Powder Coating Resins and Additives

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1 Powder Coating Resins and Additives

2 Powder Coatings Easy to use, minimal VOC and cost effective, powder coating has emerged in recent decades as a most desirable method for protecting various substrates. Its high transfer efficiency and largely recoverable overspray make powder coating especially suitable for three-dimensional shapes, such as aluminum window frames, household appliances and transportation components. By producing our powder resins in Europe, Synthomer satisfies the needs of its global and regional customer base. Our broad range of powder resin options can be tailor-formulated to meet manufacturers performance and regulatory criteria. Our products are available either for tribo/gas oven and organo tin free upon specific request. The s You Need Synthomer line of resins features both carboxyl and hydroxyl-terminated polyester resins. Carboxyl-terminated polyester resins offer polymers for Indoor (hybrid systems) and Outdoor applications (standard and superdurable). Hydroxyl-terminated polyester resins are designed for use in non-emitting polyesterurethane systems for special-effect architectural, anti-graffiti and transportation applications. Albecor resins are our newest polyester powder-coating products, specifically designed for low thermal curing. The lower temperature cure facilitated by Albecor powder coating resins increases energy efficiency and allow the application on heat sensitive subtrates. Synthomer produces SilkyMatt resins, a full range spec i- fically designed for low gloss applications. The fruit of over 25 years of experience in low gloss research and development, SilkyMatt resins are the ultimate for quality and consistency in low gloss powder coatings. Innovation You Can Trust The products listed in this guide are just a representative selection from Synthomer s broad portfolio. Building on this portfolio, our highly experienced R&D and technical service specialists will help address your toughest coating challenges. We are committed to meeting your requirements as quickly and completely as possible. For more information, contact your Sales or Business Development Representative. Coding System Resins 2 Hybrid Polyesters / SilkyMatt Resins 3 Hydroxyl Polyesters / SilkyMatt Resins 5 Outdoor durable Polyesters / SilkyMatt Resins 6 Superdurable Polyesters Albemast Resins 9 Masterbatches Albecor Resins 1 Low Thermally cured resins Outdoor durable Albecor Resins 4 Low Thermally cured resins Indoor applications 0 Standard Resin Organo tin free version is available upon request. 1 Tribo Resin 3

3 Polyester Resins for Low Temperature Cure for Exterior Use Typically cured with ß-hydroxy alkyl amide Cone & Plate Albecor min at 140 C Albecor min at 140 C Specifically designed for low temperature cure applications starting from 140 C, in 93:7 ß-HAA ratio. It combines very good reactivity along with excellent weathering and blooming resistance. Possible uses are on Architectural, parts of heavy mass, ACE, earth moving equipment. Specifically designed for low temperature cure applications starting from 140 C, in 93:7 ß-HAA ratio. It combines excellent reactivity along with good weathering and blooming resistance. Possible uses can be on heavy mass, ACE, earth moving equipment. Superdurable High gloss Albecor min Albecor min at 160 C Designed to give a superior exterior durability and considerably improved mechanical properties along with excellent flow compared to standard superdurable systems in 93:7 ratio. Good storage stability. Suitable for GSB Master and Qualicoat Class 2 approvals. Designed to give a superior exterior durability and considerably improved mechanical properties along with excellent flow compared to standard superdurable systems in 93:7 ratio. Improved flexibility compared to Albecor Suitable for GSB Master and Qualicoat Class 2 approvals. Standard durability Low gloss Albecor min at 160 C Albecor min Albecor min Albecor min Albecor min Designed for applications starting from 160 C, in 97:3 ß-HAA ratio, to achieve mat finishing by dry blending with coatings based on Albecor Improved blooming and storage stability. Designed for applications starting from 160 C, in 97:3 ß-HAA ratio, to achieve mat finishing by dry blending with coatings based on Albecor Designed for applications at 93:7 ratio with ß-HAA. It could be used in dry-blend with Albecor 1420 to produce low gloss finishing. Improved blooming and storage stability. Designed for applications at 93:7 ratio with ß-HAA. It could be used in dry-blend with Albecor 1550 to produce low gloss finishing. Designed for very low gloss in dry-blend with Albecor 1550 and Albecor Typically cured with polyglycidyl esters Albecor min at 160 C For applications in combination with Araldite PT 910 (*) or PT 912 (*) in 92:8 ratio. Resulting coatings show full mechanical properties, good flow, no blooming and good outdoor resistance. * Huntsman 4

