Product Description. Hazard Identification

Transcription

1 CARBOL XYLOL Section 1 Product Name: Recommended Use: Synonyms: Distributor: Chemical Information: Chemtrec: Section 2 Product Description CARBOL XYLOL Science education applications Carbol Xylene Carolina Biological Supply Company 2700 York Road, Burlington, NC (8am-5pm (ET) M-F) (Transportation Spill Response 24 hours) Hazard Identification Classification of the chemical in accordance with paragraph (d) of ; DANGER Flammable liquid and vapor. Harmful in contact with skin. Causes severe skin burns and eye damage. Causes serious eye damage. Suspected of causing genetic defects. Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. Toxic to aquatic life. GHS Classification: Skin Corrosion/Irritation Category 1B, Serious Eye Damage/Eye Irritation Category 1, Germ Cell Mutagenicity Category 2, Carcinogenicity Category 2, Specific Target Organ Systemic Toxicity (STOT) - Repeated Exposure Category 2, Hazardous to the aquatic environment - Acute Category 2, Flammable Liquid Category 3, Acute Toxicity - Dermal Category 4 Other Safety Precautions: IF exposed or concerned: Get medical advice/attention. Section 3 Composition / Information on Ingredients Chemical Name CAS # % m-xylene Phenol Ethylbenzene o-xylene p-xylene Section 4 First Aid Measures Emergency and First Aid Procedures Inhalation: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Eyes: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Skin Contact: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF ON SKIN: Wash with plenty of soap and water. Wash contaminated clothing before reuse. Ingestion: Section 5 Extinguishing Media: IF SWALLOWED: rinse mouth. Do NOT induce vomiting. Firefighting Procedures Use dry chemical, CO2 or appropriate foam. CARBOL XYLOL Page 1 of 5

2 Fire Fighting Methods and Protection: Fire and/or Explosion Hazards: Hazardous Combustion Products: Section 6 Firefighters should wear full protective equipment and NIOSH approved self-contained breathing apparatus. Above flashpoint, explosive vapor-air mixtures may be formed. Heating may cause an explosion. Vapors may travel back to ignition source. Closed Containers exposed to heat may explode. Carbon dioxide, Carbon monoxide Spill or Leak Procedures Steps to Take in Case Material Is Released or Spilled: Section 7 Exposure to the spilled material may be irritating or harmful. Follow personal protective equipment recommendations found in Section 8 of this SDS. Additional precautions may be necessary based on special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred. Also consider the expertise of employees in the area responding to the spill. Exposure to the spilled material may be severely irritating or toxic. Follow personal protective equipment recommendations found in Section 8 of this SDS. Personal protective equipment needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Ventilate the contaminated area. Prevent the spread of any spill to minimize harm to human health and the environment if safe to do so. Wear complete and proper personal protective equipment following the recommendation of Section 8 at a minimum. Dike with suitable absorbent material like granulated clay. Gather and store in a sealed container pending a waste disposal evaluation. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Block any potential routes to water systems. Handling and Storage Handling: Storage: Storage Code: Section 8 Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ / equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Wash thoroughly after handling. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. Avoid direct sunlight and heat. Toxic by inhalation and if swallowed. Keep away from sources of ignition - smoking. Do not breathe gas/fumes/vapor/spray. Avoid contact with skin and eyes. Take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty of water. Keep container tightly closed in a cool, well-ventilated place. Use only in well-ventilated areas. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Store locked up. Keep container tightly closed in a cool, well-ventilated place. Red - Flammables. Store in approved flammable containers. Store away from oxidizing materials. Protection Information ACGIH OSHA PEL Chemical Name (TWA) (STEL) (TWA) (STEL) m-xylene 100 TWA 150 STEL 100 TWA; 435 Phenol 5 TWA 5 TWA; 19 Ethylbenzene 20 TWA 100 TWA; 435 o-xylene 100 TWA 150 STEL 100 TWA; 435 p-xylene 100 TWA 150 STEL 100 TWA; 435 Control Parameters Engineering Measures: Personal Protective Equipment (PPE): Respiratory Protection: Respirator Type(s): Local exhaust ventilation or other engineering controls are normally required when handling or using this product to avoid overexposure. Lab coat, apron, eye wash, safety shower. respiratory protection required under normal conditions of use. ne required where adequate ventilation is provided. If airborne concentrations are above the applicable exposure limits, use NIOSH/MSHA approved respiratory protection. NIOSH approved air purifying respirator with organic vapor cartridge and HEPA filter. CARBOL XYLOL Page 2 of 5

