Version: 1. Hauptstr , Aichstetten, Germany. Tel./Fax.: Tel , Fax

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1 Revised edition: Version: 1 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Roman Lime Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Industry mortar, rendering, lime paints Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: info@kremer-pigmente.de Importer: -- Emergency No. Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) H315 Cat.: 2 H318 Cat.: 1 H335 Cat.: 3 H372 Cat.: 1 Classification according to Directive No. 67/548/EC or No. 1999/45/EC Harmful (Xn) R20 Irritating (Xi) R41 Skin irritation, hazard category 2 Serious eye damage, hazard category 1 Specific Target Organ Toxicity (single exposure), hazard category 3 Specific target organ toxicity (repeated exposure), hazard category 1 Causes skin irritation. Causes serious eye damage. May cause respiratory irritation. Causes damage to organs through prolonged or repeated exposure. Harmful by inhalation. Risk of serious damage to eyes. Safety Phrases: Possible Environmental Effects: Label Elements See Section 12. 2

2 2. 2. Page 2 Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Hazard designation: GHS05 GHS07 GHS08-2 Signal word: Hazard designation: Safety designation: H315 H318 H335 H372 P102 P261 P280 P285 P302+P352 P304+P340 P332+P313 P501 Danger Causes skin irritation. Causes serious eye damage. May cause respiratory irritation. Causes damage to organs through prolonged or repeated exposure. Keep out of reach of children. Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. Wear protective gloves/ clothing/ eye/ face protection. In case of inadequate ventilation wear respiratory protection. If on skin: Wash with soap and water. If inhaled: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If skin irritation occurs: Get medical attention. Dispose of contents/ container according to regional, national and international regulations Hazardous components for labelling: Other Hazards Composition/Information on Ingredients Substance Mixture Chemical Characterization: Information on Components / Hazardous Ingredients: Natural hydraulic lime (H ); REACH Reg. No > 30 % CAS-Nr: EINECS-Nr: EC-Nr: 3

3 Quartz, Silica (SiO2; Xn; R48/20; STOT RE1, H372) Natural calcium carbonate (ca. 97 %) > 25 % > 25 % Page 3 CAS-Nr: EINECS-Nr: EC-Nr: CAS-Nr: EINECS-Nr: EC-Nr: Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Seek medical attention in case of complaints. Supply fresh air. Consult physician if symptoms persist. Remove contaminated clothing immediately. Wash off immediately with soap and plenty of water and rinse thoroughly. Consult a physician immediately. Rinse open eye for several minutes under running water After ingestion: Most important Symptoms and Effects, both Acute and Delayed Do not induce vomiting. Consult physician immediately. Drink plenty of water. Symptoms: Skin contact: can cause skin irritation. Inhalation: can cause irritation of the respiratory tract. Eye contact: causes serious eye damage. Adverse systemic effects are not expected since the ph effect is the major health hazard Effects: No further information available. Indication of any Immediate Medical Attention and special Treatment needed Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: Treat symptomatically. Foam, CO2, dry extinguishing powder. Product itself does not burn. Unsuitable extinguishing media: 4

4 None known Special Hazards arising from the Substance or Mixture Page Special hazards: Advice for Firefighters Protective equipment: Product is not flammable. The substance is not flammable and non-combustible, it inhibits the spread of flames. Wear suitable protective clothing. Wear self-contained respiratory protective device Further information: Not combustible. Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Personal precautions: Environmental Precautions Ensure adequate ventilation. Wear protective clothing. Avoid contact with skin, eyes and clothing Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent spillage of large quantities into drains and surface waters. Contact local authorities if product pollutes soil or vegetation Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Take up mechanically and collect in suitable containers for disposal. Protective clothing, see Section 8. See Section 13 for information on disposal. Wear adequate protective clothing (see para. 8). It is recommended to provide a portable eye rinsing bottle Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Avoid contact with eyes and skin. Do not eat or drink during work. Do not smoke. Storage conditions: Keep container tightly closed Keep product away from children. Requirements for storage areas and 5

5 containers: Store the product in the original container. Unsuitable container material: aluminium. Page 5 Information on fire and explosion protection: Do not store together with: foodstuffs, beverages and feed. Do not store together with acids and nitro compounds. Storage class (VCI): Further Information: Specific End Use(s) Further information: Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): Parameters to be controlled: Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): Hydraulic lime (CAS ): TLV: 1 mg/m3 (inhalable fraction) Hydraulic lime (CAS ): TLV (A): 2 mg/m3 (inhalable fraction) TLV (CH): 5 mg/m3 (inhalable fraction) Hydraulic lime (CAS ): 4 mg/m3 (worker/consumer, inhalation, short-term exposition - local effects) 1 mg/m3 (worker/consumer, inhalation, long-term exposition - local effects) Hydraulic lime (CAS ): Fresh water: 0.49 mg/l Sea water: 0.32 mg/l Sewage treatment system (STP): 3 mg/l Soil: 1080 mg/kg (dw) Additional Information: Exposure Controls Technical protective measures: Provide adequate ventilation/exhaust system. Personal Protection General protective measures: Keep away from foodstuffs and drinks. Do not eat, drink or smoke during work. Wash hands before breaks and at the end of work. Respiratory protection: Required in case of insufficient ventilation. 6

