1. Substance/preparation and manufacturer/supplier identification

Transcription

1 Safety data sheet Page: 1/8 1. Substance/preparation and manufacturer/supplier identification Orasol Orange 245 Use: Colorants for the Paints, lacquers and varnishes industry, Colorants for industrial use Manufacturer/supplier: BASF Vietnam Co. Ltd. 12 Tu do Boulevard, Vietnam-Singapore IP Thuan An, Binh Duong, VIETNAM Telephone: Telefax number: address: Emergency information: International emergency number: Telephone: Hazard identification Classification of the substance and mixture: Hazardous to the aquatic environment - acute: Cat. 3 Hazardous to the aquatic environment - chronic: Cat. 3 Label elements and precautionary statement: Hazard Statement: Harmful to aquatic life. Harmful to aquatic life with long lasting effects. Precautionary Statements (Prevention): Avoid release to the environment. Precautionary Statements (Disposal):

2 Page: 2/8 Dispose of contents/container to hazardous or special waste collection point. Other hazards which do not result in classification: The product is under certain conditions capable of dust explosion. 3. Composition/information on ingredients Chemical nature metal complex dye C.I. Solvent Orange 56 Hazardous ingredients Hydrogen [3-[(4,5-dihydro-3-methyl-5-oxo-1-phenyl-1H-pyrazol-4-yl)azo]-2-hydroxy-5- nitrobenzenesulphonato(3-)]hydroxychromate(1-), c ompound with 3-[(2-ethylhexyl)oxy]propylamine (1:1) Content (W/W): >= 75 % - <= 100 % CAS Number: Aquatic Acute: Cat. 3 Aquatic Chronic: Cat First-Aid Measures General advice: Remove contaminated clothing. If inhaled: If difficulties occur after dust has been inhaled, remove to fresh air and seek medical attention. On skin contact: Wash thoroughly with soap and water. On contact with eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open. On ingestion: Rinse mouth and then drink plenty of water. Note to physician: Symptoms: No significant reaction of the human body to the product known. Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. 5. Fire-Fighting Measures Suitable extinguishing media: dry powder, foam Unsuitable extinguishing media for safety reasons: carbon dioxide

3 Page: 3/8 Additional information: Avoid whirling up the material/product because of the danger of dust explosion. Specific hazards: harmful vapours Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire. Special protective equipment: Wear a self-contained breathing apparatus. Further information: The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing water must be disposed of in accordance with official regulations. 6. Accidental Release Measures Personal precautions: Avoid dust formation. Use personal protective clothing. Environmental precautions: Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater. Methods for cleaning up or taking up: For small amounts: Pick up with suitable appliance and dispose of. For large amounts: Contain with dust binding material and dispose of. Avoid raising dust. 7. Handling and Storage Handling Breathing must be protected when large quantities are decanted without local exhaust ventilation. Protection against fire and explosion: Avoid dust formation. Take precautionary measures against static discharges. Storage Further information on storage conditions: Keep container tightly closed and dry; store in a cool place. 8. Exposure controls and personal protection Components with occupational exposure limits No occupational exposure limits known.

4 Page: 4/8 Personal protective equipment Respiratory protection: Suitable respiratory protection for lower concentrations or short-term effect: Particle filter with medium efficiency for solid and liquid particles (e.g. EN 143 or 149, Type P2 or FFP2) Hand protection: Hand protection not required. Eye protection: Safety glasses with side-shields. General safety and hygiene measures: Handle in accordance with good industrial hygiene and safety practice. In order to prevent contamination while handling, closed working clothes and working gloves should be used. 9. Physical and Chemical Properties Form: Colour: Odour: Odour threshold: powder orange odourless ph value: approx. 5.3 (10 g/l) Melting point: > 250 C (DIN EN ISO 3146) Boiling point: not applicable Flash point: Evaporation rate: not applicable The product is a non-volatile solid. Flammability (solid/gas): not highly flammable Lower explosion limit: For solids not relevant for classification and labelling. Upper explosion limit: For solids not relevant for classification and labelling. Thermal decomposition: 150 C, 770 kj/kg (DSC (DIN 51007)) Self heating ability: It is not a substance capable of spontaneous heating. (UN Test N.4 (self heating substances)) Minimum ignition energy: > 10 - < 30 mj The product is capable of dust explosion. Explosion hazard: not explosive Fire promoting properties: not fire-propagating