4 Polyester Resins for Low Temperature Cure for Interior Use Typically cured with epoxy resins 60/40 Hybrids Cone & Plate Albecor min Albecor min High reactivity resin for hybrid coatings. In combination with suitable epoxy resin in 60/40 ratio, it offers good mechanical properties, corrosion resistance and overall chemical resistance. Also with curing cycles from 140 C. Suitable for thin film applications and primers. High reactivity resin for hybrid coatings.in combination with suitable epoxy resins in 60/40 ratio, it offers the best balance between reactivity and flow. It is TMA free. Excellent overall performances also with curing cycles from 140 C. 70/30 Hybrids Albecor min High reactivity polyester resin for hybrid coatings.in combination with suitable epoxy resins in 70/30 ratio, Albecor 4701 offers very good mechanical properties, corrosion resistance and overall chemical resistance also with curing cycles from 140 C. Carboxyl-Terminated Polyester Resins for Exterior Use Typically cured with ß-hydroxy alkyl amide Cone & Plate min 15 min at 160 C min min min min 15 min at 170 C min min at 170 C Designed for combination with ß-HAA in 96,5:3,5 ratio. The resulting coatings exhibit good flow, exterior durability and mechanical properties along with increased reactivity. Cures at 96.5/3.5. The final coating shows very good balance between flow and flexibility, good exterior durability and excellent yellowing resistance. Cures at 96.5/3,5 ratio. Specifically designed for Dye-sublimation technology on textured powder coatings. Excellent sag resistance when high film thickness is requested. Cures at 95/5. The resulting coatings exhibit an excellent flow and appearance. Suitable for curing with proper Acrylic curative to achieve full matt. Designed for combination with ß-HAA in 95:5 ratio.the resulting coatings exhibit good flow, compatibility and yellowing resistance along with excellent flexibility and improved outdoor resistance. Suitable for GSB and Qualicoat approvals. Cures at 95/5. Good yellowing resistance, excellent flexibility and ageing. Designed for combination with ß-HAA in 95:5 ratio. It has specifically developed to provide good yellowing resistance, excellent flexibility and ageing in applications like PCM and coil coatings. Suitable for GSB and Qualicoat approvals. 5

5 Insid Carboxyl-Terminated Polyester Resins for Exterior Use Typically cured with ß-hydroxy alkyl amide Superdurable High gloss Cone & Plate min min Cures at 95/5. Designed to give a superior exterior durability and considerably improved mechanical properties compared to standard superdurable systems. Suitable for GSB Master and Qualicoat Class 2 approvals. Cures at 95/5. Designed to give a superior exterior durability and improved mechanical properties compared to standard superdurable systems. Suitable for GSB Master and Qualicoat Class 2 approvals Standard durability Low gloss SilkyMatt 5600 SilkyMatt 5540 SilkyMatt 5510 SilkyMatt 5641 SilkyMatt 5730 SilkyMatt 5631 SilkyMatt 5590 SilkyMatt 5520 SilkyMatt 5770 SilkyMatt 5680 SilkyMatt min min min min min min min min min min min Cures at 97.5/2.5. Designed for achieving very low gloss finishing by dry blending with coatings based on SilkyMatt Cures at 97/3. Designed for low gloss by dry blending with coatings based on SilkyMatt Excellent quality performances and consistency. Cures at 97/3. Designed for low gloss by dry blending with coatings based on SilkyMatt Excellent flexibility. Cures at 97/3. Designed for low gloss by dry blending with coatings based on SilkyMatt Cures at 97/3. Specially designed for low gloss in dry blend with SilkyMatt It gives excellent balance of flexibility and durability. Cures at 95/5. The resulting coatings, in dry-blend with SilkyMatt 5691 allow very low gloss finishing and are optimized for the Dye-sublimation. Cures at 93/7. Designed for low gloss by dry blending with coatings based on SilkyMatt Excellent quality performances and consistency. Cures at 93/7. Designed for low gloss by dry blending with coatings based on SilkyMatt Excellent flexibility. Cures at 93/7. Specially designed for low gloss in dry blend with SilkyMatt It gives excellent balance of flexibility and durability. Cures at 90/10, designed for very low gloss in dry-blend with low reactivity resins, especially SilkyMatt Cures at 87/13. The resulting coatings, in dry-blend with SilkyMatt 5631 allow very low gloss finishing and are optimized for the Dyesublimation. 6

