SAFETY DATA SHEET. Multi-Purpose Stain Remover Concentrate

Transcription

1 SAFETY DATA SHEET Multi-Purpose Stain Remover Concentrate This Safety Data Sheet contains information about the potential risks to those involved in handling, transporting and working with this product, as well as describing potential risks to the environment. This information must be made available to those who may come into contact with the product or are responsible for its use. This Safety Data Sheet has been prepared in accordance with the formatting requirements described in the REACH Regulation (EC) No 1907/2006 and the CLP Regulation (EC) No 1272/2008. SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Multi-purpose stain remover concentrate 0220 Water based detergent 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified use: Cleaner for domestic and professional use Uses advised against: None 1.3 Details of the supplier of the safety data sheet TMGTV Inc. Front Suite, Flr High Street, Teddington Middlesex, TW11 8HH Tel: E mail: hbrunt@tmgtv.ca 1.4 Emergency telephone number Tel: CANUTEC: or *666 (cellular) Hours: 24/7 SECTION 2: Hazards Identification 2.1 Classification of the substance or mixture Classification according to the Dangerous Preparations Directive 1999/45/EC: Not classified as hazardous Classification according to the Classification Labelling and Packaging Regulation (EC) No 1272/2008: Not classified as hazardous Page 1 of 8

2 2.2 Label elements Label according to the Classification Labelling and Packaging Regulation (EC) No 1272/2008: P P351 +P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/attention. S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice 2.3 Other hazards None known. SECTION 3: Composition 3.1 Substances 3.2 Mixtures Aqueous solution Product/ingredient name Isopropylamine Dodecylbenzene Sulfonate Identifiers % 67/548/EEC EC: CAS: <15 Xi Irritant R36, R38 Classification Regulation (EC) No 1272/2008 [CLP] Skin Irrit 2 H315 Eye Irrit 2 H319 Alcohol ethoxylate CAS < 5 Xi Irritant R36 Eye Irrit 2 H319 Also contains co-solvents and fragrance in aqueous mixture No further hazardous impurities or substances present considered PBT or vpvb, present above thresholds of concern, or substances with a community workplace exposure limit assigned which required reporting in this section See Section 16 for the full text of the R-phrases declared above. See Section 16 for the full text of the H statements declared above. SECTION 4: First Aid Measures 4.1 Description of first aid measures EYE CONTACT: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. SKIN CONTACT: Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. INGESTION: Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur. Page 2 of 8

3 INHALATION: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if symptoms occur. Protection of First Aiders: No specific measures. 4.2 Most important symptoms and effects, both acute and delayed No known significant effects or critical hazards. 4.3 Indication of any immediate medical attention and special treatments needed Note to physician: Treat symptomatically with dilution of material. Specific treatment: Dilution SECTION 5: Firefighting Measures 5.1 Extinguishing media Use an extinguishing agent suitable for the surrounding fire. 5.2 Special hazards arising from the substance or mixture Hazards from the mixture: No specific hazards. Hazardous combustion: products No specific hazards. 5.3 Advice for fire fighters Special protective actions: for fire-fighters Special protective equipment: for fire-fighters Remarks: No special measures required. No special measures required The material will not support combustion SECTION 6: Accidental Release Measures 6.1 Personal precautions, protective equipment and emergency procedures No special precautions 6.2 Environmental precautions Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. 6.3 Methods and materials for containment and cleaning up Small Spill (< 10 litres): Dilute with water and mop up. Alternatively, absorb liquid onto suitable inert absorbent, sweep up and place in an appropriate waste disposal container. Large Spill (> 10 litres): Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or contain and collect spillage with absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). 6.4 References to other sections See Section 1 for emergency contact information. See Section 8 for information on appropriate personal protective equipment. See Section 13 for additional waste treatment information. Page 3 of 8

4 SECTION 7: Handling and Storage 7.1 Precautions for safe handling Protective Measures: Put on appropriate personal protective equipment (see Section 8). 7.2 Conditions for safe storage, including any incompatibilities No specific conditions for storage Store below 40 C Store in original container protected from direct sunlight in a dry, cool and well-ventilated area Keep container tightly closed and sealed until ready for use. 7.3 Specific end use(s) For use only in industrial applications SECTION 8: Exposure Controls/Personal Protection 8.1 Control parameters Occupational exposure limits: none No substance specific DNELs considered relevant for this SDS No substance PNECs considered relevant for this SDS 8.2 Exposure controls No specific controls Eye protection Safety glasses with side shields required when handling bulk material. Hand protection Detergent impervious gloves may be worn if repeated contact with the concentrated material Skin and body protection No specific protection required Respiratory protection No special protection is required. SECTION 9: Physical and Chemical Properties 9.1 Information on basic physical and chemical properties Appearance physical state: Clear liquid. Aqueous. Odour: Lemon fragrance Odour threshold: not available ph: 5-6 (concentrated) Melting point / range: 0 C (approximate, water) Boiling point: 100 C (approximate, water) Page 4 of 8

