MATERIAL SAFETY DATA SHEET

Transcription

1 Page 1 of 6 MATERIAL SAFETY DATA SHEET CHEM LINK, INC. Emergency Phone No PO Box Information Phone No Kalamazoo, MI Date Prepared: 12/11/02 SECTION I PRODUCT INDENTIFICATION PRODUCT NAME: CAS NUMBER: CHEMICAL FAMILY: PRODUCT USE: (Mixture) Silyl terminated polyether Moisture cure sealant SECTION II HAZARDOUS COMPONENTS/IDENTITY INFORMATION The criteria for listing components in this section are as follows: Carcinogens are listed when present at 0.1% or greater. Components which are otherwise hazardous according to OSHA are listed when present at 1.0% or greater. This is not intended to be a complete compositional disclosure.the composition or components of this mixture may be proprietary information. In the event of a medical emergency, compositional information will be provided to a physician or nurse. Hazardous Components: ACGIH/TLV OSHA/PEL Manufacturer Chemical name CAS Number % TWA STEL TWA STEL TWA STEL Amino Silane Proprietary Vinyltrimethoxysilane Proprietary 5.0 ppm

2 Page 2 of 6 SECTION III - HEALTH HAZARD DATA National Fire Protection Association (NFPA) Primary Routes of Entry: Health: 1 Flammability: 1 EYE X SKIN X INHALATION INGESTION Reactivity: 1 Specific Hazard: None HEALTH HAZARDS: Acute: EYES: Contact can cause severe irritation. Repeated or prolonged contact may cause chemical burns to the eyes SKIN: May cause irritation. Repeated or prolonged contact may cause dermatitis. INGESTION: May be harmful if ingested. INHALATION: Short-term harmful health effects are not expected from vapors generated at ambient temperatures. However, this material is capable of generating small amounts of methanol when reacted with water. Methanol vapor may cause dizziness, drowsiness, disturbance of vision, and tingling, numbness in hands and forearms. Chronic: No adverse effects anticipated from available information. Medical Conditions Aggravated by Exposure: Preexisting skin and eye disorders may be aggravated by exposure to this product. Carcinogenicity: NTP? No OSHA? No IARC? No SECTION IV - FIRST AID MEASURES EYES: SKIN: Irrigate immediately with plenty of water for several minutes. Clean product from affected area with alcohol; Then wash with soap and water. Inhalation: If irritation, headache, nausea, or drowsiness occurs, remove to fresh air. Get medical attention if breathing becomes difficult or respiratory irritation persists. Ingestion: Induce vomiting as directed by medical personnel.

3 Page 3 of 6 SECTION V - EXPOSURE CONTROLS / PERSONAL PROTECTION Respiratory Protection: Not ordinarily required. Use NIOSH or MSHA approved respirator as appropriate. Ventilation: Local Exhaust: Yes Mechanical (General) No Special: No Other: No Skin Protection: Wear gloves and protective clothing to minimize contact with skin. Eye Protection: Wear safety glasses or goggles to avoid eye contact. Other Protective Clothing or Equipment: Work/Hygienic Practices: Avoid prolonged or repeated contact with skin. Wash thoroughly with soap and water after use. SECTION VI - PHYSICAL/CHEMICAL CHARACTERISTICS Appearance: Boiling Point: Specific Gravity: Gray color; Viscous liquid (H2O = 1) Vapor Density: > 384 F Vapor Pressure: Evaporation Rate: Solubility in Water: % Non-volatile Negligible > 99%

4 Page 4 of 6 SECTION VII - REACTIVITY DATA Stability: (Conditions to Avoid:) Incompatibility (Materials to Avoid): Considered stable. Reacts with water and moisture; Reaction with water or moisture releases trace amounts of methanol. Hazardous Decomposition or Byproducts: Thermal decomposition may produce toxic fumes of CO and/or CO2. Hazardous Polymerization: Will not occur. SECTION VIII - FIRE AND EXPLOSION HAZARD DATA Flash Point: Not established Flammable Limits: LEL: UEL: Extinguishing Media: Foam, CO2, and Dry chemical. This material is reactive with water, but the reaction will not significantly increase the fire severity. Special Fire Fighting Procedures: Wear full protective clothing and positive pressure self-contained breathing apparatus. Unusual Fire and Explosion Hazards: None. This product is not considered flammable, but may become involved in a fire with other materials releasing typical hydrocarbon products of combustion.

5 Page 5 of 6 SECTION IX - PRECAUTIONS FOR SAFE HANDLING AND USE Steps to be Taken in Case Material is Released or Spilled: Contain large spill by building a dike with absorbent material. Collect remainder of the spill with absorbent material and place the material into a container approved for waste disposal. For minor spill, collect with absorbent material and dispose of properly. Waste Disposal Method: If this product becomes a waste, it would not be a hazardous waste by RCRA criteria. Place in an appropriate disposal facility in compliance with local regulations. Precautions to be taken in Handling and Storing: Use appropriate personal protection equipment. Avoid eye, skin and clothing contact. Keep away from heat, sparks and flame Storage: Store in a cool, dry area away from incompatible materials. Do not freeze. Store away from heat, sparks, and flame. Other Precautions: SECTION X - TRANSPORT IMFORMATION DOT: Proper Shipping Name: Hazard Class: Identification Number: Packaging Group: Label Required: Shipping class: 55

6 Page 6 of 6 SECTION XI - ADDITIONAL REGULATORY INFORMATION AND OTHER Toxicological: Chemical CAS Oral Inhalation Dermal Eye Amino Silane LD50 >2,000 mg/kg LD50 >2,000 mg/kg Severe irritation Causes corneal injury Vinyltrimethoxy silane LD50 (Rat) >7,300 mg/kg LC 50 (Rat) mg/l 4h LD50 >3,400 mg/kg Minimal irritation Federal Regulations: CERCLA: All components in this product are listed or are exempt from the Toxic Substance Control Act (TSCA) Chemical Substance Inventory. No SARA Title III: Section 311/312: Immediate (Acute) Health Hazard. Section 302/304: Section 313: This product does not contain any chemicals currently on the Extremely Hazardous Substance list. This product does not contain any chemicals currently on the Toxic Chemical List. California Proposition 65: This product contains no levels of listed substances, which the state of California has found to cause cancer, birth defects or other reproductive harm. Other state lists: Other Information: This product is only for industrial use. Do not use this product for such applications as food, pharmaceuticals, and cosmetics, which have the possibility of direct ingestion or exposure to the human body. To the best of our knowledge, the information contained herein is accurate. However Chem Link Inc. does not assume any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be handled with care. Although we have described herein all of the hazards to which we are currently aware, we cannot guarantee that these are the only hazards which exist.