For professional use only

Transcription

1 Date of issue 28/02/2011 Revision date 07/04/2015 Supersedes 03/12/2014 Version 1.0 SECTION 1 Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name Mixture Product code FC Type of product Firefighting foam concentrate (High-Ex) 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Industrial/Professional use spec Use of the substance/mixture Uses advised against 1.3. Details of the supplier of the safety data sheet ANGUS FIRE Ltd Station Road Bentham LA2 7NA - United Kingdom T F general.enquiries@angusuk.co.uk - Industrial For professional use only Firefighting foam concentrate 1.4. Emergency telephone number Emergency number T +44(0) (Standard office hours Monday to Friday 830am 430pm GMT) Contact person EH&S Manager SECTION 2 Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Skin Irrit. 2 H315 Eye Irrit. 2 H319 Aquatic Chronic 2 H411 Full text of H-phrases see section 16 Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Xi; R36/38 N; R51/53 Full text of R-phrases see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) Signal word (CLP) Hazard statements (CLP) GHS07 Warning Precautionary statements (CLP) P264 - Wash hands thoroughly after handling P280 - Wear eye protection, protective clothing, protective gloves P302+P352 - IF ON SKIN Wash with plenty of water P305+P351+P338 - IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P332+P313 - If skin irritation occurs Get medical advice/attention 07/04/2015 EN (English) 1/7 GHS09 H315 - Causes skin irritation H319 - Causes serious eye irritation H411 - Toxic to aquatic life with long lasting effects

2 2.3. Other hazards PBT not relevant no registration required vpvb not relevant no registration required SECTION 3 Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture P337+P313 - If eye irritation persists Get medical advice/attention Name Product identifier % Classification according to Directive 67/548/EEC 2-Butoxyethanol (CAS No) (EC no) (EC index no) Xn; R20/21/22 Xi; R36/ Xi; R41 Xi; R38 Disodium lauramido mea-sulfosuccinate (CAS No) (EC no) Alcohols C12-13 (CAS No) (EC no) Xi; R36/ N; R50/53 Xi; R36/38 Name Product identifier Specific concentration limits (5 =< C < 10) Xi;R36 (10 =< C < 100) Xi;R41 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] 2-Butoxyethanol (CAS No) (EC no) (EC index no) Disodium lauramido mea-sulfosuccinate (CAS No) (EC no) Alcohols C12-13 (CAS No) (EC no) Acute Tox. 4 (Inhalation), H332 Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Oral), H302 Eye Irrit. 2, H319 Skin Irrit. 2, H Skin Irrit. 2, H315 Eye Dam. 1, H318 Aquatic Chronic 3, H Skin Irrit. 2, H315 Eye Irrit. 2, H Skin Irrit. 2, H315 Eye Irrit. 2, H319 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Name Product identifier Specific concentration limits Full text of R- and H-phrases see section 16 (5 =< C < 10) Eye Irrit. 2, H319 (10 =< C < 100) Eye Dam. 1, H318 SECTION 4 First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). Allow victim to breathe fresh air. Allow the victim to rest. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs Get medical advice/attention. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists Get medical advice/attention. Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/injuries after skin contact Causes skin irritation. Symptoms/injuries after eye contact Causes serious eye irritation Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5 Firefighting measures 5.1. Extinguishing media Suitable extinguishing media No specific measures are necessary. This product is a fire extinguishing medium. 07/04/2015 EN (English) 2/7

3 Unsuitable extinguishing media Special hazards arising from the substance or mixture Fire hazard No fire hazard Advice for firefighters Firefighting instructions Protection during firefighting.. SECTION 6 Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Evacuate unnecessary personnel. Do not attempt to take action without suitable protective equipment. For further information refer to section 8 "Exposure controls/personal protection" Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections 8. Exposure controls/personal protection. 13. Disposal considerations. SECTION 7 Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. Avoid contact with skin and eyes. Wear recommended personal protective equipment. Read and follow manufacturer's recommendations. Handle in accordance with good industrial hygiene and safety procedures. Wash hands thoroughly after handling Conditions for safe storage, including any incompatibilities Storage conditions 7.3. Specific end use(s) Firefighting foam concentrate. SECTION 8 Exposure controls/personal protection 8.1. Control parameters Store in original container. Keep container tightly closed. Store at temperatures not exceeding 60 C (140 F). Protect from freezing. Keep/Store away from incompatible materials Exposure controls Appropriate engineering controls Personal protective equipment Hand protection Eye protection Skin and body protection Respiratory protection Thermal hazard protection Environmental exposure controls Other information Ensure adequate ventilation. Follow the exposure limits given on this material safety data sheet. Wear recommended personal protective equipment. Wear protective gloves. Chemical goggles or safety glasses. Wear suitable protective clothing. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Wear thermal protective clothing, when necessary. Contain spills. Prevent releases. Observe national regulations on emissions. Ensure all national/local regulations are observed. Do not eat, drink or smoke when using this product. SECTION 9 Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Liquid Colour Amber. Odour Characteristic. Odour threshold ph /04/2015 EN (English) 3/7