5 Page: 5/8 Vapour pressure: not applicable Density: approx. 1.4 g/cm3 (20 C) Relative density: approx. 1.4 (20 C) Bulk density: kg/m3 Relative vapour density (air): The product is a non-volatile solid. Solubility in water: insoluble Hygroscopy: The product has not been tested. Solubility (quantitative) solvent(s): ethanol approx. 200 g/l (20 C) Partitioning coefficient n-octanol/water (log Pow): 10. Stability and Reactivity Conditions to avoid: Avoid dust formation. Avoid deposition of dust. Avoid sources of ignition. Avoid humidity. Thermal decomposition: 150 C, 770 kj/kg (DSC (DIN 51007)) Substances to avoid: strong acids, strong bases, strong oxidizing agents Hazardous reactions: Dust explosion hazard. Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. 11. Toxicological Information Acute toxicity Assessment of acute toxicity: Virtually nontoxic after a single ingestion. Experimental/calculated data: LD50 rat (oral): > 5,000 mg/kg LC50 (by inhalation): LD50 (dermal):

6 Page: 6/8 Irritation Experimental/calculated data: Skin corrosion/irritation rabbit: non-irritant Serious eye damage/irritation rabbit: non-irritant (OECD Guideline 405) Respiratory/Skin sensitization Experimental/calculated data: Germ cell mutagenicity Assessment of mutagenicity: The substance was not mutagenic in bacteria. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Carcinogenicity Assessment of carcinogenicity: No data available concerning carcinogenic effects. Reproductive toxicity Assessment of reproduction toxicity: Developmental toxicity Assessment of teratogenicity: Specific target organ toxicity (single exposure): Remarks: Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity: Aspiration hazard No aspiration hazard expected. 12. Ecological Information Ecotoxicity Assessment of aquatic toxicity:

7 Page: 7/8 Acutely harmful for aquatic organisms. Harmful to aquatic life with long lasting effects. The inhibition of the degradation activity of activated sludge is not anticipated when introduced to biological treatment plants in appropriate low concentrations. Toxicity to fish: LC50 (96 h), Fish Aquatic invertebrates: EC50 (48 h) mg/l, Daphnia magna (OECD Guideline 202, part 1, static) Aquatic plants: EC50 (72 h), algae Chronic toxicity to fish: Chronic toxicity to aquatic invertebrates: Assessment of terrestrial toxicity: No data available concerning terrestrial toxicity. Mobility Assessment transport between environmental compartments: Bioaccumulation potential Assessment bioaccumulation potential: The product has not been tested. Other adverse effects The product contains: Chromium (III) ion The heavy metals mentioned are present in complex bound form as substantial constituent of the colourant. Additional information Add. remarks environm. fate & pathway: Treatment in biological waste water treatment plants has to be performed according to local and administrative regulations. 13. Disposal Considerations Must be disposed of or incinerated in accordance with local regulations. Contaminated packaging: Uncontaminated packaging can be re-used. Packs that cannot be cleaned should be disposed of in the same manner as the contents.

8 Page: 8/8 14. Transport Information Domestic transport: Not classified as a dangerous good under transport regulations Sea transport IMDG Not classified as a dangerous good under transport regulations Air transport IATA/ICAO Not classified as a dangerous good under transport regulations 15. Regulatory Information Other regulations 16. Other Information Vertical lines in the left hand margin indicate an amendment from the previous version. The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. This safety data sheet is neither a Certificate of Analysis (CoA) nor technical data sheet and shall not be mistaken for a specification agreement. Identified uses in this safety data sheet do neither represent an agreement on the corresponding contractual quality of the substance/mixture nor a contractually designated use. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.