Optimized Process Solutions from Feed to Product based on Uhde HTW TM and PRENFLO gasification technologies GTC 2014, Washington, 27.

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1 Optimized Process Solutions from Feed to Product based on Uhde HTW TM and PRENFLO gasification technologies, 27. October, 2014 Max Heinritz-Adrian, Head of Gas Technologies

2 Agenda 1. Introduction ThyssenKrupp Industrial Solutions 2. Optimised Process Chain based on Gasification 3. The TKIS World Gasification Map 4. The BioTfueL Project 5. HTW Darmstadt 6. Summary 2

3 Agenda 1. Introduction ThyssenKrupp Industrial Solutions 2. Optimised Process Chain based on Gasification 3. The TKIS World Gasification Map 4. The BioTfueL Project 5. HTW Darmstadt 6. Summary 3

4 Introduction to ThyssenKrupp Industrial Solutions The new dimension in Plant Engineering Business Area ThyssenKrupp Industrial Solutions Business Unit Marine Systems Process Technologies Resource Technologies System Engineering Submarines Surface Vessels Services Fertilizer/ Coke Plant Technologies Chemicals/Oil& Gas Services Implementation Mining Cement Services Assembly Systems Car Body Technology Lightweight Solutions Forming Dies Testing Solutions Regional Organisations Germany Singapore Australia Canada Qatar II Americas Headquarter V MENA I Europe/CIS III India VI Sub-Saharan Africa Asia Pacific Germany France UK Italy Spain USA Mexico Brazil India China Russia 4

5 Introduction to ThyssenKrupp Industrial Solutions Fullcoal/biomasstoproductsprocesschaincompetencefromasinglesource Resource Technologies: - Mining - Material Handling - Grinding, Milling - Drying, Torrefaction Process Technologies - Gasification Source: STM (BMI) Process Technologies: - Gas Treatment - Product Synthesis 5

6 Agenda 1. Introduction ThyssenKrupp Industrial Solutions 2. Optimised Process Chain based on gasification 3. The TKIS World Gasification Map 4. The BioTfueL Project 5. HTW Darmstadt 6. Summary 6

7 Optimised Process Chain based on gasification requirebestin-classtechnologiesandprocesschainintegration Raw Material Technologies Products Gas Methanol MTG Gasoline LPG Naphtha Reforming Ammonia Urea AN Petcoke Oil Biomass Gasification Syngas (CO+H 2 ) H 2 Fischer- Tropsch Diesel Naphtha DRI Waxes Lubes Coal SNG Wastes IGCC/Power Flexibility in Feedstock and Product Generation 7

8 Optimised Process Chain based on gasification aswellascarefulconsiderationofotherfactors Raw Material Technologies Products Gas Naphtha Reforming Methanol Ammonia MTG Urea Gasoline LPG AN Petcoke Oil Biomass Gasification Syngas (CO+H 2 ) H 2 Fischer- Tropsch Diesel Naphtha DRI Waxes Lubes Coal Wastes SNG Flexibility in Feedstock and Product Generation IGCC/Power - Technologies - Capacity (Economy of Scale) - Process integration and Optimisation - Redundancy and Availability -. 8

9 Optimised Process Chain based on gasification requiredifferenttechnologiesfordifferentfeedstocks 9 PSG PDQ PRENFLO Entrained-Flow HTW Fluidised Bed

10 Optimised Process Chain based on gasification Technologydecisionmatrix Solid Feedstock Liquid/Gas Low Rank Fuels Lignite Peat Biomass High High Reactivity Low Ash Content High Rank Fuels Hard Coal Petcoke Residues Low High Ash Softening Point Low H2 rich / Chemicals Product Gas CO rich / Power HTW PRENFLO PDQ PRENFLO PSG Oil gasificat. 10

11 Agenda 1. Introduction ThyssenKrupp Industrial Solutions 2. Optimised Process Chain based on gasification 3. The TKIS World Gasification Map 4. The BioTfueL Project 5. HTW Darmstadt 6. Summary 11

12 The TKIS World Gasification Map More than 100 gasifiers built, many new projects in different phases Source: STM (GT) 12

13 The TKIS World Gasification Map A.updateA. - New projects include PRENFLO, HTW gasification and fertiliser, methanol, synfuels, synthetic gas - Feedstocks employed in new projects range from biomass to lignite and high-ash coal - Recently a collaboration agreement was signed with Chinese supplier for Proprietary Equipment manufacuring in China 13

14 Agenda 1. Introduction ThyssenKrupp Industrial Solutions 2. Optimised Process Chain based on gasification 3. The TKIS World Gasification Map 4. The BioTfueL Project 5. HTW Darmstadt 6. Summary 14

15 The BioTfueL Project Demonstration of a B-XTL Process Chain Feedstocks Pretreatment Gasification Gas Treatment Synthesis Wood Straw, Residues Coal Petcoke Torrefaction Milling CO-Shift Acid Gas Removal Fine Purification Gasel TM Fischer- Tropsch Synthesis and product upgrading Biodiesel, Biojetfuel Liquid Feeds / FT-Recycle 15 PRENFLO PDQ CO 2 CCS/EOR option - The BioTfueL demonstration project objectives are to develop, demonstrate and commercialize an integrated B-XTL chain for the production of biodiesel and biokerosene - Joint project by IFP/Axens, Total, TKIS, Sofiproteol and CEA

16 Biomass Torrefaction The BioTfueL Project Biomass Torrefaction applying TKIS POLTORR Technology 16

17 The BioTfueL Project EPC Phase has starteda Dunkirk (Total) site overview Milling and Storage Gasification Unit Gas treatment - EPC contracts signed and effective in September Comissioning starts in 2016, start-up beginning Investment in Dunkirk site approx. 110 Mio, in Venette site approx. 12 Mio - EPC for Gasification and Overall site integration by TKIS 17

18 Agenda 1. Introduction ThyssenKrupp Industrial Solutions 2. Optimised Process Chain based on gasification 3. The TKIS World Gasification Map 4. The BioTfueL Project 5. HTW Darmstadt 6. Summary 18

19 HTW Darmstadt New state-of-the-art Pilot Plant for HTW HTW Pilot Plant at Technical University Darmstadt, Germany Fluidized bubbling bed Gasification Agents: O 2 /Steam/CO 2 Gasification Temperature: Fluidized bed: C Freeboard: C Purpose: Feedstock Tests for Clients Tests of new feedstock Design Parameters Further process enhancement Start-up in early

20 Summary ThyssenKrupp Industrial Solutions has more than 70 years commercial experience in gasification and provides full and optimized process chain solutions from a single source Optimised process solutions require carefull consideration of technology selection and process chain integration Best fitting gasification technology has to be selected depending on feedstock and process chain Uhde HTW and PRENFLO gasification technologies provide best-in class technology options for all feedstocks and applications The BioTfueL project has entered EPC realization and will start-up in early 2017 A new HTW pilot plant at TU Darmstadt will start-up in early