Supertough 32ST05S01 Innovative Technology Polyethylene Blown Film Grade

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1 Supertough 32ST05S01 Innovative Technology Polyethylene Blown Film Grade Sankt Augustin Germany July th, 2012 B. Riquet F. Fant

2 OUTLOOK 1. Presentation of Total with accent on Polyolefins 2. New development, Supertough 32ST05 3. Some case studies with Supertough 32ST05

3 AT A GLANCE

4 01 TOTAL > ENERGY IN MOTION Total is a leading international oil and gas company. We operate in more than 130 countries and all oil industry segments. We are much more than an oil company. We are a full-fledged energy company: diversification in solar energy, biomass, etc.

5 FOSSIL ENERGIES TO REPRESENT 76% OF ENERGY SUPPLY IN 2030 WORLD ENERGY SUPPLY Mboe/d* Solar, wind, others Hydro Biomass excl biofuels Biofuels Nuclear 4% 3% 10% 1% 6% 2010 Fossil energies represent 81% incl.: Oil: 33% Gas: 22% Coal: 26% Coal Gas Oil 2030 Fossil energies represent 76% incl.: Oil: 30% Gas: 24% Coal: 22% EFFICIENT CO2 EMISSIONS MANAGEMENT AND DIVERSIFICATION OF ENERGY SUPPLY ARE KEY ISSUES.* Million barrels of oil equivalent per day. Source: Total estimates after Fukushima accident 5

6 TRANSPORTATION FUELS AND POLYMER DEMAND KEEPS GROWING WHILE OIL PRODUCTION WILL PEAK WORLD DEMAND, INDEX % OF OIL USE BY APPLICATION Average Growth Rate % 3.2% 2.0% 1.3% Polymer GDP Mbd 15% 10% 31% 5% 26% Power generation Residential/ other industries % 56% Transportation fuels 300 Transportation fuel Crude oil % 41% 13% 4% 8% Petrochemicals Source: TOTAL OIL CUTS WILL BE PREFERABLY USED FOR PETROCHEMICALS AND TRANSPORTATION FUELS, WHERE SUBSTITUTION WITH ALTERNATIVE ENERGY SOURCES IS THE MOST DIFFICULT 6

7 02 REFINING & CHEMICALS within TOTAL AN INTEGRATED BUSINESS MODEL UPSTREAM World s 5 th largest oil & gas producer Production: 2.38 million boe/d SUPPLY & MARKETING # 1 in Europe l Network : service stations REFINING & CHEMICALS A world-class player # 1 refiner in Europe Proven reserves: 10.7 billion boe Sales :2.5 million boe/d Among the leaders in each activity

8 KEY FIGURES OF THE REFINING & CHEMICALS BUSINESS 50,600 employees Including: France 17,300 Belgium 3,300 Other Europe 13,200 China 3,400 Other Eastern 1,900 RoW 700 America 10,800 The industrial setup Interests in 13 refineries, including 9 directly operated plants. The production capacities 2.1 Mb/d* refining capacity, i.e. 103 Mt/y 21 petrochemical production sites 11 steamcrackers at 9 production sites 5 being integrated into the refineries. More than 150 locations worldwide in specialty chemicals and fertilizers. 6.3 Mt polymer production capacity (PS, PP, PE) 4 Mt of ethylene production capacity * Total Group capacity, including 0.15 Mb/d for Supply & Marketing All data at , except Ethylene: March 2012

9 MAJOR INTEGRATED PLATFORMS Refinery Refinery + Petrochemicals complex Petrochemicals Plant CTO project La Porte, Texas Bayport, Texas Carville, Louisiana Dalian China Foshan China Singapore Port Arthur Normandy Antwerp Jubail Qatar Daesan 9

10 03 Polymers The THERMOPLASTICS Triangle World market rankings # 2 for PS # 4 for PP # 13 for PE High Tech Polymers Engineering Plastics Standard Plastics EPS 2% PET 7% PS 8% <<1 % < 10 % ca 90 % PP 23% PE 35% PVC 18% Core business PE, PP & PS About 6,000 employees worldwide

11 POLYMERS EUROPE - ASSETS DAESAN, S. Korea LDPE / EVA HDPE LLDPE BAYPORT, Tx (50% TP 50% Samsung) HDPE CARVILLE, LA PS QATAR, Qatar LLDPE 1,5 MT PS 1,5 MT PE 2,5 MT PP ANTWERP, B FELUY, B mpe, MDPE, HDPE CARLING, F LDPE GONFREVILLE, F PO plant Ethylene plant Ethylene Pipeline mpe, MDPE, HDPE MR, PPH, PPC, PPR LDPE (Qapco 20% TP) PS Foshan, China PS EVA, MDPE, HDPE PPH, PPC Singapore PS PS LAVERA, F PPH, PPR Stalybridge, UK PS Prat de L.lobregat, E PS

12 TOTAL S COMPLETE RANGE OF POLYOLEFINS RESINS FOR FILM HD & MDPE BIMODAL EVA LDPE LLDPE PP cast mpe PP blown INTRODUCTION GROWTH MATURITY HDPE & MDPE mpe (C6) EVA LDPE PP LLDPE (C4) Bimodal HDPE Total Petrochemicals commitment to the film market 12