6 nside Superdurable Low gloss Cone & Plate SilkyMatt 6520 SilkyMatt 6530 SilkyMatt 6540 SilkyMatt 6550 SilkyMatt 6570 SilkyMatt 6580 SilkyMatt min min min min min min min Cures at 97.5/2.5. Provides very low gloss when dry-blended with SilkyMatt GSB Master and Qualicoat Class 2 approvals. Cures at 97/3. Good flow, high exterior durability. Provides low gloss when dry-blended with SilkyMatt GSB Master and Qualicoat Class 2 approvals. Cures at 96.5/3.5. Provides low gloss when dry-blended with Silky- Matt 6580, improved water resistance in comparison with SilkyMatt Superdurable, suitable for GSB Master and Qualicoat Class 2 approvals. Cures at 96/4. Specifically designed for low gloss in dry blend with SilkyMatt The system provides improved humidity resistances versus standard versions. Superdurable, suitable for GSB Master and Qualicoat Class 2 approvals. Cures at 93/7. Provides low gloss when dry blended with SilkyMatt 6520 or Superdurable, suitable for GSB Master and Qualicoat Class 2 approvals. Cures at 92/8. Provides low gloss when dry blended with SilkyMatt 6520 or Superdurable, suitable for GSB Master and Qualicoat Class 2 approvals. Cures at 90/10. Specifically designed for low gloss in dry blend with SilkyMatt The system provides improved humidity resistances versus standard versions. Superdurable, suitable for GSB Master and Qualicoat Class 2 approvals. Typically cured with polyglycidyl esters Cone & Plate min Designed for combination with Araldite PT 910 (*) in 93:7 ratio. The resulting coatings are designed for industrial exterior coatings exhibiting good weathering durability and flow along with excellent flexibility Low reactivity carboxyl polyester resin used in 93:7 ratio with Araldite PT910 or Araldite PT912 (*). It is used in combination with other similar resins to adjust reactivity. The resulting coatings exhibit excellent flow and storage stability min min Designed for combination with Araldite PT910 or Araldite PT912 (*) in 93:7 ratio. The resulting coatings exhibit very good mechanical properties, storage stability and flow along with good color retention in direct gas-ovens. Designed for combination with Araldite PT910 or Araldite PT912 (*) in 92:8 ratio. The resulting coatings exhibit very good mechanical properties, storage stability and reactivity along with good colour retention in direct gas-ovens. Superdurable High gloss min Superior exterior durability in 95:5 ratio with Araldite PT 912 (*). Coatings based on 6800 are suitable for GSB Master and Qualicoat Class 2 approvals. 7

7 Carboxyl-Terminated Polyester Resins for Exterior Use Typically cured with TGIC (Triglycidyl Isocyanurates) Cone & Plate min min min at 200 C min at 150 C min min min at 200 C Designed for combination with TGIC in 95:5 ratio. The resulting coatings are designed for industrial exterior finishing. Low reactivity resin showing excellent storage stability together with an excellent flow. Exterior durable for architectural applications, Qualicoat and GSB approvable, suitable for TGIC at 93/7 ratio. Low reactivity resin designed for combination with TGIC in 93:7 ratio. The resulting coatings exhibit excellent flexibility, storage stability and outstanding flow. It is suitable for GSB, Qualicoat and AAMA approvals. Designed for curing with TGIC in 93:7 ratio for high speed lines. The resulting coatings exhibit, excellent flexibility and exterior durability. Designed to be used with texturing agent for wrinkle effect. It starts curing from 130 C Designed for combination with TGIC in 93:7 ratio. The resulting coatings exhibit excellent flow, good flexibility and exterior durability. Designed for combination with TGIC in 93:7 ratio or with ß-HAA in 95:5 ratio. The resulting coatings exhibit excellent reactivity. Suitable for curing with proper Acrylic curative to achieve full matt. Medium-high reactivity resin, designed for combination with TGIC in 93:7 ratio. The resulting coatings exhibit excellent flexibility, storage stability and outstanding flow along with excellent boiling water resistance. Superdurable High gloss min Designed to give a superior exterior durability in 93:7 ratio with TGIC.Suitable for GSB and Qualicoat Class 2 approvals. Standard durability Low gloss SilkyMatt min Cures at 96/4 with TGIC, excellent for matt coatings when dry-blended with SilkyMatt Suitable for GSB and Qualicoat approvals min Suitable for combination with TGIC in 94:6 or 95:5 ratios for industrial coatings. Specifically designed for one shot matt finishing with proper matting agent and curing cycle at 200 C for 10 min. Excellent storage stability. SilkyMatt min Cures at 90:10 ratio with TGIC. Designed for low gloss dry-blend in combination with SilkyMatt Suitable for GSB and Qualicoat approvals. Suitable for dye-sublimation with excellent film and paper detachment. 8