6 Hand protection: Protective gloves (EN 374) Page 6 Protective glove material: Eye protection: Body protection: Nitrile rubber Safety glasses (EN 166) It is recommended to provide a portable eye rinsing bottle. Protective suit with long sleeves Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Prevent contamination of open water ways and sewage system. Avoid contamination of ground water. Form: Color: Odor: Odor threshold: ph-value: Melting temperature: Boiling temperature: Flash point: Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: powder white odorless No information available. not determined not available not available not flammable no information available no information available No information available. Density: 7

7 Solubility in water: dispersible Page Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: Explosive properties: Oxidizing properties: Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: No relative auto-ignition temperature below 400 C (EU A.16 Method) No data available. not determined Product is not explosive. not oxidizing No further information. Stable if used according to specifications. Stable if used according to specifications. Exothermic reaction with acids. No further information available. Thermal decomposition: Avoid heat Imcompatible Materials Reacts with acids: heat development. 8

8 10.6. Hazardous Decomposition Products None known Further Information 11. Toxicological Information Information on Toxicological Effects Page 8 Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Calcium hydroxide: LD50: > 2000 mg/kg bw (rat; OECD 425) Calcium hydroxide: LD50: > 2500 mg/kg bw (rabbit; OECD 402) No information available. Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Irritating (rabbit) Irritating effect (rabbit). No information available. No information available No sensitizing effects known. Not mutagenic (OECD 471 Bacterial Reverse Mutation Test) In vitro Mammalian Cell Gene Mutation Test (OECD 476): negative Not considered to be toxic to reproduction. No cancerogenic effect (rat). No information available. Single exposure: From the data from studies in humans it can be concluded that Ca(OH)2 irritates the respiratory tract. As recommended in the SCOEL (Anonymus, 2008), calcium dihydroxide is classified as irritating to the respiratory tract (R37, Irritating to the resp. system; STOT SE 3 (H335). By analogy, these results can be applied for the product itself. Repeated exposure: no toxicological effects. Additional toxicological information: Aspiration hazard: 9

9 Page Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: Calcium hyroxide: LC50: 457 mg/l (96h; seawater fish) Calcium hyroxide: LC50: 50.6 mg/l (96h; freshwater fish) Calcium hydroxide: LC50: 158 mg/l (96h; Daphnia magna) Calcium hydroxide: EC50: 49.1 mg/l (48h; Daphnia magna) Calcium hydroxide: NOEC: 32 mg/l (14d) At high concentrations, the product causes an increse of the ph value. This effect is used for the purification of sewage sludge. Toxicity to soil dwelling organisms: Calcium hydroxide: EC10/LC50/NOEC: 2000 mg/kg soil dw (macro-organisms) Calcium hydroxide: EC10/LC50/NOEC: mg/kg soil dw (micro-organisms) Calcium hydroxide: EC50: mg/l (72h, freshwater algae) Calcium hydroxide: NOEC: 48 mg/l (72h, freshwater algae) Inorganic substance. Biological degradability is not affected. Bioaccumulation is not to be expected. Weak solubility and mobility. Inorganic substance: does not comply with the criteria for the classification as PBT or vpvb. 1, slightly hazardous Do not allow undiluted product or large quantities of it to reach ground water, waterways or sewage system. Harmful to aquatic organisms caused by a ph shift. Acute ph Effect. Although this product can be used to neutralize acidified water, water organisms can be damaged when 1 g/l is exceeded. The ph value > 12 is rapidly reduced due to dilution and carbonization. AOX Value: 13. Disposal Considerations Waste Treatment Methods 10

10 Page 10 Product: Dispose of product residues according to the waste disposal guidelines 2008/98/EC as well as according to official national and local regulations. European Waste Code (EWC): Uncleaned packaging: Dispose of according to official local regulations. Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: IMDG/IATA: No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel restriction code: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: IATA: Environmental Hazards Special Precautions for User None none known Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information 11

11 Page Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 1, slightly hazardous for water (German Regulation) Local regulations on chemical accidents: Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information This product contains substances for which a Chemical Safety Assessment has been carried out. Seveso Directive: not regulated / Regulation (EC) 850/ Persistent organic pollutants and amending Directive 79/117/EEC: not regulated / Regulation (EC) 2037/ Substances that Deplete the Ozone Layer: not regulated / This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.