KÖMMERLING CHEMISCHE FABRIK GMBH

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1 KÖMMERLING CHEMISCHE FABRIK GMBH Adhesives for the photovoltaic industry European Coatings CONFERENCE 22. & 23. November 2011, Berlin

2 PRODUCTS Adhesives and sealants for Insulating glass Structural Glazing Direct Glazing PV / Solar thermal Transportation Marine Industrial applications

3 Global Structure Germany Pirmasens Headquarter, Production site Langelsheim Production site Global, Integrated Platform France Strasbourg Sales office Great Britain Uxbridge Sales office Russia Moscow Sales office ADCO Koemmerling China Beijing Sales office Nanjing Production site ADCO USA Michigan Center Production site Chagrin Falls Production site Mundelein Production site

4 ADHESIVES FOR PHOTOVOLTAICS Bonding and sealing of the J-box Potting of the J-box Edge sealing Edge bonding / laminate free Back rail bonding

5 ADHESIVES FOR PHOTOVOLTAICS Attachment solution for flexible thin film modules

6 BONDING AND SEALING OF THE J-BOX Current solutions in the market Bonding and sealing: Acrylic tapes / pads Silicones 1 and 2 part

7 BONDING AND SEALING OF THE J-BOX Requirements Bonding / Sealing Easy processing Fast curing high level of green strength (handling stability) Compensation of tolerances Good adhesion on plastics and glass Compensation of differences in thermal expansion UV stability Temperature stability High bonding strength and good adhesion > 25 years Water and moisture vapour tightness Must pass damp heat -, thermal cycling- and humidity freeze test Compatibility

8 BONDING AND SEALING OF THE J-BOX Properties of Silicones 1-part 2-part Easy processing ++ o Fast curing high level of green strength (handling stability) o + Compensation of tolerances Compensation of differences in thermal expansion UV stability Temperature stability High bonding strength and good adhesion > 25 years Water tightness Moisture vapour tightness -- --

9 BONDING AND SEALING OF THE J-BOX Properties of Acrylic Tapes Easy processing peel and stick + Fast curing high level of green strength (handling stability) ++ Compensation of tolerances o Compensation of differences of thermal expansion + UV stability ++ Temperature stability + High bonding strength and good adhesion > 25 years o Water tightness + Moisture vapour tightness --

10 BONDING AND SEALING OF THE J-BOX 2 part silicones Standard and Fast curing Shore A Time in [h] Standard Fast

11 BONDING AND SEALING OF THE J-BOX 50 2 part silicones Curing development = f (Temperature) 40 Shore A Time [h] 30 C 23 C 15 C

12 BONDING AND SEALING OF THE J-BOX 50 2-part silicones Curing development = f (mixing ratio) 40 Shore A Time [h] + 10% 0 % - 10 %

13 BONDING AND SEALING OF THE J-BOX Peel test

14 BONDING AND SEALING OF THE J-BOX UV stability of silicones Peel strength glass to aluminium after UV/H 2 O-Storage 9 8 peel strength [N/mm] Storage time [h] 2 part silicone

15 MOISTURE VAPOUR TIGHTNESS MVTR (MOISTURE VAPOUR TRANSMISSION RATE ) of different materials at 38 C and 85 C 200,00 193,00 MVTR [g/m²d] 150,00 100,00 50,00 0,00 88,00 82,00 26,00 16,00 7,00 0,29 4,00 PIB Epoxy Silicone Acrylic tape % RH % RH

16 POTTING OF THE J-BOX Moisture vapour barrier with PIB based hotmelt High first position tack No need for an additional acrylic tape

17 Compatibility Compatibility None of the components involved should be affected by any of the other components in a way that detracts from its function in the system and the system should not be affected by interactions of any of its components Interactions Chemical or physical processes during contact of two or more materials => often migration Harmful Interactions Performance and function are compromised by Change of mechanical and optical properties Loss of efficiency rate

18 Migration Process

19 AIR SPACE TECHNOLOGY Laminate free crystalline PV module Modified PIB Structural Silicone

20 AIR SPACE TECHNOLOGY MULTI CRYSTALLINE SILICON MODULE Source: Apollon Solar

21 BACK RAIL BONDING Structural bonding with 2-part silicones Frameless Modules Edge Sealing necessary?

22 BACK RAIL BONDING Requirements Easy processing Fast curing high level of green strength (handling stability) Compensation of tolerances Compensation of differences in thermal expansion UV stability Temperature stability High bonding strength and good adhesion > 25 years No creep Must pass damp heat -, thermal cycling- and humidity freeze test Structural Glazing Guideline ETAG 002

23 BACK RAIL BONDING Structural bonding with 2-part silicones Double sided tape Structural silicone

24 ROOF INSTALLATION FLEXIBLE THIN FILM MODULES PV attachment solution High Strength Thermoset Butyl

25 ROOF INSTALLATION FLEXIBLE THIN FILM MODULES Requirements Ease of installation Peel and stick speed Release liner with superior release properties even under rooftop conditions High bond strength Resists high wind loading Resists upcurl and lifting Good adhesion to: TPO, EPDM, Mod-Bit, Coated steel No creep Long term durability under rooftop conditions > 20 years Compatibility

26 ROOF INSTALLATION FLEXIBLE THIN FILM MODULES PV attachment solution

27 Product Range Bonding and sealing of the J-box with HelioBond PVA 200 or 205 Potting of the J-box with HelioSeal PVS 800 Edge Sealing / Bonding with HelioSeal PVS 101 HelioBond PVA 200 Back rail bonding with HelioBond PVA 200 or 500

28 THANK YOU Questions Are Appreciated

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