SAFETY DATA SHEET. This SDS complies with REACH 1907/2006 and 2001/58/EC, GHS REVISION 5, OSHA 29CFR

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1 SAFETY DATA SHEET This SDS complies with REACH 1907/2006 and 2001/58/EC, GHS REVISION 5, OSHA 29CFR Section 1: Chemical Product and Company Identification Part No. VINYBLAN 701 / 700 SDS Page 1 of 6 CHEMICAL SUPPLIER COMPANY NAME EMERGENCY TELEPHONE Shin-Etsu MicroSi, Inc. Chemtrec 24 HOUR: (800) South 51 st Street Information: (480) Phoenix, AZ Fax: (480) Safety Data Sheet Competent Person: Customer Service csteam@microsi.com MANUFACTURER S NAME: Nissin Chemical Industry Co., Ltd. ADDRESS: Uchikanda TK Bldg Uchikanda, Chiyodaku, Tokyo, , Japan TELEPHONE NUMBER: FAX NUMBER: DATE PREPARED: March 1, 2012 DATE REVIEWED: August 23, 2015 PRODUCT NAME: VINYBLAN 701 / 700 CHEMICAL FAMILY: PRODUCT USE: Section 2: Hazards Identification Colloidal dispersion of PVC copolymer in water. This product is intended for use in inks, coatings, adhesives, and sealants. GHS Hazard Class Not Applicable. This product does not meet the physical, health, or environmental classification criteria of GHS (Globally Harmonized System). Hazards not otherwise classified (HNOC) or not covered by GHS: Wear protective gloves/protective clothing/eye protection/face protection. Store in a closed container. Dispose of contents/container: Follow the waste disposal requirements of your country, state, or local authorities. <40 % of mixture consists of ingredients of unknown acute toxicity HAZARD CLASSIFICATION: FIRE AND EXPLOSION: APPEARANCE: Not Hazardous Not considered flammable or combustible. Milky - white liquid NFPA RATINGS: Component Health Flammability Instability (Blue) (Red) (Yellow) VINYBLAN 701 / Special (White) SAFETY NOTICE VINYL CHLORIDE EXPOSURE The manufacturing process of Vinyblan products results in residual Vinyl Chloride (VC) being contained in the product. During shipment, the exposure of this product to ambient temperatures causes the residual VC to volatilize and accumulate within the shipping container. Vinyl Chloride has both a very low flash point (-108 F) and boiling point (7 F). Ambient air testing has been conducted to determine the initial concentration of VC that an employee may be exposed to when opening the container doors prior to unloading the product. The OSHA exposure limit for VC is 1 ppm TWA including a 15-minute ceiling limit of 5 ppm. Vinyl Chloride is an IARC Group 1 carcinogen. 15 minute test results in shipping containers completely full of Solbin products have confirmed Vinyl Chloride concentrations at >10 ppm. However, after leaving the container doors open for an hour or more the laboratory reported VC concentrations are non-detect.

2 Part No. VINYBLAN 701 / 700 SDS Page 2 of 6 Section 3: Composition, Information on Ingredients PRODUCT COMPOSITION APPROX % CAS NO. Water > Vinyl chloride copolymer <20 TS Acrylic copolymer <20 TS <300 ppm Vinyl Chloride residual (<0.03%) Some items on this SDS may be designated as trade secrets (TS). Bona fide requests for disclosure of trade secret information to medical personnel must be made in accordance with the provisions contained in 29 CFR I Section 4: First Aid Measures Description of First Aid Measures INHALATION: SKIN CONTACT: EYE CONTACT: INGESTION: Remove to fresh air. If not breathing, provide CPR (cardio pulmonary resuscitation) get immediate medical attention. Wash skin with clean water. Get medical attention if irritation persists. Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation persists. If swallowed do not induce vomiting, give large quantities of water to drink. Never give anything to an unconscious person. Get immediate medical attention. Most important symptoms and effects, both acute and delayed Symptoms/Injuries after Inhalation Symptoms/Injuries after Skin Contact Symptoms/Injuries after Eye Contact Symptoms/Injuries after Ingestion May cause respiratory tract irritation. May cause skin irritation. Symptoms may include redness, drying, defatting, and cracking of the skin. May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness and swelling. May be harmful if swallowed. May cause stomach distress, nausea, or vomiting. Indication of any immediate medical attention and special treatment needed Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately. Section 5: Fire-fighting Measures Suitable extinguishing media Special hazards arising from the substance or mixture Protective actions fire-fighters Further information Section 6: Accidental Release Measures Personal precautions, protective equipment, and emergency procedures Wear proper personal protective equipment. Avoid breathing vapors or mist. Use foam, dry chemical, or carbon dioxide. During fire, irritating and highly toxic gas may be generated by thermal decomposition or combustion. Wear standard protective equipment and self contained breathing apparatus for firefighting if necessary. Use water spray to cool unopened containers. Environmental precautions Prevent further leakage or spillage if safe to do so. Prevent spills or contaminated rinse water from entering sewers or watercourses. Methods and materials for containment and cleaning up In case of small spills, absorb with inert materials such as earth or dry sand. Place in a chemical waste container.

