SAFETY DATA SHEET Molly Maid Fresh

Transcription

1 SAFETY DATA SHEET 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING PRODUCT NAME PRODUCT NO. APPLICATION SUPPLIER M0231MOL Fragrance/Odour Control Agent Molly Maid UK Limited Molly Maid House 0 Moorbridge Road Maidenhead Berkshire SL6 8BW Freephone: ukso@mollymaid.co.uk EMERGENCY TELEPHONE Molly Maid UK, Tel: (Mon - Fri, ) 2 HAZARDS IDENTIFICATION Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. CLASSIFICATION (1/45) N;R50/53. ENVIRONMENT Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. PHYSICAL AND CHEMICAL HAZARDS The product is flammable, and heating may generate vapours which may form explosive vapour/air mixtures. HUMAN HEALTH Irritating to eyes. See section 11 for additional information on health hazards. 3 COMPOSITION/INFORMATION ON INGREDIENTS Name EC No. CAS-No. Content % Classification (67/548/EEC) COCO AMINE OXIDE % Xi;R38,R41. Limonene < 1% Xi;R38. N;R50/53. R43,R10. CITRAL < 1% R43 Xi;R38 BETA PINENE < 1% Xn;R65. N;R50/53. R10,R43. MONOPROPYLENE GLYCOL < 1% - The Full Text for all R-Phrases is Displayed in Section 16 COMPOSITION COMMENTS The data shown are in accordance with the latest EC Directives. 4 FIRST-AID MEASURES Remove affected person from source of contamination. Get medical attention if any discomfort continues. INHALATION In case of inhalation of spray mist: Move person into fresh air and keep at rest. Get medical attention if any discomfort continues. INGESTION Immediately rinse mouth and drink plenty of water. Keep person under observation. If person becomes uncomfortable seek hospital and bring these instructions. SKIN CONTACT Immediately remove contaminated clothing. Wash off promptly and flush contaminated skin with water. Promptly remove clothing if soaked through and flush skin with water. 1 / 5

2 EYE CONTACT Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Get medical attention promptly if symptoms occur after washing. 5 FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA Fire can be extinguished using: Water spray, fog or mist. Foam, carbon dioxide or dry powder. Dry chemicals, sand, dolomite etc. SPECIAL FIRE FIGHTING PROCEDURES Cool containers exposed to flames with water until well after the fire is out. Keep run-off water out of sewers and water sources. Dike for water control. Avoid breathing fire vapours. UNUSUAL FIRE & EXPLOSION HAZARDS No unusual fire or explosion hazards noted. SPECIFIC HAZARDS The product is non-combustible. If heated, irritating vapours may be formed. PROTECTIVE MEASURES IN FIRE Self contained breathing apparatus and full protective clothing must be worn in case of fire. 6 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS Wear protective clothing as described in Section 8 of this safety data sheet. ENVIRONMENTAL PRECAUTIONS Do not allow ANY environmental contamination. The product should not be dumped in nature but collected and delivered according to agreement with the local authorities. To prevent release, place container with damaged side up. Contain spillages with sand, earth or any suitable adsorbent material. SPILL CLEAN UP METHODS Keep combustibles away from spilled material. Absorb in vermiculite, dry sand or earth and place into containers. Wash thoroughly after dealing with a spillage. Ventilate well. Collect spillage in containers, seal securely and deliver for disposal according to local regulations. Prevent discharge of larger quantity to drain. 7 HANDLING AND STORAGE USAGE PRECAUTIONS Avoid spilling, skin and eye contact. Observe good chemical hygiene practices. STORAGE PRECAUTIONS Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container. STORAGE CLASS Miscellaneous hazardous material storage. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Name STD TWA - 8 Hrs STEL - 15 Min Notes MONOPROPYLENE GLYCOL 25 ppm 7 mg/m3 INGREDIENT COMMENTS WEL = Workplace Exposure Limits PROTECTIVE EQUIPMENT PROCESS CONDITIONS Provide eyewash station. ENGINEERING MEASURES Provide adequate ventilation, including appropriate local extraction, to ensure that the defined occupational exposure limit is not exceeded. All handling to take place in well-ventilated area. HAND PROTECTION Use protective gloves made of: Neoprene. Nitrile. Rubber (natural, latex). 2 / 5

