Interim Final. Section 9 Supplemental Guidance for Select Contaminants of Concern APPENDIX 9-A GENERAL PESTICIDE INFORMATION

Transcription

1 Interim Final Section 9 Supplemental Guidance for Select Contaminants of Concern APPENDIX 9-A GENERAL PESTICIDE INFORMATION Hawai i HEER TGM 9-A April 2014

2 Table 9-A General Pesticide Information Ametryn Triazine 8141 or 619M Yes 4.5E E+02 5 Arsenic Atrazine Benomyl Bromodichloromethane Bromomethane Captafol Captan Chlordane (Technical) Chlorpyrifos Dalapon Diazinon Carbamates 8321 Yes 5.2E E+02 6 Moderately persistent fungicide used for seed dipping. Used since the 1970s. VOCs 8260 Yes 3.5E E+00 3 Fumigant with low VOCs 8260 Yes 1.4E E+01 2 Fumigant with low 8081 or 8270 Yes 2.7E E+00 8 Fumigant with low SVOCs 8270 Yes 8.6E E+00 8 Fumigant with low Moderately persistent insecticide Yes 8.7E E+02 8 Cancelled in Yes 6.8E E+01 1 Moderately persistent insecticide used since the 1970s. Low to moderately persistent herbicide 8151 or 8321 Yes 2.7E E+01 8 used since the 1950s. Dibromo-3- Chloropropane, 1,2- Dibromochloromethane on Page 9-A-7 Heavy Metals 6010B/ 6020 Yes? na - Highly persistent herbicide component. Triazine 8141 or 619M Yes 2.3E E Yes 1.3E E+01 8 VOCs 8260 or 8081 Yes 1.3E E+02 1 VOCs 8260 Yes 3.5E E+02 2 Moderately persistent insecticide broadly used since the 1960s (possibly earlier). Moderately persistent (although volatile) fumigant broadly used from the 1940s through 1980s. Moderately persistent pesticide; unknown if used in cultivation. Hawai`i HEER TGM 9-A-1 April 2013

3 Table 9-A (continued) Dibromoethane, 1,2- Dicamba Dichlorodiphenyldichloroethane (DDD) Dichlorodiphenyldichloroethylene (DDE) Dichlorodiphenyltrichloroethane (DDT) Dichlorophenol, 2,4- Dichlorophenoxyacetic Acid (2,4 D) Dichloropropane, 1,2- Dichloropropene, 1,3- Dioxins/Furans Diuron Endosulfan on Page 9-A-7 VOCs 8260 Yes 4.4E E or 8321 Yes 2.9E E or 8270 Yes 1.5E E or 8270 Yes 1.5E E or 8270 Yes 2.2E E+02 8 SVOCs 8270 Yes 7.2E E+00 1 Moderately persistent (although volatile) fumigant broadly used from the 1940s through 1980s. Herbicide with low to moderate Highly persistent impurity of DDT insecticide. Highly persistent impurity of DDT insecticide. Moderately persistent insecticide. Used by State for mosquito control until banned in Intermediate product of 2,4-D and other herbicides with low 8151 or 8321 Yes 7.2E E+01 8 Herbicide with low 8151 Yes 6.8E E+02 8 Moderately persistent (although volatile) fumigant used from the 1940s to Yes 8.1E E+01 8 Fumigant with low Dioxins/furans 8280/8290 Yes 2.6E E+04 1 Carbamates 8321 Yes 1.4E E+01 8 Highly persistent impurity of chlorinated phenol pesticides (pentachlorophenol; 2,4,5-T; 2,4,5- TP) or 8270 Yes 2.2E E Pesticide with moderate Hawai`i HEER TGM 9-A-2 April 2013

4 Table 9-A (continued) Ethephon Glyphosate Heptachlor Heptachlor Epoxide Hexachlorocyclohexane, Gamma Hexazinone Lead Malathion Mercury Methyl Mercury Methyl Sulfanilcarbamate Metribuzin on Page 9-A-7 SVOC 8270 Yes 3.6E E+00 7 Growth regulator with low Other 547 Yes 1.9E E+01 - Herbicide with low to moderate persistence (beaks down in water). Moderately persistent insecticide and component of technical chlordane or 8270 Yes 5.2E E+02 8 Cancelled in Potentially used in fields with drip irrigation between 1979 & Highly persistent component of 8081 or 8270 Yes 5.3E E+02 - technical chlordane or 8270 Yes 3.4E E Moderately persistent insecticide. Triazine 8141 Yes 6.1E E+02 7 Moderately persistent herbicide used since the 1970s. Heavy Metals 6010B/ 6020 Yes? na - Unknown if lead-based insecticides, herbicides, & rodenticides used in cultivation. Highly persistent. Organo- Insecticide with low Used phosphorus 8141 or 8270 Yes 3.1E E+00 7 Highly persistent fungicide (seed Heavy Metals 7471 Yes 1.7E+02? - dipping). All food uses cancelled in Heavy Metals 7471 Yes?? - Methylated form of mercury generated in reducing environments; potential byproduct. Carbamates 8321A Yes 1.2E E+01 - Herbicide used since the 1970s. Low to moderate Triazine 8141 Yes 1.2E E+02 7 Highly persistent herbicide used since the 1970s. Hawai`i HEER TGM 9-A-3 April 2013