8 Hydroxyl-Terminated Polyester Resins for Exterior Use Typically cured with isocyanates OH Value Cone & Plate * min min max min max min max min max min max min Resin designed to be cured with low ratios of Uretdione curing agents. Formulation cost reduction still keeping excellent flexibility along with good gloss and weathering resistance. Designed to be cured with low ratios of uretdione curing agents. It is characterized by high Tg and superior viscosity during the extrusion process. It allows to formulate powder coatings with special surface effects. Designed primarily to be cured with aliphatic isocyanates but also with Uretdione technology. Superior flow, excellent exterior durability, flexibility, gloss and pigment wetting. Also suitable for clear coating. Cured in combination with non-emitting isocyanates, offers excellent solvent, detergent and stain resistance with good mechanical properties. It has been specifically developed for Antigraffiti coatings cured with non-emitting Isocyanates.The resin, having a high cross-link density, gives a very hard film with superior solvent and stain resistance. Specifically developed for antigraffiti coatings cured with non-emitting isocyanate. With high cross-linking density, it gives very hard film with superior solvent and stain resistance. Enhanced outdoor durability in comparison with It has been specifically developed for antigraffiti paint cured with non-emitting isocyanate. Having a high cross-link density, gives a very hard film with superior solvent and stain resistance. Superdurable High gloss max min Used in combination with non-emitting isocyanate curatives, offers excellent stain, detergent/chemical resistance. The resin has been specifically designed to give a superior exterior durability in the range of superdurable resins. Suitable for GSB Master and Qualicoat Class 2 approvals. Standard durability Low gloss SilkyMatt 3225 SilkyMatt 3600 SilkyMatt max min max min min Low gloss in one shot with SilkyMatt 3115 and non-emitting isocyanate curative. The resulting coating system offers good flexibility, impact resistance and exterior durability. Specifically designed for Dye Sublimation effect. Low gloss in one shot with SilkyMatt 3115 and non-emitting isocyanate curative. The resulting coating system offers good flexibility, impact resistance and exterior durability. Specifically designed for Dye Sublimation effect with high storage stability. Hydroxyl functional, highly branched resin. Combines in one shot with SilkyMatt 3225 or SilkyMatt 3600 for low gloss finishes. These systems are recommended in dye-sublimation and automotive applications. When used by itself, the resin provides an excellent antigrafitti and solvent resistance. * schedule of hydroxyl-terminated polyesters is related to Uretdione technology. 9

9 Hydroxyl-Terminated Polyester Resins for Exterior Use Typically cured with isocyanates Superdurable Low gloss app. OH Value Cone & Plate * SilkyMatt 6620 SilkyMatt 6320 SilkyMatt max min max min max min Superdurable resin to be blended in one shot with SilkyMatt 6615 to produce low gloss finishing suitable for dye-sublimation, outstanding weathering and Florida resistance compared to SilkyMatt Suitable for GSB Master and Qualicoat Class 2 approvals. Low gloss in one shot with SilkyMatt 3115 and non-emitting isocyanate curative. The resulting coating system offers good flexibility, impact resistance and exterior durability. Specifically designed for Dye Sublimation effect with improved outdoor performances. GSB and Qualicoat approvable. Superdurable resin to be blended in one shot with SilkyMatt 6620 to produce low gloss finishing suitable for dye-sublimation, outstanding weathering and Florida resistance. Suitable for GSB Master and Qualicoat Class 2 approvals. * schedule of hydroxyl-terminated polyesters is related to Uretdione technology. Carboxyl-Terminated Polyester Resins for Interior Use Typically cured with epoxy resins 50/50 Hybrids Cone & Plate min at 160 C min at 160 C min at 160 C High reactivity polyester resin for hybrid coatings. It offers an improved flow, good mechanical properties, corrosion and overall chemical resistance. High reactivity resin for hybrid coatings. In combination with suitable epoxy resin in 50/50 ratio, it is the typical resin for Domestic Appliance when excellent chemical properties are required. High reactivity polyester resin for 50/50 hybrids. It offers good flow, good chemical and mechanical properties. 60/40 Hybrids min at 200 C min at minutes min at minutes Low reactivity resin for 60/40 hybrid coatings. In combination with suitable epoxy resins, it offers outstanding flow and is suitable as Primer on metal substrates. It can be applied in the transportation field. High reactivity resin for hybrid coatings in combination with suitable epoxy resins in 60/40 ratio. It is the perfect resin for thin film applications and high quality for Domestic Appliance coatings. High reactivity polyester resin for hybrid coatings in combination with suitable epoxy resins in 60/40 ratios. High reactivity resin for hybrid coatings. In combination with suitable epoxy resins in 60/40 ratio, it offers good flow along with excellent flexibility, corrosion resistance and overall chemical resistance. TMA free resin. High reactivity polyester resin for hybrid coatings in 60/40 ratio. It combines all the advantages given by a high Tg along with an excellent flow. 10