3 EYE PROTECTION Wear splash-proof eye goggles to prevent any possibility of eye contact. OTHER PROTECTION Wear appropriate clothing to prevent any possibility of skin contact. HYGIENE MEASURES DO NOT SMOKE IN WORK AREA! Wash hands at the end of each work shift and before eating, smoking and using the toilet. Promptly remove any clothing that becomes contaminated. Use appropriate skin cream to prevent drying of skin. When using do not eat, drink or smoke. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE ODOUR Colourless-pale yellow liquid. Fruity. Lemon. RELATIVE DENSITY ~ ph-value, CONC. SOLUTION ~ STABILITY AND REACTIVITY STABILITY No particular stability concerns. CONDITIONS TO AVOID HAZARDOUS POLYMERISATION POLYMERISATION DESCRIPTION MATERIALS TO AVOID No specific, or groups of materials are likely to react to produce a hazardous situation. HAZARDOUS DECOMPOSITION PRODUCTS Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours. 11 TOXICOLOGICAL INFORMATION TOXICOLOGICAL INFORMATION No information available. Prolonged and repeated contact with solvents over a long period may lead to permanent health problems. INHALATION In high concentrations, vapours may irritate throat and respiratory system and cause coughing. INGESTION Gastrointestinal symptoms, including upset stomach. SKIN CONTACT Acts as a defatting agent on skin. May cause cracking of skin, and eczema. EYE CONTACT Irritating and may cause redness and pain. 12 ECOLOGICAL INFORMATION ECOTOXICITY Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. MOBILITY The product contains substances, which are water soluble and may spread in water systems. BIOACCUMULATION No data available on bioaccumulation. DEGRADABILITY There are no data on the degradability of this product. ACUTE FISH TOXICITY Harmful to aquatic organisms 13 DISPOSAL CONSIDERATIONS 3 / 5

4 Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste Disposal Authority. DISPOSAL METHODS Dispose of waste and residues in accordance with local authority requirements. Contact specialist disposal companies. 14 TRANSPORT INFORMATION PROPER SHIPPING NAME UN NO. ROAD ADR CLASS ADR PACK GROUP ADR LABEL NO. UN NO. SEA IMDG CLASS IMDG PACK GR. UN NO. AIR AIR CLASS AIR PACK GR. ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Contains Limonene) Class : Miscellaneous dangerous substances and articles. 15 REGULATORY INFORMATION LABELLING RISK PHRASES SAFETY PHRASES Detergent Labelling EU DIRECTIVES Dangerous for the environment R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S2 S61 P14 < 5% non-ionic surfactants Contains perfumes Do not empty into drains. Avoid release to the environment. Refer to special instructions/safety data sheets. Contains CITRAL,Limonene. May produce an allergic reaction. 1,2-BENZISOTHIAZOL-3(2H)-ONE,CITRAL,Linalool,Limonene Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1/45/EC, and amending Regulation (EC) No 107/2006 with amendments. NATIONAL REGULATIONS Workplace Exposure Limits 2005 (EH40) Regulation (EC) No 107/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1/45/EC and repealing Council Regulation (EEC) No 73/3 and Commission Regulation (EC) No 1488/4 as well as Council Directive 76/76/EEC and Commission Directives 1/155/EEC, 3/67/EEC, 3/105/EC and 2000/21/EC, including amendments. 16 OTHER INFORMATION REVISION DATE 25/04/2013 REV. NO./REPL. SDS GENERATED 1 4 / 5

5 RISK PHRASES IN FULL R10 Flammable. R65 Harmful: may cause lung damage if swallowed. R38 Irritating to skin. R43 May cause sensitisation by skin contact. R41 Risk of serious damage to eyes. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 5 / 5