4 Relative evaporation rate (butylacetate=1) Melting point Freezing point < -3 C Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Non flammable Density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10 Stability and reactivity Reactivity 7 mm²/s The product is stable and non reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid Incompatible materials. Extremely high or low temperatures Incompatible materials Alkali metals. Oxidizing agent. Water reactive substances Hazardous decomposition products Carbon oxides. Sulphur oxides. Hydrogen fluoride. Nitrogen oxides (NOx). Sodium oxides. SECTION 11 Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Causes skin irritation. ph 6-8 Causes serious eye irritation. ph /04/2015 EN (English) 4/7

5 Aspiration hazard Potential adverse human health effects and symptoms SECTION 12 Ecological information Toxicity Ecology - water LC50 fishes 1 EC50 Daphnia 1 LC50 fish 2 EC50 Daphnia 2. Toxic to aquatic life with long lasting effects. 89 ppm (24h; Oncorhynhus mykiss) 37 ppm (24h; Daphnia magna) 60 ppm (48h; Oncorhynhus mykiss) 10 ppm (48h; Daphnia magna) Persistence and degradability Persistence and degradability Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) May cause long-term adverse effects in the environment g O₂/g substance (5 days) 0.62 g O₂/g substance Bioaccumulative potential Bioaccumulative potential Alcohols C12-13 ( ) Bioaccumulative potential The product is not expected to bioaccumulate. No bioaccumulation data available Mobility in soil Results of PBT and vpvb assessment PBT not relevant no registration required vpvb not relevant no registration required Other adverse effects Other adverse effects An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. SECTION 13 Disposal considerations Waste treatment methods Waste disposal recommendations Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials Avoid release to the environment. European List of Waste (LoW) code * - organic wastes containing dangerous substances SECTION 14 Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number Not regulated for transport UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport hazard class(es) ADR Transport hazard class(es) (ADR) 07/04/2015 EN (English) 5/7

6 IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information Yes Yes No supplementary information available Special precautions for user Overland transport Transport by sea Air transport Inland waterway transport Carriage prohibited (ADN) Not subject to ADN Rail transport Carriage prohibited (RID) No No No Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable 07/04/2015 EN (English) 6/7

7 SECTION 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions Contains no substance on the REACH candidate list National regulations Chemical safety assessment No chemical safety assessment has been carried out SECTION 16 Other information Data sources Other information REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. None. Full text of R-, H- and EUH-phrases Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4 Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Acute 1 Hazardous to the aquatic environment Acute Hazard, Category 1 Aquatic Chronic 1 Hazardous to the aquatic environment Chronic Hazard, Category 1 Aquatic Chronic 2 Hazardous to the aquatic environment Chronic Hazard, Category 2 Aquatic Chronic 3 Hazardous to the aquatic environment Chronic Hazard, Category 3 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 H302 H312 H315 H318 H319 H332 H400 H410 H411 H412 Harmful if swallowed Harmful in contact with skin Causes skin irritation Causes serious eye damage Causes serious eye irritation Harmful if inhaled Very toxic to aquatic life Very toxic to aquatic life with long lasting effects Toxic to aquatic life with long lasting effects Harmful to aquatic life with long lasting effects R20/21/22 Harmful by inhalation, in contact with skin and if swallowed R36/38 Irritating to eyes and skin R38 R41 Irritating to skin Risk of serious damage to eyes R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment N Dangerous for the environment Xi Xn Irritant Harmful SDS EU (REACH Annex II) - Angus Fire This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 07/04/2015 EN (English) 7/7