3 Eye Protection: Skin Protection: Gloves: Section 9 Wear chemical splash goggles when handling this product. Have an eye wash station available. Avoid skin contact by wearing chemically resistant gloves, an apron and other protective equipment depending upon conditions of use. Inspect gloves for chemical break-through and replace at regular intervals. Clean protective equipment regularly. Wash hands and other exposed areas with mild soap and water before eating, drinking, and when leaving work. Nitrile, Nitrile - Extra Thick (8 mm), Neoprene, Butyl rubber Physical Data Formula: See Section 3 Vapor Pressure: Molecular Weight: Evaporation Rate (BuAc=1): Appearance: Colorless Cloudy (milky) Vapor Density (Air=1): Odor: Strong Aromatic Acrid aromatic Sweet Specific Gravity: Odor Threshold: 6 mg/m3 Solubility in Water: ph: data available Log Pow (calculated): Melting Point: C Autoignition Temperature: data available Boiling Point: C Decomposition Temperature: data available Flash Point: 29 C Viscosity: data available Flammable Limits in Air: LEL 1% UEL 7% Percent Volatile by Volume: 75% Section 10 Reactivity: Chemical Stability: Conditions to Avoid: Incompatible Materials: Hazardous Decomposition Products: Hazardous Polymerization: Section 11 Reactivity Data data available Stable under normal conditions. Temperatures above flash point in combination with sparks, open flames, or other sources of ignition. Elevated temperatures Oxidizing materials, Acetaldehydes, Mineral acids, Metals Carbon dioxide, Carbon monoxide Will not occur Toxicity Data Routes of Entry Symptoms (Acute): Delayed Effects: Inhalation, Ingestion, and Skin contact. data available Acute Toxicity: Chemical Name CAS Number Oral LD50 Inhalation LC50 m-xylene Oral LD50 Rat 4988 mg/kg Phenol Oral LD50 Rat 512 mg/kg Ethylbenzene Oral LD50 Rat 3500 mg/kg Rabbit UL/KG Rabbit 630 mg/kg Rabbit > 5000 mg/kg LC50 Mouse 5267 LC50 Rat 316 MG/M3 LC50 Rat MG/M3 LC50 Mouse MG/M3 LC50 Rabbit 4000 CARBOL XYLOL Page 3 of 5

4 o-xylene Oral LD50 Rat 3567 mg/kg p-xylene Oral LD50 Rat 3910 mg/kg LC50 Mouse 4595 Carcinogenicity: Chemical Name CAS Number IARC NTP OSHA m-xylene t listed t listed t listed Phenol t listed t listed t listed Ethylbenzene Listed t listed Listed o-xylene t listed t listed t listed p-xylene t listed t listed t listed Chronic Effects: Mutagenicity: Evidence of a mutagenic effect. Teratogenicity: evidence of a teratogenic effect (birth defect). Sensitization: evidence of a sensitization effect. Reproductive: evidence of negative reproductive effects. Target Organ Effects: Acute: See Section 2 Chronic: Certain components or species of this product are considered potential carcinogens., Reproductive data cited. Section 12 Ecological Data Overview: Mobility: Persistence: Bioaccumulation: Degradability: Other Adverse Effects: This material is not expected to be harmful to the ecology. data Evaporation into atmosphere, Biodegradation, Adsorbs to soil. data data data Chemical Name CAS Number Eco Toxicity m-xylene HR EC50 PSEUDOKIRCHNERIELLA SUBCAPITATA 4.9 Phenol HR LC50 BRACHYDANIO RERIO HR LC50 LEPOMIS MACROCHIRUS HR LC50 ONCORHYNCHUS MYKISS HR LC50 PIMEPHALES PROMELAS HR EC50 DAPHNIA MAGNA HR EC50 PSEUDOKIRCHNERIELLA SUBCAPITATA Ethylbenzene HR LC50 POECILIA RETICULATA HR LC50 LEPOMIS MACROCHIRUS HR EC50 DAPHNIA MAGNA HR EC50 PSEUDOKIRCHNERIELLA SUBCAPITATA > HR EC50 PSEUDOKIRCHNERIELLA SUBCAPITATA 4.6 o-xylene Aquatic LC50 (96h) Guppy 12 Aquatic EC50 (48h) Daphnia HR EC50 PSEUDOKIRCHNERIELLA SUBCAPITATA HR EC50 PSEUDOKIRCHNERIELLA SUBCAPITATA 4.2 p-xylene Aquatic LC50 (96h) Rainbow Trout HR EC50 PSEUDOKIRCHNERIELLA SUBCAPITATA HR EC50 CHLORELLA VULGARIS CARBOL XYLOL Page 4 of 5

5 Section 13 Disposal Methods: Waste Disposal Code(s): Section 14 Disposal Information Dispose in accordance with all applicable Federal, State and Local regulations. Always contact a permitted waste disposer (TSD) to assure compliance. t Determined Transport Information Ground - DOT Proper Shipping Name: UN1307 (Xylene); UN1671 (Phenol); Description: Flammable liquid, toxic, N.O.S. (xylene, phenol), 3, III Section 15 Air - IATA Proper Shipping Name: t regulated for air transport by IATA. Regulatory Information TSCA Status: All components in this product are on the TSCA Inventory. Chemical Name CAS Number 313 Name 304 CERCLA 302 TPQ CAA 112(2) TQ m-xylene m-xylene 1000 lb final Phenol Phenol 1000 lb Ethylbenzene Ethylbenzene 1000 lb 1000 lb final 1000 lb final o-xylene o-xylene 1000 lb final p-xylene p-xylene 100 lb ; 45.4 kg final 500 lb lower TPQ; lb upper TPQ California Prop 65: Section 16 WARNING: This product contains a chemical known to the state of California to cause cancer, birth defects or other reproductive harm. Additional Information Revised: 09/03/2014 Replaces: 08/27/2014 Printed: The information provided in this (Material) Safety Data Sheet represents a compilation of data drawn directly from various sources available to us. Carolina Biological Supply makes no representation or guarantee as to the suitability of this information to a particular application of the substance covered in the (Material) Safety Data Sheet. Glossary ACGIH CAS CERCLA DOT IARC American Conference of Governmental Industrial Hygienists Chemical Abstract Service Number Comprehensive Environmental Response, Compensation, and Liability Act U.S. Department of Transportation International Agency for Research on Cancer t Available NTP OSHA PEL RCRA SARA TLV TSCA IDLH National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Parts per million Resource Conservation and Recovery Act Superfund Amendments and Reauthorization Act Threshold Limit Value Toxic Substances Control Act Immediately dangerous to life and health CARBOL XYLOL Page 5 of 5