5 Flash point: > 100 C Evaporation rate: Flammability: As water Will not support combustion Upper/lower flammability limits: Not applicable Vapour pressure: Vapour density: As water Not applicable Relative density: Approximately 1 Solubility in water: Solubility in other solvents: Aqueous solution. Miscible in water Soluble in polar solvents Partition coefficient (log Kow): Not applicable; mixture of water soluble components Auto-ignition temperature: As water Decomposition temperature: Stable to boiling point of water Viscosity: Explosive properties: Oxidising properties: 9.2 Other information Solution in water Not measured. Aqueous solution. Not classified as explosive Not classified as oxidising SECTION 10: Stability and Reactivity 10.1 Reactivity No specific test data related to reactivity is available for this product or its components 10.2 Chemical stability The product is stable under expected conditions of use 10.3 Possibility of hazardous reactions Under normal conditions of storage and use, hazardous reactions will not occur 10.4 Conditions to avoid No specific data 10.5 Incompatible materials No specific data 10.6 Hazardous decomposition products No specific data SECTION 11: Toxicological Information 11.1 Information on toxicological effects The solution has not been tested. Assessment is based on consideration of the registered substance. (a) acute toxicity (b) skin corrosion/irritation The product has not been tested Solution not considered to be harmful by ingestion, inhalation or on skin based on toxicity of ingredients Solution considered to be mildly irritating to skin. Page 5 of 8

6 (c) serious eye damage/irritation Data on ingredients suggests mild eye irritation but not sufficient for classification (d) respiratory/skin sensitisation No components over 0.1% considered to be potential sensitiser Contains citrus fragrances below 0.1% (e) germ cell mutagenicity No indication that any components are a potential mutagen (f) carcinogenicity (g) reproductive toxicity (h) STOT-single exposure (i) STOT-repeated exposure (j) aspiration hazard No indication that any components are a potential carcinogen No indication that any components are a potentially toxic for reproduction No known adverse effects from any components No known adverse effects from any components Aqueous solution. Not applicable. SECTION 12: Ecological Information The solution has not been tested. Assessment is based on consideration of the components Toxicity Fish LC 50 Daphnia EC 50 Algal inhibition > 100 mg/l based on actives > 100 mg/l based on actives > 100 mg/l based on actives 12.2 Persistence and degradability The organic components are biodegradable and meet the requirement of the Detergents Regulation 12.3 Bioaccumulative potential None of the components are considered to be significantly bioaccumulative 12.4 Mobility in soil The substance is miscible in water and potentially mobile in soil 12.5 Results of PBT and vpvb assessment The active components are not PBT or vpvb 12.6 Other adverse effects No known significant effects or critical hazards SECTION 13: Disposal Considerations 13.1 Waste treatment methods Methods of disposal: Dispose of surplus product via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Incineration or landfill should be considered only when recycling is not feasible. This material and its container must be disposed of in a safe way. Hazardous waste: The product is not regarded as hazardous waste as defined by EU Directive 91/689/EEC. SECTION 14: Transport Information Page 6 of 8

7 Not classified as hazardous for transport UN Number 14.2 UN Proper shipping name 14.3 Transport hazard class(es) 14.4 Packing group 14.5 Environmental hazards 14.6 Special precautions for user 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory Information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture This product is subject to the Detergent Regulation (EC) No 648/2004 EU Regulation (EC) No. 1907/2006 (REACH) The supplier has not yet registered any of the components 15.2 Chemical Safety Assessment A CSR for the components is not available SECTION 16: Other Information Revision information: First EU SDS R Phrases and H Statements used in Section 3: R36 Irritating to eyes R38 Irritating to skin H315 Causes skin irritation H319 Causes Serious Eye Irritation Status under REACH Article 31: An SDS is not obligatory for the material under the criteria laid down in Article 31(1) or Article 31(3) Abbreviations and acronyms: CLP Classification, Labelling and Packaging Regulation (EC) No 1272/2008 EC European Community/Commission EU European Union PBT Persistent, Bioaccumulative and Toxic REACH Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006 SDS Safety Data Sheet TWA time-weighted average vpvb very Persistent, very Bioaccumulative WEL Workplace Exposure Limit (UK) Page 7 of 8

8 Sources of key data: Source: European Chemicals Agency, Method used for classification of mixture: Ingredient-based approaches and expert judgment According to AISE framework formulation D10, a neutral mixture of maximum 15% non-ionic and maximum 5% anionic surfactant is unlikely to be irritating to skin or eyes. Page 8 of 8