10 Carboxyl-Terminated Polyester Resins for Interior Use Typically cured with epoxy resins 70/30 Hybrids Cone & Plate min at min at min at min at min at 200 C High reactivity resin. In combination with suitable epoxy resins in 70/30 ratio, it provides hybrid decorative coatings with good mechanical and flow properties, along with improved storage stability. High reactivity resin. In combination with suitable epoxy resins in 70/30 ratio, it provides hybrid decorative coatings with good mechanical and flow properties. Medium reactivity resin. In combination with suitable epoxy resins in 70/30 ratio, it provides hybrid decorative coatings with good mechanical and enhanced flow properties. High reactivity resin. In combination with suitable epoxy resins in 70/30 ratio, 2681 provides hybrid decorative coatings with good mechanical and flow properties along with good color retention in gas oven. Low reactivity resin. In combination with suitable epoxy resins in 70/30 ratio, 2600 provides hybrid decorative coatings with good mechanical properties along with excellent flow. Additives Additives Additives app. OH Value (mg KOH/g) Cone & Plate Albemast max Tribo additive masterbatch suitable to adjust the tribo chargeability of all standard polyester resins. Albemast 9100 is a hydroxyl terminated polyester containing 5% of active matter. Albemast Tribo additive masterbatch 5% content based on carboxyl terminated resins, suitable to adjust the tribo chargeability of any type of carboxyl powder coating. Albemast Flow promoter 15% additive masterbatch on Hydroxyl terminated resins, suitable to adjust the flow of any powder coating formulation. Albemast Designed for gloss control in low gloss poly-urethane one shot powder coatings formulations based on SilkyMatt resins. Small additions on binder raise the gloss of coated film to the desired level. Dye sublimation proved. 11

11 Leading in emulsions and speciality polymers Synthomer is one of the world s leading suppliers of emulsion and speciality polymers supporting leadership positions in many market segments including coatings, construction, technical textiles, adhesives, paper and synthetic latex gloves. The company has its Head Office in London (UK) and provides customer focused services from operational centres in Harlow (UK), Marl (Germany), Kuala Lumpur (Malaysia), Shanghai (China) and Dubai (UAE). In June 2016 we have acquired the Monomers, Dispersions and Powders business (MDP) from Hexion with dedicated production, sales and customer service facilities in North America, Europe and South East Asia. The newly acquired business significantly improves our footprint to a number of speciality markets which we will continue to serve through a strong network of local technical service and sales branches, supported by regional application development and production in our key markets. We deliver the right formula, globally, individually. Disclaimer: This information and any other advice or recommendations given or made by us (collectively Information ), are provided in good faith and are not intended to, nor do they, constitute professional advice or services. Information is provided AS IS and on an AS AVAILABLE basis and without warranty. We do not warrant or accept responsibility for the accuracy, timeliness or completeness of the Information, or for the suitability of the Information for a particular purpose. We do not accept responsibility, and exclude all liability (including under any implied warranties), for any matters arising out of or in connection with your reliance on the Information (including as to infringement of third party intellectual property rights) to the fullest extent permitted by law. Any Information concerning any possible use or application of Synthomer products is given by us in good faith; we do not warrant the fitness of any Synthomer products for any particular purpose and it is entirely for you to satisfy yourself fully as to the suitability of Synthomer products for any particular purpose. Synthomer products are sold in accordance with Synthomer s standard terms and conditions of sale which are available from Group Head Office Synthomer plc 45 Pall Mall London SW1Y 5JG United Kingdom info@synthomer.com Business Unit Powder Coatings Synthomer Specialty Resins S.r.l. Via Morozzo Sant Albano Stura Italy Phone infopowder@synthomer.com