Safety data sheet according to U.S.A. Federal Hazcom ULTRAcheck Solids Sample. reference material and/or laboratory reagent

Transcription

1 Handling Composition/information Transport Regulatory Stability Other information. and information. storage. reactivity.... /... >>... on /... >> / >> / ingredients. >>... / >> Page n / 07 Safety data sheet according to U.S.A. Federal Hazcom RCRA Mixtures. Conditions Possibility Transport Code: hazard for of Resource hazardous safe class(es). storage, Conservation reactions. including and any Recovery incompatibilities. Act Code No Keep REL: component(s) hazardous the Recommended product reactions listed. in clearly exposure are labelled foreseeable limitcontainers. normal Keep conditions containers of use away and from storage. any incompatible materials, see section 10 for details. Not Contains: RID: applicable. Regulation concerning the international transport of dangerous goods by train CAA TLV: Specific Conditions 112 Threshold (r) end 1. RMP to use(s). Identification Limit avoid. TQ: Value of the substance/mixture and of the company/undertaking Information None Identification. TLV Packing component(s) CEILING: particular. not group. Concentration listed. However Conc. the that usual %. should precautions Classification: not be exceeded used for chemical during any products time of should occupational be respected. exposure TSCA: Product Toxic identifier Substances Control Act State Not water TWA Incompatible applicable. Regulations. STEL: Shortterm materials. exposure limit Code: Information CAS. TWA: Timeweighted not 8. Exposure average 96 controls/personal 100 exposure limit QCI711 protection Massachussetts: Product VOC: Control Environmental Volatile name parameters. organic hazards. Compounds ULTRAcheck Solids Sample Note: WHMIS: Hazardous component(s) Upper Workplace limit decomposition is listed. not Hazardous included products. into Materials the range. Information System Information Not The Information Relevant applicable. full wording identified not not of hazard uses (H) of phrases the substance is given or in section mixture 16 and of the uses sheet. advised against Minnesota: GERAL BIBLIOGRAPHY: No Intended GHS Exposure Special component(s) rev. use 3precautions listed. 4. controls. for user. reference material and/or laboratory reagent The Merck 11. Index. First Toxicological 10th aid Edition measures. information New 4.1. According Comply Not Handling Details Description applicable. Jersey: of with Chemical the supplier to the of currently safety first Safety of the safety data sheet aid available measures. usually data, this applied product when has handling not chemical yet produced substances. health damages. Anyway, it must be handled carefully according to good No industrial Not HAND Niosh component(s) specifically PROTECTION Registry listed. practices. necessary. of Toxic This Effects product Observance of may Chemical of have good Substances slight industrial health hygiene effects is recommended. on sensitive people, by inhalation and/or cutaneous absorption and/or contact with Name eyes None INRS Transport and/or required. Fiche ingestion. in Toxicologique bulk according (toxicological Annex sheet) II of MARPOL73/78 ULTRA Scientific, and the Inc. IBC Code. New York: 4.2. Full SKIN Patty address Most PROTECTION important Industrial Hygiene symptoms and and Toxicology 250 Smith Street effects, both acute and delayed No District None Information N.I. component(s) Information episodes Sax and required. Dangerous Country not of relevant. listed. damage on toxicological properties health effects. of ascribable Industrial to Materials7, the product 1989 N. have Edition Kingstown (RI) been reported. EYE ECHA PROTECTION website USA Pennsylvania: Tel None Indication component(s) required. 15. of any Regulatory listed. immediate medical attention and special treatment needed. This Information RESPIRATORY 6 NYCRR product part not is not 597 information. Fax PROTECTION considered to be a carcinogen by IARC, ACGIH, NTP, and OSHA. Information None Cal/OSHA address required, not website of the competent person California: unless indicated otherwise in the chemical risk assessment responsible VIRONMTAL California Safety, health Safe for the Drinking Safety and EXPOSURE environmental Water Data Sheet and CONTROLS. Toxic regulations/legislation Enforcement Regulatory@ultrasci.com Act specific for the substance or mixture. The EPA website emissions 5. Firefighting generated by measures. manufacturing processes, including those generated by ventilation equipment, should be checked to ensure Product 5.1. compliance Hazard distribution Comunication 12. Extinguishing with environmental Ecological by Standard media. standards. (HCS information. 