SAFETY DATA SHEET Revised edition no : 2 SDS/MSDS Date : 7 / 12 / 2012

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1 Page : 1 1. Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name : Product code : Identification of the product : Iodine CAS No : EC No : Annex No : Relevant identified uses of the substance or mixture and uses advised against Use : Industrial. For professional use only Details of the supplier of the safety data sheet Company identification : 107 Wode House Road, Jehangir Villa, Colaba Mumbai INDIA 1.4. Emergency telephone number Phone nr : (9:00am - 6:00 pm) [ Office hours ] 2. Hazards identification -DSD 2.1. Classification of the substance or mixture Classification EC 67/548 or EC 1999/45 Classification : Xn; R20/21 N; R50 Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP) Health hazards Environmental hazards : Acute toxicity, Inhalation - Category 4 - Warning (CLP : Acute Tox. 4) H332 Acute toxicity, dermal - Category 4 - Warning (CLP : Acute Tox. 4) H312 : Hazardous to the aquatic environment - Acute hazard - Category 1 - Warning (CLP : Aquatic Acute 1) H Label elements

2 Page : 2 2. Hazards identification -DSD (continued) Labelling EC 67/548 or EC 1999/45 Symbol(s) Symbol(s) R Phrase(s) S Phrase(s) Contains êx ên : Xn : Harmful N : Dangerous for the environment : R20/21 : Harmful by inhalation and in contact with skin. R50 : Very toxic to aquatic organisms. : S23 : Do not breathe the gas, fumes, vapours, spray. S25 : Avoid contact with eyes. S61 : Avoid release to the environment. Refer to special instructions/safety data sheets. : Iodine Labelling Regulation EC 1272/2008 (CLP) Hazard pictograms Signal words Hazard statements Precautionary statements General Prevention Response Disposal considerations Contains MÄ MÅ : Warning : H312 : Harmful in contact with skin. H332 : Harmful if inhaled. H400 : Very toxic to aquatic life. : P102: Keep out of reach of children. P103: Read label before use. P101: If medical advice is needed, have product container or label at hand. : P280: Wear protective gloves, protective clothing, eye protection, face protection. P271: Use only outdoors or in a well-ventilated area. P261: Avoid breathing dust, fume, gas, mist, vapours, spray. P273: Avoid release to the environment. : P302+P352: IF ON SKIN : Wash with plenty of soap and water. P391: Collect spillage. P304+P340: IF INHALED : Remove to fresh air and keep at rest in a position comfortable for breathing. P363: Wash contaminated clothing before reuse. : P501: Dispose of this material and its container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. : Iodine 2.3. Other hazards

3 Page : 3 2. Hazards identification -DSD (continued) Other hazards : The substance does not fulfil the criteria to be identified as PBT substance or vpvb substance according to Annex XIII of Regulation REACH. 3. Composition/information on ingredients Substance / Preparation Hazardous component(s) : Iodine CAS No : EC No : Annex No : Substance. : This product is hazardous. Substance name Contents CAS No EC No Annex No REACH Ref. Classification Iodine : 100 % Xn; R20/21 N; R Acute Tox. 4 (skin) _ H312 Acute Tox. 4 (inhal) _ H332 Aquatic Acute 1 _ H400 Contains no other components or impurities which will influence the classification of the product. 4. First aid measures 4.1. Description of first aid measures Inhalation Skin contact Eye contact Ingestion : Assure fresh air breathing. Allow the victim to rest. Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. Immediately call a POISON CENTER or doctor. Specific treatment (see on this label). Wash with plenty of soap and water. Wash contaminated clothing before reuse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Obtain emergency medical attention. Rinse mouth. Do NOT induce vomiting Most important symptoms and effects, both acute and delayed Symptoms relating to use : Repeated exposure to this material can result in absorption through skin causing significant health hazard. Danger of serious damage to health by prolonged exposure through inhalation Indication of any immediate medical attention and special treatment needed General information : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).

4 Page : 4 5. Fire-fighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Surrounding fires : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream. : Use water spray or fog for cooling exposed containers Special hazards arising from the substance or mixture Hazardous combustion products : Under fire conditions, hazardous fumes will be present Advice for fire-fighters Protection against fire Special procedures : Do not enter fire area without proper protective equipment, including respiratory protection. : Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For emergency responders For non-emergency personnel : Equip cleanup crew with proper protection. Ventilate area. : Evacuate unnecessary personnel Environmental precautions Environmental precautions : Prevent entry to sewers and public waters. Notify authorities if product enters sewers or public waters. Avoid release to the environment Methods and material for containment and cleaning up Clean up methods : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Store away from other materials. Collect spillage Reference to other sections See section 8. Exposure controls/personal protection 7. Handling and storage 7.1. Precautions for safe handling

