections in normal of this conditions material of safety use Other IMO: International hazards. Maritime Organization data sheet. Avoid leakage of the product in the environment. Do not eat, drink or smoke during use INDEX Chemical UN proper NUMBER: stability. shipping Identifier name. in Annex VI of CLP - On LC50: the basis Lethal of Concentration available data, 50% the product does not contain any PBT or vpvb in percentage greater than 0,1% Conditions product is for stable safe in srage, normal conditions including of any use incompatibilities. srage. - LD50: applicable. Lethal dose 50% Keep - OEL: the Occupational product in Exposure clearly labelled Level containers. Keep containers away from any incompatible materials, see section 10 for details SECTION Possibility of hazardous reactions PBT: 7.3. Transport Persistent 3. Composition/information Specific powders hazard bioaccumulative end are use(s). potentially class(es). xic as REACH on Regulation ingredients. explosive when mixed with air. - PEC: Predicted environmental Concentration 3.1. Substances. Information not PEL: Conditions applicable. Predicted exposure level avoid. - PNEC: Predicted no effect concentration Avoid product environmental does not dust contain build-up. substances classified as being hazardous human health or the environment pursuant the provisions REACH: SECTION Packing EC group. Regulation 1907/2006 Regulation (EU) 8. Exposure 1272/2008 (CLP) controls/personal ( subsequent amendments protection. supplements) in such quantities as require the statement. - RID: Regulation concerning the international transport of dangerous goods by train Incompatible materials Information - TLV: Control applicable. Threshold parameters. Limit Value 3.2. Mixtures. not - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure TWA Hazardous Environmental STEL: Short-term decomposition hazards. exposure limit Information not relevant. products. During - TWA: Time-weighted Information the not risk assessment average exposure process, limit it is essential take in consideration the ACGIH occupational exposure levels for inert particulate not otherwise - VOC: applicable. Volatile classified organic (PNOC Compounds respirable fraction: 3 mg/m3; PNOC inhalable fraction: 10 mg/m3). For values above these limits, use a P type SECTION filter, - vpvb: whose Very 4. class Persistent First (1, 2 aid or 3) measures. very must Bioaccumulative be chosen according as for REACH the outcome Regulation of risk assessment WGK: Special Water precautions hazard classes for user. (German) Description of first aid measures Exposure controls. specifically necessary. Observance of good industrial hygiene is recommended. applicable. GERAL BIBLIOGRAPHY

2 SECTION 4. First aid measures.... / >> 4.2. Most important sympms effects, both acute delayed. No episodes of damage health ascribable the product have been reported. Page n. 2 / Indication of any immediate medical attention special treatment needed. Information not SECTION 5. Firefighting measures Extinguishing media. SUITABLE EXTINGUISHING EQUIPMT extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder water spray. UNSUITABLE EXTINGUISHING EQUIPMT None in particular Special hazards arising from the substance or mixture. HAZARDS CAUSED BY EXPOSURE IN THE EVT OF FIRE Do not breathe combustion products. product is combustible, when the powder is released in the air in sufficient concentrations in the presence of a source of ignition, it can create explosive mixtures with air. Fires may start or get worse by leakage of the solid product from the container, when it reaches high temperatures or through contact with sources of ignition Advice for firefighters. GERAL INFORMATION Use jets of water cool the containers prevent product decomposition the development of substances potentially hazardous for health. Always wear full fire prevention gear. Collect extinguishing water prevent it from draining in the sewer system. Dispose of contaminated water used for extinction the remains of the fire according applicable regulations. SPECIAL PROTECTIVE EQUIPMT FOR FIRE-FIGHTERS Normal fire fighting clothing i.e. fire kit (BS 469), gloves (BS 659) boots (HO specification A29 A30) in combination with self-contained open circuit positive pressure compressed air breathing apparatus (BS 137). SECTION 6. Accidental release measures Personal precautions, protective equipment emergency procedures. Use breathing equipment if fumes or powders are released in the air. se indications apply for both processing staff those involved in emergency procedures Environmental precautions. product must not penetrate in the sewer system or come in contact with surface water or ground water Methods material for containment cleaning up. Confine using earth or inert material. Collect as much material as possible eliminate the rest using jets of water. Contaminated material should be disposed of in compliance with the provisions set forth in point Reference other sections. Any information on personal protection disposal is given in sections SECTION 7. Hling srage Precautions for safe hling. Before hling the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product in the environment. Do not eat, drink or smoke during use Conditions for safe srage, including any incompatibilities. Keep the product in clearly labelled containers. Keep containers away from any incompatible materials, see section 10 for details Specific end use(s). Information not SECTION 8. Exposure controls/personal protection Control parameters. During the risk assessment process, it is essential take in consideration the ACGIH occupational exposure levels for inert particulate not otherwise classified (PNOC respirable fraction: 3 mg/m3; PNOC inhalable fraction: 10 mg/m3). For values above these limits, use a P type filter, whose class (1, 2 or 3) must be chosen according the outcome of risk assessment Exposure controls.