2012) ULTRA Scientific, Inc. Proposition 65: U.S. IARC Federal website Use This SUITABLE product Regulations. this product EXTINGUISHING does not according contain EQUIPMT to any good substances working know practices. to the State Avoid of littering. California Inform to cause the cancer, competent reproductive authorities, harm should or birth the defects List Emergency Of Lists EPA: telephone Consolidated numberlist of Chemicals Subject to EPCRA, CERCLA and Section 112 of the Clean Air Act product reach waterways or sewers The extinguishing or contaminate 9. Physical equipment soil or and should vegetation. chemical be of the conventional properties. kind: carbon dioxide, foam, powder and water spray. International Massachussetts Regulations. 105 CMR Department of public health : "Right to Know" UNSUITABLE EXTINGUISHING EQUIPMT TSCA: Substances For Minensota urgent inquiries subject Chapter refer to 5206 to exportation Departemnt reporting Of pursuant Labor and to (EC) US: Industry Reg. (800) Hazardous 649/2012: Substances, Employee "Right to Know" None Information in particular. on basic physical and chemical properties. All New components Jersey Worker are listed and on Community TSCA Inventory. Right know Act Outside N.J.S.A. US: (703) Appearance NTP. Toxicity Report on Carcinogens, 12th Edition. liquid 5.2. Information Colour Special hazards not arising from the substance or mixture. Clean Substances OSHA Air website Act Section 112(b): subject HAZARDS Odour CAUSED 2. Hazards to the Rotterdam BY EXPOSURE identification. Convention: IN THE EVT Not OF FIRE Pennsylvania, component(s) Hazardous listed. Substance List, Chapter Do Odour Persistence not threshold. breathe combustion and degradability. products Classification of the substance or mixture. Clean Information ph. not Substances Air Act subject Section to 602 the Class Stockholm I Substances: Convention: 5.3. Note Melting Advice point for firefighters. / freezing point. The component(s) product for users: is not listed. classified as hazardous pursuant to the provisions set forth in OSHA Hazard Communication Standard (HCS) (29 CFR GERAL The Initial Bioaccumulative boiling INFORMATION point. potential. 100 C. (212 F) ). information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the suitability Clean Candadian Use Information Boiling thoroughness jets Air range. of Act WHMIS. water not Section to of cool 602 provided Class the containers information II Substances: to according prevent product to Not each decomposition specific use of and the the product. development of substances potentially hazardous for health. Always This No Information Flash point. wear full fire prevention gear. Collect > extinguishing 93 C. water to prevent (199.4 it F) from draining into the sewer system. Dispose of contaminated water Hazard component(s) document pictograms: not must listed. not be regarded as a guarantee on any specific product property used The Evaporation Mobility for extinction Rate soil. and the remains of the fire according Not to applicable regulations. Signal use words: of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health and Clean SPECIAL safety Information Flammability Water laws PROTECTIVE and not Act of solids regulations. Priority and Pollutants: EQUIPMT gases The producer FOR is FIREFIGHTERS relieved Not from any liability arising from improper uses. Normal Provide Lower inflammability fire fighting limit. clothing i.e. fire kit (BS Not 469), gloves (BS 659) and boots (HO specification A29 and A30) in combination with component(s) 16. Other listed. information. Hazard statements: appointed staff with adequate training on how to use chemical products selfcontained Upper Results inflammability of PBT open and circuit limit. vpvb positive assessment. pressure compressed air breathing apparatus (BS 137). Clean Information Lower Water explosive not Act limit. Toxic Pollutants: LEGD: Precautionary statements: Upper explosive limit Prevention: Vapour 313 Other CATEGORY pressure. adverse 6. Accidental effects. CODE: Emergency release Planning measures. and Community mmhg Rightto Know Act Section 313 Category Code 6.1. DEA Vapour ADR: Personal List European density I Chemicals Agreement precautions, (Precursor concerning protective Chemicals): the carriage