Version: 4.0. Hauptstr , Aichstetten, Germany. Tel./Fax.: Tel , Fax

Transcription

1 Revised edition: Version: 4.0 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Product Name: Dispersion K 9 Page Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Binding agent for outside paints Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: info@kremer-pigmente.de Importer: -- Emergency No. Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Classification according to Directive No. 67/548/EC or No. 1999/45/EC This product does not require classification and labelling as hazardous according to CLP/GHS. The material is not subject to classification according to EC lists. Safety Phrases: Possible Environmental Effects: Label Elements Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Hazard designation: Not applicable. Signal word: Hazard designation: Safety designation: EUH208 May produce an allergic reaction. Hazardous components for labelling: Other Hazards Contains 1,2-Benzisothiazol-3(2H)-one: can cause allergic 2

2 reactions. 3. Composition/Information on Ingredients Substance Mixture This produkt is a mixture. Page 2 Chemical Characterization: Information on Components / Hazardous Ingredients: This product does not contain any hazardous components according to EC Directive 1272/ Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Exempted from the mandatory REACH Registration. Seek medical attention in case of complaints. Supply fresh air. Wash off with plenty of water and soap. Consult a physician if irritation persists. Rinse open eyes with plenty of water. In case of discomfort seek medical help After ingestion: Most important Symptoms and Effects, both Acute and Delayed Rinse mouth with water and give plenty of water to drink. Consult a physician. Never give anything by mouth to an unconscious person. Symptoms: No further information available Effects: No further information available. Indication of any Immediate Medical Attention and special Treatment needed Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: No further information available. Use extinguishing media for surrounding fire. Unsuitable extinguishing media: None known. 3

3 5. 2. Special Hazards arising from the Substance or Mixture Page Special hazards: Advice for Firefighters Protective equipment: Material can splatter above 100 C/212 F. Dried product can burn. Wear self-contained respiratory protective device and protective clothing Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Personal precautions: Environmental Precautions Wear appropriate protective equipment. Keep spectators away. Floor may be slippery; use care to avoid falling Environmental precautions: Methods and Material for Containment and Cleaning Up Caution: Keep spills and cleaning runoff out of municipal sewers and open bodies of water Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Contain with absorbent material (e.g. sand, acid binder, universal binder, sawdust) and collect in appropriate containers for disposal. See Section 13 for information on disposal. Avoid contact with eyes, skin and clothing. Do not breathe vapors, spray or gas Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Wash hands at the end of work. Preventive skin protection recommended. Storage conditions: Requirements for storage areas and containers: Keep from freezing; material may coagulate. Store between 1-49 C ( F). Stir well before use. Store in closed container and keep product dry. No special measures necessary. Information on fire and explosion protection: Monomer vapors may be evolved when material is heated during 4

4 processing operations. Page 4 Storage class (VCI): Further Information: Specific End Use(s) Further information: Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): No exposure limits for this product. Parameters to be controlled: Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): No values available. No values available Additional Information: Exposure Controls Technical protective measures: Use local exhaust ventilation in case of dust and/or fume formation. Facilities storing or utilizing this material should be equipped with an eyewash facility. Personal Protection General protective measures: Respiratory protection: Hand protection: Protective glove material: Eye protection: Remove contaminated clothing. Wash hands after work. Respiratory equipment required in case of insufficient ventilation, filter combination type A-P2. Chemical protective gloves (EN 374 (Europe), F739 (US)). Recommended: Protective index 4, > 120 min. of permeation time (EN 374). Butyl rubber, nitrile rubber (NBR), natural rubber (NR), polyvinyl chloride (PVC) Not suitalble material: Neoprene Safety glasses with protective shields (EN 166). Chemical splash goggles (ANSI Z87,1 or approved equivalent). Body protection: Environmental precautions: 5

5 Physical and Chemical Properties Information on Basic Physical and Chemical Properties Page 5 Prevent contamination of open water ways and sewage system. Avoid contamination of ground water. Form: Color: Odor: Odor threshold: liquid milky white acrylic ph-value: Melting temperature: Boiling temperature: Flash point: Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: Explosive properties: Oxidizing properties: 0 C (H20) 100 C (H20) not combustible < 1 H20 not available not determined not determined 2226,474 Pa (20 C; H2O) < 1 H2O g/cm3 dilutable no information available No data available mpa.s not available Bulk density: 6

6 9. 2. Further Information Page Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects Irritant effect on skin: Percent volatility: % water None known. Unknown. Thermal decomposition may yield acrylic monomers. There are no known products which are incompatible with this product. Product does not polymerize. > 5000 mg/kg (rat) > 2000 mg/kg (rabbit) Vapors may cause respiratory irritation. Slight irritant effect possible (rabbit) Irritant effect on eyes: Can cause a slight temporary eye irritation. 7

7 A corneal injury is unlikely. Page Inhalation: Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: Carcinogenicity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects No information available Aspiration hazard: not applicable By analogy with a product of similar composition. No data available. no information available On the basis of available data, the product does not contain and PBT or vpvb in percentage greater than 0.1 %. Water hazard class: 8

8 1, slightly hazardous Page 8 Behaviour in sewage systems: Further ecological effects: No ecological problems expected. No ecological data available AOX Value: Disposal Considerations Waste Treatment Methods Product: Coagulate the emulsion by the stepwise addition of ferric chloride and lime. Remove the clear supernatant and flush to a chemical sewer. Incinerate liquid and contaminated solids in accordance with local, state and federal regulations. Dispose of according to official national and local regulations. European Waste Code (EWC): Uncleaned packaging: Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: IMDG/IATA: Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel restriction code: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG. not applicable not applicable ADR/RID: 9

9 Page 9 not applicable IMDG: IATA: Environmental Hazards Special Precautions for User None Not classified as a dangerous good under transport regulations Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code not applicable Further Information Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: Local regulations on chemical accidents: 1, slightly hazardous for water (German Regulation) Seveso III Directive: not applicable under Directive 2012/18/EC Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information A Chemical Safety Assessment is not necessary for this product. REACH: This mixture contains exclusively components which have been either pre-registered, are exempted from registration or must not be registered according to EC Regulation 1907/2006 (REACH). Polymers are exempted from the REACH Registration. This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.