3 SECTION 8. Exposure controls/personal protection.... / >> Page n. 3 / 6 Comply with the safety measures usually applied when hling chemical substances. HAND PROTECTION None required. SKIN PROTECTION None required. EYE PROTECTION None required. RESPIRATORY PROTECTION Use a type P filtering facemask (see stard 149) or equivalent device, whose class (1, 2 or 3) effective need, must be defined according the outcome of risk assessment. VIRONMTAL EXPOSURE CONTROLS. emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked ensure compliance with environmental stards. SECTION 9. Physical chemical properties Information on basic physical chemical properties. Appearance solid powder Colour white Odour odourless Odour threshold. ph. Melting point / freezing point. > 165 C. Initial boiling point. applicable. Boiling range. Flash point. applicable. Evaporation rate Flammability (solid, gas) Lower inflammability limit. Upper inflammability limit. Lower explosive limit. Upper explosive limit. Vapour pressure. Vapour density Relative density. 0,910 Kg/l Solubility insoluble Partition coefficient: n-octanol/water Au-ignition temperature. Decomposition temperature. Viscosity Explosive properties Oxidising properties 9.2. Other information. Information not SECTION 10. Stability reactivity Reactivity. re are no particular risks of reaction with other substances in normal conditions of use Chemical stability. product is stable in normal conditions of use srage Possibility of hazardous reactions. powders are potentially explosive when mixed with air Conditions avoid. Avoid environmental dust build-up Incompatible materials. Information not Hazardous decomposition products. Information not

4 Page n. 4 / 6 SECTION 11. Toxicological information Information on xicological effects. Information not SECTION 12. Ecological information. Use this product according good working practices. Avoid littering. Inform the competent authorities, should the product reach waterways or contaminate soil or vegetation Toxicity. Information not Persistence degradability. Information not Bioaccumulative potential. Information not Mobility in soil. Information not Results of PBT vpvb assessment. On the basis of available data, the product does not contain any PBT or vpvb in percentage greater than 0,1% Other adverse effects. Information not SECTION 13. Disposal considerations Waste treatment methods. Reuse, when possible. Neat product residues should be considered special non-hazardous waste. Disposal must be performed through an authorised waste management firm, in compliance with national local regulations. Solid residues may be suitable for disposal in an authorised lfill site. CONTAMINATED PACKAGING Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations. SECTION 14. Transport information UN number. applicable UN proper shipping name. applicable Transport hazard class(es). applicable Packing group. applicable Environmental hazards. applicable Special precautions for user. applicable.

5 SECTION 14. Transport information.... / >> Transport in bulk according Annex II of MARPOL73/78 the IBC Code. Page n. 5 / 6 Information not relevant. SECTION 15. Regulary information Safety, health environmental regulations/legislation specific for the substance or mixture. Seveso category. Restrictions relating the product or contained substances pursuant Annex XVII EC Regulation 1907/2006. Substances in Cidate List (Art. 59 REACH). Substances subject authorisarion (Annex XIV REACH). Substances subject exportation reporting pursuant (EC) Reg. 649/2012: Substances subject the Rotterdam Convention: Substances subject the Sckholm Convention: Healthcare controls. Information not Chemical safety assessment. No chemical safety assessment has been processed for the mixture the substances it contains. SECTION 16. Other information. LEGD: - ADR: European Agreement concerning the carriage of Dangerous goods by Road - CAS NUMBER: Chemical Abstract Service Number - CE50: Effective concentration (required induce a 50% effect) - CE NUMBER: Identifier in ESIS (European archive of existing substances) - CLP: EC Regulation 1272/ DNEL: Derived No Effect Level - EmS: Emergency Schedule - GHS: Globally Harmonized System of classification labeling of chemicals - IATA DGR: International Air Transport Association Dangerous Goods Regulation - IC50: Immobilization Concentration 50% - IMDG: International Maritime Code for dangerous goods - IMO: International Maritime Organization - INDEX NUMBER: Identifier in Annex VI of CLP - LC50: Lethal Concentration 50% - LD50: Lethal dose 50% - OEL: Occupational Exposure Level - PBT: Persistent bioaccumulative xic as REACH Regulation - PEC: Predicted environmental Concentration - PEL: Predicted exposure level - PNEC: Predicted no effect concentration - REACH: EC Regulation 1907/ RID: Regulation concerning the international transport of dangerous goods by train - TLV: Threshold Limit Value - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. - TWA STEL: Short-term exposure limit - TWA: Time-weighted average exposure limit - VOC: Volatile organic Compounds - vpvb: Very Persistent very Bioaccumulative as for REACH Regulation - WGK: Water hazard classes (German). GERAL BIBLIOGRAPHY

6 SECTION 16. Other information.... / >> 1. Regulation (EU) 1907/2006 (REACH) of the European Parliament 2. Regulation (EU) 1272/2008 (CLP) of the European Parliament 3. Regulation (EU) 790/2009 (I Atp. CLP) of the European Parliament 4. Regulation (EU) 2015/830 of the European Parliament 5. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament 6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament 7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament 8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament 9. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament Page n. 6 / 6 - Merck Index. - 10th Edition - Hling Chemical Safety - INRS - Fiche Toxicologique (xicological sheet) - Patty - Industrial Hygiene Toxicology - N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition - ECHA website e for users: information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the suitability thoroughness of provided information according each specific use of the product. This document must not be regarded as a guarantee on any specific product property. use of this product is not subject our direct control; therefore, users must, under their own responsibility, comply with the current health safety laws regulations. producer is relieved from any liability arising from improper uses. Provide appointed staff with adequate training on how use chemical products.