equipment and Not of Dangerous emergency goods by Road Response: procedures. No Information Use Relative CAA component(s) 112 breathing density. not RMP equipment listed. TQ: Risk Management Plan Threshold if fumes or powders are 1.000Quantity released Kg/l (Clean Air Act Section 112 ) into the air. These indications apply for both processing staff and those involved in emergency Solubility CAS NUMBER: Chemical Abstract Service Number Storage: procedures. soluble in water DEA Partition CE50: List Effective II coefficient: Chemicals concentration noctanol/water (Essential Chemicals): (required to induce a 50% effect) 6.2. No Autoignition CERCLA 13. Environmental component(s) RQ: temperature. Reportable Disposal considerations. precautions. listed. Quantity (Comprehensive Not Environment Response, Compensation, and Liability Act) Disposal: The Decomposition CLP: EC Regulation Waste product treatment must temperature. 1272/2008 not methods. penetrate into the sewer system Not or come into contact with surface water or ground water. EPA Reuse, Viscosity DEA: List Drug of Lists: Enforcement Administration when possible. Neat product residues should Not be considered special nonhazardous waste Explosive EmS: Category Emergency Disposal Methods must properties Code: Schedule 2.2. Other hazards. and be material performed containment through an authorised and cleaning waste Not up. management firm, in compliance with national and local regulations. No Confine Oxidising EPA: component(s) US CONTAMINATED using properties Environmental listed. Protection Agency earth PACKAGING or inert material. Collect as much material as possible and eliminate the rest using jets of water. Contaminated material should 9.2. EPCRA: be Contaminated Other disposed information. Emergency Planning and Community Rightto Know Act The product of is packaging not compliance classified must as with be hazardous the recovered provisions for or environment disposed set forth in of pursuant point compliance 13. to the with provisions national set waste forth management in EC Regulation regulations. 1272/2008 (CLP). EPCRA Information EPCRA not EHS EHS TPQ: TPQ: Extremely Hazardous Substance Threshold Planning Quantity (Section 302 Category Code) No EPCRA component(s) 304 EHS listed. RQ: Extremely Hazardous Substance Reportable Quantity (Section 304 Category Code) 6.4. Reference to other sections. EPCRA 313 Any information TRI: Composition/information 10. on Transport Toxics Release Stability personal protection information. Inventory (Section on 313 ingredients. Category Code) and reactivity. and disposal is given in sections 8 and 13. EPCRA GHS: Globally 304 EHS Harmonized RQ: System of classification and labeling of chemicals No IATA Substances. UN component(s) number. DGR: International listed. Air Transport Association Dangerous Goods Regulation Reactivity. IC50: Immobilization 7. Handling Concentration and storage. 50% There are no particular risks of reaction with other substances in normal conditions of use. CERCLA Information IMDG: International RQ: not relevant. Maritime Code for dangerous goods 7.1. No IMO: Precautions component(s) International for listed. safe Maritime handling. Organization Before LC50: UN Chemical proper Lethal handling stability. shipping Concentration the product, name. 50% consult all the other sections of this material safety data sheet. Avoid leakage of the product into the environment. Do The not eat, product drink is or stable smoke in during normal use. conditions of use and storage. EPCRA LD50: Lethal 313 TRI: dose 50% Not OEL: component(s) applicable. Occupational listed. Exposure Level PEL: Predicted exposure level

2 3. Composition/information on ingredients.... / >> Page n. 2 / Mixtures. Contains: Identification. Conc. %. Classification: water CAS Note: Upper limit is not included into the range. The full wording of hazard (H) phrases is given in section 16 of the sheet. 4. First aid measures Description of first aid measures. Not specifically necessary. Observance of good industrial hygiene is recommended Most important symptoms and effects, both acute and delayed. No episodes of damage to health ascribable to the product have been reported Indication of any immediate medical attention and special treatment needed. 