5 Mirex Oxamyl Parathion Pentachlorophenol Picloram Propiconazole Simazine Terbacil Tetrachlorophenol, 2,3,4,6- Trichlorophenoxyacetic Acid, 2,4,5- (2,4,5 T) Trichlorophenoxypropioni c Acid, 2,4,5- (2,4,5 Tp) Trichloropropene, 1,2,3- (TCP) Trifluralin on Page 9-A-7 Highly persistent insecticide. Very 8081 or 8270 Yes 4.7E E+02 - limited use in Hawai'i. Not sold in US since Carbamates 8321 Yes 1.0E E+01 7 Insecticide with low SVOCs or 8141 or 8270 Yes 1.7E E or 8151 Yes 3.4E E Yes 1.8E E+02 7 Carbamates 8321 Yes 5.6E E+01 7 Triazine 8141 or 619M Yes 1.5E E+02 8 Organonitrogen 633 Yes 7.8E E+02 7 SVOCs 8270 Yes 2.0E E or 8321 Yes 1.2E E or 8321 Yes 4.9E E VOCs 8260 Yes 1.3E E+01 - Table 9-A (continued) 8081 or 8270 Yes 9.7E E+01 8 Highly persistent insecticide. Registration cancelled in Herbicide used from 1960s (possibly earlier) until the mid-1980s. Low to moderate Moderately persistent sugarcane herbicide used since the 1960s (possibly earlier). Moderately persistent fungicide. Used since the 1980s. Highly persistent herbicide. Limited used since the 1970s; not significantly toxic. Component of pentachlorophenol with low to moderate Moderately persistent herbicide. Suspended in Herbicide with low Suspended in Impurity in 1,3 dichloropropene with low to moderate since the 1980s. Hawai`i HEER TGM 9-A-4 April 2013

6 Used But No Toxicity Data And/Or No Method Amitrole Other? No 2.0E E+01 4 Herbicide used pre-1971 with low Herbicide used in the 1960s until Ammonium Sulfamate Other? Yes?? - possibly the 1980s; assumed low Bromacil Carbamates 8321 No 9.3E E+02 3 since the 1960s. Chloropicrin Other No 5.1E E+00 8 Fumigant with low Dichloropropene, 2, No 8.1E E+01 8 Fumigant with low Diphacinone Other? No 5.0E E+02? Rodenticide with moderate to high Diquat Other? Yes 1.9E E+03 8 Highly persistent growth regulator. Endrin Aldehyde 8081 or 8270 No 1.1E E+02 8 Highly persistent impurity of Endrin. Fenaminosulf Other? Yes 1.0E E+01 8 Fungicide with low Fenamiphos 8141 No 2.3E E+00 8 Nematicide with low Fenthion 8141 or 8270 No 1.1E E+01 8 Moderately persistent insecticide used since the 1960s. Fosetyl-Aluminum Hydramethylnon Mancozeb Monuron Paraquat on Page 9-A-7 Table 9-A (continued) Other? Yes 5.3E E-01 8 Fungicide with low Other? No 6.3E+08? - Insecticide (ant control) with unknown Other? Yes 1.0E E+00 7 Fungicide with low Carbamates 8321 No? 1.0E+02 - Other? Yes 1.4E E Herbicide with moderate Registration cancelled in Highly persistent herbicide. Used since the 1960s. Hawai`i HEER TGM 9-A-5 April 2013

7 Table 9-A (continued) Pindone Quizalofop-P-Ethyl Sodium Chlorate Sodium Monofluoracetate Sodium Trichloroacetate Sulfometuron-Methyl Temephos Other? No 2.8E+01? - Other? No 5.4E E+01 3 Rodenticide with unknown from the 1980s until present. Other? No 1.0E+00? - Herbicide with unknown Other? Yes 1.2E+00? - Other? No 1.0E+00? - Carbamates (modified) Rodenticide with unknown Used in 1960s until unknown time. Herbicide with unknown Used in the 1960s until unknown time. 8321Mod No 7.8E E+01 7 Herbicide with low Other? Yes 1.6E+06? - Insecticide with unknown Used in the 1960s until unknown time. on Page 9-A-7 Hawai`i HEER TGM 9-A-6 April 2013

8 : * analytical method used to categorize pesticides may not match actual pesticide chemical category. ** Toxicity value availability noted as "Yes" if listed in May 2008 USEPA Regional Screening Levels guidance (USEPA, 2008). values from same reference. *** References. The number in the column above corresponds to the references shown below Table 9-A (continued) Montgomery, J.H Groundwater s. Desk Reference (3rd Ed). Mackay, Shiu, Ma Illustrated Handbook of Physical- Properties and Environmental Fate for Organic s. Extonet. Available online at: USEPA. Reregistration Eligibility Decision - Amitrole. List A. Case ( Spectrum. fact Sheet - Ametryn ( Benomyl fact Sheet. News No.35, March 1997, p20-21 ( ARS Pesticide Properties Database ( Knisel & Davis Groundwater Loading Effects of Agricultural Management Systems. Toxicological Profile for Pentachlorophenol. ATSDR Spectrum fact Sheet - 2,4,5-Trichlorophenoxyacetic Acid. Spectrum fact Sheet - 2,4,5-Trichlorophenoxypropionic Acid. Extoxnet - Lindane (BHC). Available online at Extoxnet - Parathion. Available online at Extoxnet - Paraquat. Available online at Toxnet HSDB. Available online at Hawai`i HEER TGM 9-A-7 April 2013