Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet NFPA HMIS Personal Protective Equipment 0 Health Hazard Fire Hazard 0 See Section 5. Section. Chemical Product and Company Identification Page Number: Common Name/ Trade Name Manufacturer Commercial Name(s) Synonym Chemical Name Chemical Family Chemical Formula Supplier Palladium Hydroxide on Carbon Powder, SPECTRUM LABORATORY PRODUCTS INC S. SAN PEDRO STREET GARDENA, CA SPECTRUM LABORATORY PRODUCTS INC S. SAN PEDRO STREET GARDENA, CA Catalog Number(s). CAS# RTECS CI# P840 Mixture. CALL (30) TSCA T S C A 8 ( b ) i n v e n t o r y : C h a r c o a l ( C a r b o n ) ; Palladium Hydroxide IN CASE OF EMERGENCY CHEMTREC (24hr) Section 2.Composition and Information on Ingredients Name CAS # Exposure Limits TWA (mg/m 3 ) STEL (mg/m 3 ) CEIL (mg/m 3 ) % by Weight ) Charcoal (Carbon) ) Palladium Hydroxide Toxicological Data on Ingredients Charcoal, Activated LD50: LC50: Section 3. Hazards Identification Potential Acute Health Effects Potential Chronic Health Effects Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. CARCINOGENIC EFFECTS: MUTAGENIC EFFECTS: TERATOGENIC EFFECTS: DEVELOPMENTAL TOXICITY: The substance is toxic to mucous membranes. The substance may be toxic to lungs. Repeated or prolonged exposure to the substance can produce target organs damage.

2 Page Number: 2 Section 4. First Aid Measures Eye Contact Skin Contact Serious Skin Contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 5 minutes. Get medical attention if irritation occurs. Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Inhalation Serious Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Ingestion Serious Ingestion Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband. Section 5. Fire and Explosion Data Flammability of the Product Auto-Ignition Temperature Flash Points Flammable Limits Products of Combustion Fire Hazards in Presence of Various Substances Explosion Hazards in Presence of Various Substances Fire Fighting Media and Instructions Fire Hazards Explosion Hazards May be combustible at high temperature. The lowest known value is 452 C (845.6 F) (Charcoal, Ac tivated). Slightly flammable to flammable in presence of open flames and sparks, of heat. Risks of explosion of the product in presence of mechanical impact: Risks of explosion of the product in presence of static discharge: SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet. Section 6. Accidental Release Measures Small Spill Large Spill Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.

3 Page Number: 3 Section 7. Handling and Storage Precautions Storage Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not breathe dust. Keep away from incompatibles such as oxidizing agents, metals, acids. Keep container tightly closed. Keep container in a cool, well-ventilated area. Air Sensitive Section 8. Exposure Controls/Personal Protection Engineering Controls Personal Protection Personal Protection in Case of a Large Spill Exposure Limits Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Charcoal (Carbon) TWA: 5 (mg/m 3 ) from OSHA (PEL) [United States] Inhalation Respirable. TWA: 3.5 (mg/m 3 ) from ACGIH (TLV) [United States] Inhalation Respirable. TWA: 4 (mg/m 3 ) [United Kingdom (UK)] Inhalation Respirable. TWA: 0 (mg/m 3 ) [United Kingdom (UK)] Inhalation Total. TWA: 2 (mg/m 3 ) [Canada] Inhalation Respirable. TWA: 5 (mg/m 3 ) from OSHA (PEL) [United States] Inhalation Total. Consult local authorities for acceptable exposure limits. Section 9. Physical and Chemical Properties Physical state and appearance Solid. (Powdered solid.) Odor Molecular Weight ph (% soln/water) Taste Color Black. Grey-black Boiling Point Melting Point Critical Temperature Not disponible Specific Gravity Vapor Pressure Vapor Density Volatility Odor Threshold Water/Oil Dist. Coeff. Ionicity (in Water) Dispersion Properties Is not dispersed in cold water, hot water. Solubility Insoluble in cold water, hot water.

4 Section 0. Stability and Data Stability The product is stable. Page Number: 4 Instability Temperature Conditions of Instability Incompatibility with various substances Corrosivity Excess heat, dust generation, incompatible materials Reactive with oxidizing agents, acids, alkalis. Non-corrosive in presence of glass. Corrosivity Polymerization Incompatible with alcohols, organic solvents, Sulfur, Bromine, Ammonia, Zinc. Air sensitive. Will not occur. Section. Toxicological Information Routes of Entry Toxicity to Animals Chronic Effects on Humans Other Toxic Effects on Humans Toxicity to Animals Chronic Effects on Humans other Toxic Effects on Humans Inhalation. Ingestion. LD50: LC50: Contains material which may cause damage to the following organs: lungs. Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation. May cause adverse reproductive effects based on animal test data. (Charcoal, Activated) Acute Potential Health Effects: Skin: May cause skin irritation. Eyes: May cause eye irritation. Inhalation: May cause respiratory tract irritation. Ingestion: May cause digestive tract irritation. Section 2. Ecological Information Ecotoxicity BOD5 and COD Products of Biodegradation Toxicity of the Products of Biodegradation the Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.

5 Page Number: 5 Section 3. Disposal Considerations Waste Disposal Waste must be disposed of in accordance with federal, state and local environmental control regulations. Section 4. Transport Information DOT Classification Not a DOT controlled material (United States). Identification Special Provisions for Transport DOT Section 5. Other Regulatory Information and Pictograms Federal and State Regulations California Proposition 65 Warnings Other Regulations Rhode Island RTK hazardous substances: Charcoal (Carbon) TSCA 8(b) inventory: Charcoal (Carbon); Palladium Hydroxide California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: No products were found. California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: No products were found. OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR ). EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances: Carbon; Palladium Hydroxide Canada Domestic Substances List (DSL): Carbon Canada Non-Domestic Substances List (NDSL): Palladium Hydroxide China: Listed on National Inventory: Carbon Japan: Listed on National Inventory (ENCS): Palladium Hydroxide Korea: Listed on National Inventory (KECI): Carbon; Palladium Hydroxide Philippines: Listed on National Inventory (PICCS): Carbon Australia: Listed on AICS: Carbon Other Classifications WHMIS (Canada) Not controlled under WHMIS (Canada). DSCL (EEC) This product is not classified according to the EU regulations. HMIS (U.S.A.) Health Hazard Fire Hazard Personal Protection 0 E National Fire Protection Association (U.S.A.) Health 0 Flammability Specific hazard WHMIS (Canada) DSCL (Europe)

6 TDG (Canada) Page Number: 6 ADR (Europe) Protective Equipment Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Safety glasses. Section 6. Other Information MSDS Code References Other Special Considerations P0037 Validated by Sonia Owen on 5/24/200. Verified by Sonia Owen. Printed 5/24/200. CALL (30) Notice to Reader All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product is combined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop proper methods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products, Inc. assumes no responsibility for the completeness or accuracy of the information contained herein.