5. Firefighting measures Extinguishing media. SUITABLE EXTINGUISHING EQUIPMT The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray. UNSUITABLE EXTINGUISHING EQUIPMT None in particular Special hazards arising from the substance or mixture. HAZARDS CAUSED BY EXPOSURE IN THE EVT OF FIRE Do not breathe combustion products Advice for firefighters. GERAL INFORMATION Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated water used for extinction and the remains of the fire according to applicable regulations. SPECIAL PROTECTIVE EQUIPMT FOR FIREFIGHTERS Normal fire fighting clothing i.e. fire kit (BS 469), gloves (BS 659) and boots (HO specification A29 and A30) in combination with selfcontained open circuit positive pressure compressed air breathing apparatus (BS 137). 6. Accidental release measures Personal precautions, protective equipment and emergency procedures. Use breathing equipment if fumes or powders are released into the air. These indications apply for both processing staff and those involved in emergency procedures Environmental precautions. The product must not penetrate into the sewer system or come into contact with surface water or ground water Methods and material for containment and cleaning up. Confine using earth or inert material. Collect as much material as possible and eliminate the rest using jets of water. Contaminated material should be disposed of in compliance with the provisions set forth in point Reference to other sections. Any information on personal protection and disposal is given in sections 8 and Handling and storage Precautions for safe handling. Before handling the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the environment. Do not eat, drink or smoke during use.

3 7. Handling and storage.... / >> Page n. 3 / Conditions for safe storage, including any incompatibilities. Keep the product in clearly labelled containers. Keep containers away from any incompatible materials, see section 10 for details Specific end use(s). 8. Exposure controls/personal protection Control parameters Exposure controls. Comply with the safety measures usually applied when handling chemical substances. HAND PROTECTION None required. SKIN PROTECTION None required. EYE PROTECTION None required. RESPIRATORY PROTECTION None required, unless indicated otherwise in the chemical risk assessment. VIRONMTAL EXPOSURE CONTROLS. The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure compliance with environmental standards. 9. Physical and chemical properties Information on basic physical and chemical properties. Appearance liquid Colour Odour Odour threshold. ph. Melting point / freezing point. Initial boiling point. 100 C. (212 F) Boiling range. Flash point. > 93 C. (199.4 F) Evaporation Rate Flammability of solids and gases Lower inflammability limit. Upper inflammability limit. Lower explosive limit. Upper explosive limit. Vapour pressure mmhg Vapour density Relative density Kg/l Solubility soluble in water Partition coefficient: noctanol/water Autoignition temperature. Decomposition temperature. Viscosity Explosive properties Oxidising properties 9.2. Other information. 10. Stability and reactivity Reactivity. There are no particular risks of reaction with other substances in normal conditions of use Chemical stability. The product is stable in normal conditions of use and storage.

4 10. Stability and reactivity.... / >> Page n. 4 / Possibility of hazardous reactions. No hazardous reactions are foreseeable in normal conditions of use and storage Conditions to avoid. None in particular. However the usual precautions used for chemical products should be respected Incompatible materials Hazardous decomposition products. 11. Toxicological information. According to currently available data, this product has not yet produced health damages. Anyway, it must be handled carefully according to good industrial practices. This product may have slight health effects on sensitive people, by inhalation and/or cutaneous absorption and/or contact with eyes and/or ingestion Information on toxicological effects. This product is not considered to be a carcinogen by IARC, ACGIH, NTP, and OSHA. 12. Ecological information. Use this product according to good working practices. Avoid littering. Inform the competent authorities, should the product reach waterways or sewers or contaminate soil or vegetation Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects. 13. Disposal considerations Waste treatment methods. Reuse, when possible. Neat product residues should be considered special nonhazardous waste. Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations. CONTAMINATED PACKAGING Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations. 14. Transport information UN number UN proper shipping name.