5 Page : 5 7. Handling and storage (continued) Handling Technical protective measures : Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and when leaving work. Avoid breathing dust, fume, gas, mist, vapours, spray. Use only outdoors or in a well-ventilated area. : Provide good ventilation in process area to prevent formation of vapour Conditions for safe storage, including any incompatibilities Storage Storage - away from : Keep only in the original container in a cool, well ventilated place. Keep container closed when not in use. : Strong bases. Strong acids. Sources of ignition. Direct sunlight Specific end use(s) Specific end use(s) : None. 8. Exposure controls/personal protection 8.1. Exposure controls Personal protection Respiratory protection Hand protection Eye protection Others : Avoid all unnecessary exposure. : In case of insufficient ventilation, wear suitable respiratory equipment. : Wear protective gloves. : Chemical goggles or safety glasses. : When using, do not eat, drink or smoke Control parameters Occupational Exposure Limits : No data available. 9. Physical and chemical properties 9.1. Information on basic physical and chemical properties Odour threshold : No data available. Melting point [ C] : 113 C Decomposition point [ C] : N/A Flammability (solid, gas) : N/A Boiling point [ C] : 184 C Evaporation rate : N/A Vapour pressure mm/hg : 0.3 mm 200C Vapour density : 8,8

6 Page : 6 9. Physical and chemical properties (continued) Density [g/cm3] : 4,98 Relative density, gas (air=1) : N/A Relative density, liquid (water=1) : N/A Solubility in water [% weight] : 0.03 g/100 g Log Pow octanol / water at 20 C : No data available. Solubility : 5, Other information Explosive properties Oxidising properties : N/A : No data available. 10. Stability and reactivity Reactivity Reactivity : Not established Chemical stability Chemical stability : Stable under recommended storage conditions Possibility of hazardous reactions Hazardous reactions : Not established Conditions to avoid Conditions to avoid : Direct sunlight. Extremely high or low temperatures Incompatible materials Materials to avoid : Strong acids. Strong bases Hazardous decomposition products Hazardous decomposition products : Fumes. Carbon monoxide. Carbon dioxide. 11. Toxicological information Information on toxicological effects Acute toxicity

7 Page : Toxicological information (continued) Inhalation Dermal Ingestion Corrosion Irritation Sensitization Carcinogenicity Toxic for reproduction STOT-single exposure STOT-repeated exposure Aspiration hazard : Harmful if inhaled. : Harmful in contact with skin. 12. Ecological information Toxicity Toxicity information : Very toxic to aquatic life Persistence - degradability Persistence - degradability : Biodegradable Bioaccumulative potential Bioaccumulative potential : Not established Mobility in soil Mobility in soil : Not established Results of PBT and vpvb assessment Results of PBT and vpvb assessment : The substance does not fulfil the criteria to be identified as PBT substance or vpvb substance according to Annex XIII of Regulation REACH Other adverse effects Environmental precautions : Avoid release to the environment. 13. Disposal considerations Waste treatment methods

8 Page : Disposal considerations (continued) General : Avoid release to the environment. Dispose in a safe manner in accordance with local/national regulations. Dispose of this material and its container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. 14. Transport information Land transport (ADR-RID) Proper shipping name : IODINE UN N : 3495 H.I. nr :86 ADR - Class :8 Labelling - Transport : 8 : Corrosive substance. 6.1 : Toxic substances. ADR - Classification code { LÉ : CT2 CT2 CT2 ADR - Group : III ADR - Packing instructions : P002 R001 ADR - Limited Quantity : 5 KG ADR - Tunnel code : E : Passage forbidden through tunnels of category E Sea transport (IMDG) [English only]» Proper shipping name : IODINE UN N : 3495 IMO-IMDG - Class or division : 8 : Corrosive substance. ( 6.1 : Toxic substances. ) IMO-IMDG - Packing group : III IMO- IMDG - Packing instructions : P002 LP02 IMO-IMDG - Limited quantities : 5 kg IMO-IMDG - Marine pollution : Yes EMS-Nr : F-A S-F

9 Page : Transport information (continued) Air transport (ICAO-IATA) [English only] Proper shipping name : IODINE UN N : 3495 IATA - Class or division : 8 : Corrosive substance. ( 6.1 : Toxic substances. ) IATA - Packing group : III IATA - Passenger and Cargo Aircraft : ALLOWED - Passenger and Cargo - Packing : 860 instruction - Passenger and Cargo - Maximum : 25 kg Quantity/Packing IATA - Cargo only : ALLOWED - Cargo only - Packing instruction : Cargo only - Maximum Quantity/ : 100 kg Packing IATA - Limited Quantites : 5 kg ERG-Nr :8P 15. Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Safety, health and environmental : Ensure all national/local regulations are observed. regulations/legislation specific for the substance or mixture REACH Restrictions - Annex XVII : The components of this product are not subject to restrictions. REACH Authorisation - Annex XIV : The components of this product are not subject to authorization Chemical Safety Assessment Chemical Safety Assessment : It has not been carried out. 16. Other information Revision : Revision - See : * Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic. vpvb: very persistent and very bioaccumulative Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006

10 Page : Other information (continued) List of relevant R phrases (heading 3) : R20/21 : Harmful by inhalation and in contact with skin. R50 : Very toxic to aquatic organisms. List of full text of H-statements in section 3 Further information : H312 : Harmful in contact with skin. H332 : Harmful if inhaled. H400 : Very toxic to aquatic life. : None. In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation (CE) Nº 1272/2008 DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. End of document