13 STRATEGY: METALLOCENE IN ADDED VALUE APPLICATIONS M 1810 EP M1810EP M1811PCE M6012EP Density d = Melt 1.0 M 5510 EP M 2310 EP M 4707 EP M 2710 EP M 2704 EP M 3410 EP 13

14 WHAT NEXT? SUPERTOUGH 32ST05S01 Innovative Technology Polyethylene Blown Film Grade

15 TODAY S AND FUTURE MARKET DRIVERS? Innovative and Efficient Multilayer Structures Down-Gauging Optimized Production Process 15

16 Innovative and Efficient Multilayer Structures Down-Gauging Optimized Production Process 16

17 INNOVATIVE AND EFFICIENT MULTILAYER STRUCTURES Innovative multi layer structures need no compromise in raw material, each layer has to bring one functionality Example of 7 layer structure SuperTough 32ST05 brings the Toughness! 17

18 Innovative and Efficient Multilayer Structures Down-Gauging Optimized Production Process 18

19 SUPERTOUGH BRINGS HIGH DOWN-GAUGING POTENTIAL

20 Down-Gauging Potential = Dart [gr] x Tensile at Yield TD [Mpa] SuperTough brings Double-digit thickness reduction 20 All grades processed on a blown-line in LDPE configuration with same processing parameters: 60RPM - Die diameter 120mm - Die gap 1.4mm - BUR µm film thickness

21 Innovative and Efficient Multilayer Structures Down-Gauging Optimized Production Process 21

22 OPTIMIZED PRODUCTION PROCESS Packaging Integrity Defect Free Lamination Flexibility of Sealing Line 22

23 HIGH BUBBLE STABILITY WITH EXCELLENT THICKNESS CONTROL SuperTough offers LDPE-like processability! 23 All grades processed on blown-line in LDPE configuration with same processing parameters: 60RPM - Die diameter 120mm - Die gap 1.4mm - BUR µm film thickness

24 HIGH OUTPUT WITHOUT PRESSURE LIMITATION Max output defined as Output with 10% of 2-sigma thickness repartition 24 All grades processed on a blown-line in LDPE configuration with same processing parameters: Die diameter 120mm - Die gap 1.4mm - BUR µm film thickness

25 SuperTough Brings Packaging Integrity Down-Gauging Potential 25

26 SuperTough brings Down-Gauging potential without compromising the processing Down-Gauging potential = Dart [gr] x Tensile at Yield TD [Mpa] Ease of process = Output / 2-sigma 26

27 CASE STUDIES WITH SUPERTOUGH 32ST05S01 Innovative Technology Polyethylene Blown Film Grade

28 CASE STUDY MATTRESS COVER Main Requirements Good mechanics High sealing strength to hold mattress compression Good slow puncture resistance (abuse resistance, grapping pack) Broad sealing window Mattress cover film based on SuperTough formulation from 80µm to 60 µm 40% of SuperTough in the structure brings 25% of downgauging potential 28

29 CASE STUDY DEEP FREEZE PACKAGING Main Requirements Outstanding Toughness Rigidity balance even at low temperature Broad sealing window High hot-tack strength Excellent optics & printability Good organoleptics, low volatiles SuperTough 32ST05 brings Better packaging integrity thanks to extra dart drop of the core layer Potential down-gauging of 10% vs. standard market 29

30 CASE STUDY COLLATION SHRINK Main Requirements High mechanics Excellent optics Well balanced shrinkage 3-layer structure vs 5-layer structure 3-layer formulation (A/B/A) in 15/70/15 A: 100% M2710EP B: 55% SuperTough 32ST % LD % 2008SN60 5-layer formulation (A/B/C/B/A) in 10/20/40/20/10 A: 100% M2710EP B: 100% SuperTough 32ST05 C: 55% LD % 2008SN60 Same overall composition and same thickness (35µm) for both structures 30

31 Comparison of the 5-layer structure vs 3-layer 17% gain of Impact Resistance (dart drop) with the 5-layer structure Other properties are similar 31

32 Thanks! 32

33 DISCLAIMER These information are provided for General Information for the use of the addressee only, it should not be given to a third party without prior approval form TOTAL. To the best of our knowledge and at the time of publication, this information are true and accurate. It shall, however, in no event be held to constitute or imply any warranty, undertaking express or implied commitment from our part. The companies within TOTAL disclaim any liability that may be claimed for infringement or alleged infringement of patents. LUMICENE is a registered trademark of PETROFINA / TOTAL PETROCHEMICALS or TOTAL Group 33

34 ANNEX

35 35 PROPERTY COMPARISON FOR A GIVEN TENSILE STRENGTH

36 SHRINK PROPERTIES: SuperTough offers Superior shrinkability 36 Shrink tests are performed in an oven: Temperature: around 135 C - 40µm film thickness - Retraction force is measured at oven temperature - Holding force is measured at 23 C