5 14. Transport information.... / >> Page n. 5 / Transport hazard class(es) Packing group Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code. Information not relevant. 15. Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture. U.S. Federal Regulations. TSCA: All components are listed on TSCA Inventory. Clean Air Act Section 112(b): Clean Air Act Section 602 Class I Substances: Clean Air Act Section 602 Class II Substances: Clean Water Act Priority Pollutants: Clean Water Act Toxic Pollutants: DEA List I Chemicals (Precursor Chemicals): DEA List II Chemicals (Essential Chemicals): EPA List of Lists: 313 Category Code: EPCRA 302 EHS TPQ: EPCRA 304 EHS RQ: CERCLA RQ: EPCRA 313 TRI:

6 15. Regulatory information.... / >> Page n. 6 / 7 RCRA Code: CAA 112 (r) RMP TQ: State Regulations. Massachussetts: Minnesota: New Jersey: New York: Pennsylvania: California: Proposition 65: This product does not contain any substances know to the State of California to cause cancer, reproductive harm or birth defects. International Regulations. Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012: Substances subject to the Rotterdam Convention: Substances subject to the Stockholm Convention: Candadian WHMIS. 16. Other information. LEGD: 313 CATEGORY CODE: Emergency Planning and Community Rightto Know Act Section 313 Category Code ADR: European Agreement concerning the carriage of Dangerous goods by Road CAA 112 RMP TQ: Risk Management Plan Threshold Quantity (Clean Air Act Section 112 ) CAS NUMBER: Chemical Abstract Service Number CE50: Effective concentration (required to induce a 50% effect) CERCLA RQ: Reportable Quantity (Comprehensive Environment Response, Compensation, and Liability Act) CLP: EC Regulation 1272/2008 DEA: Drug Enforcement Administration EmS: Emergency Schedule EPA: US Environmental Protection Agency EPCRA: Emergency Planning and Community Rightto Know Act EPCRA 302 EHS TPQ: Extremely Hazardous Substance Threshold Planning Quantity (Section 302 Category Code) EPCRA 304 EHS RQ: Extremely Hazardous Substance Reportable Quantity (Section 304 Category Code) EPCRA 313 TRI: Toxics Release Inventory (Section 313 Category Code) GHS: Globally Harmonized System of classification and labeling of chemicals IATA DGR: International Air Transport Association Dangerous Goods Regulation IC50: Immobilization Concentration 50% IMDG: International Maritime Code for dangerous goods IMO: International Maritime Organization LC50: Lethal Concentration 50% LD50: Lethal dose 50% OEL: Occupational Exposure Level PEL: Predicted exposure level

7 16. Other information.... / >> Page n. 7 / 7 RCRA Code: Resource Conservation and Recovery Act Code REL: Recommended exposure limit RID: Regulation concerning the international transport of dangerous goods by train TLV: Threshold Limit Value TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. TSCA: Toxic Substances Control Act TWA STEL: Shortterm exposure limit TWA: Timeweighted average exposure limit VOC: Volatile organic Compounds WHMIS: Workplace Hazardous Materials Information System. GERAL BIBLIOGRAPHY: GHS rev. 3 The Merck Index. 10th Edition Handling Chemical Safety Niosh Registry of Toxic Effects of Chemical Substances INRS Fiche Toxicologique (toxicological sheet) Patty Industrial Hygiene and Toxicology N.I. Sax Dangerous properties of Industrial Materials7, 1989 Edition ECHA website 6 NYCRR part 597 Cal/OSHA website California Safe Drinking Water and Toxic Enforcement Act EPA website Hazard Comunication Standard (HCS 2012) IARC website List Of Lists EPA: Consolidated List of Chemicals Subject to EPCRA, CERCLA and Section 112 of the Clean Air Act Massachussetts 105 CMR Department of public health : "Right to Know" Minensota Chapter 5206 Departemnt Of Labor and Industry Hazardous Substances, Employee "Right to Know". New Jersey Worker and Community Right to know Act N.J.S.A. NTP Report on Carcinogens, 12th Edition. OSHA website Pennsylvania, Hazardous Substance List, Chapter 323 Note for users: The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the suitability and thoroughness of provided information according to each specific use of the product. This document must not be regarded as a guarantee on any specific product property. The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health and safety laws and regulations. The producer is relieved from any liability arising from improper uses. Provide appointed staff with adequate training on how to use chemical products.