3 In case of large spills, dike the spill, if possible. Call emergency services. Absorb the chemical. Part No. VINYBLAN 701 / 700 SDS Page 3 of 6 Reference to other Sections For personal protection reference section 8. For disposal reference section 13. Section 7: Handling and Storage Precautions for safe handling Store a 5 C 35 C. Prevent exposure to sunlight. Prevent freezing of product. Use only in well ventilated areas. Keep container closed when not in use. Wear proper protective equipment when handling this material. Avoid contact with skin, eyes or clothing. Wash hands after handling this material. Conditions for safe storage, including any incompatibilities Use only in well ventilated areas. Store upright in a cool, well ventilated location. Prevent freezing of product. Protect from direct sunlight. Follow all applicable local regulations for handling and storage. Utilize chemical segregation. Specific uses This product is intended for use in inks, coatings, adhesives, and sealants. Section 8: Exposure Controls/Personal Protection Control Parameters Exposure controls VENTILATION: RESPIRATORY PROTECTION: PROTECTIVE GLOVES: EYE PROTECTION: PROTECTIVE CLOTHING: OTHER EQUIPMENT: WORK/HYGIENE PRACTICES: PRODUCT COMPOSITION ACGIH TLV OSHA PEL NIOSH REL Water Vinyl chloride copolymer Acrylic copolymer Vinyl Chloride residual 1 ppm; 2.6 mg/m3 Section 9: Physical and Chemical Properties 1 ppm; 5 ppm 15 min Ceiling PRODUCT CRITERIA APPEARANCE COLOR: Milky white dispersion PHYSICAL STATE: Liquid ODOR: Peculiar odor ODOR THRESHOLD PH 6-10 MELTING POINT/FREEZING POINT: Always provide good general, mechanical room ventilation where this chemical is used. Not required. Wear chemical impervious gloves at all times while working with this product. Recommended glove types include: Laminate Film, Nitrile, or Tri-polymer. Check with your company s glove supplier to ensure chemical resistance. Safety Glasses, Chemical goggles, face shield Wear suitable protective clothing to prevent skin contact. Make safety shower, eyewash stations, and hand washing equipment available in the work area. Avoid contact with eyes. Wash hands after handling

4 INITIAL BOILING POINT AND BOILING RANGE: Approximately 100 ºC FLASH POINT: Part No. VINYBLAN 701 / 700 SDS Page 4 of 6 EVAPORATION RATE: Negligible FLAMMABILITY (Solid, gas) UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS Not Measured VAPOR PRESSURE Negligible VAPOR DENSITY (AIR = 1) RELATIVE DENSITY (@25 o C): SOLUBILITY(IES) Infinite solubility in water OXIDIZING PROPERTIES PARTITION COEFFICIENT: n-octanol/water AUTO IGNITION TEMPERATURE DECOMPOSITION TEMPERATURE VISCOSITY VOC CONTENT Section 10: Stability and Reactivity Reactivity: Chemical Stability: Possibility of Hazardous Reactions: Conditions to Avoid: Incompatibility (Materials to Avoid): Hazardous Decomposition Products: Not reactive. Stable Will not occur Heat, direct sunshine, contact with acids, metallic oxides, amines, combustible materials, sparks, and other sources of ignition. Acids, metallic oxides, amines, and combustible materials. Toxic fumes of carbon monoxide, carbon dioxide, and/or hydrogen chloride when heated to decomposition of the polymer. Section 11: Toxicological Information GHS Required Criteria Toxicity Criteria Toxicity Information Comments Chemical Constituent Acute Toxicity Skin Corrosion/Irritation Serious Eye Damage / Eye Irritation Respiratory or Skin Sensitization Germ Cell Mutagenicity Tumorigenic Carcinogenicity NTP Not listed IARC Group 1 Vinyl chloride OSHA Not listed Reproductive Toxicity STOT -- Single Exposure STOT Repeated Exposure Aspiration Hazard STOT = Specific Target Organ Toxicity Section 12: Ecological Information Toxicity: Persistence and degradability: Bioaccumulative potential Mobility in soil: PBT and vpvb assessment: Other adverse effects:.... PBT/vPvB assessment not available as chemical assessment not required/not conducted. Section 13: Disposal Considerations Waste from residues/unused products: Follow the waste disposal requirements of your country, state, or local authorities. Contaminated packaging: Contaminated packaging material should be disposed of as stated above for residues and unused product. Rinsate: Do not dispose of rinse water containing product in a sanitary sewer system or stormwater drainage system.

5 Part No. VINYBLAN 701 / 700 SDS Page 5 of 6 Section 14: Transport Information DOT TRANSPORT: ADR = International Carriage of Dangerous Goods by Road RAIL TRANSPORT: Not Regulated Not Regulated Not Regulated SEA TRANSPORT: IMDG Not Regulated AIR TRANSPORT: IATA/ICAO Not Regulated Section 15: Regulatory Information TOXIC SUBSTANCES CONTROL ACT (TSCA) STATUS: This product is in compliance with rules, regulations, and orders of TSCA. All components are listed on the TSCA Inventory. SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA) TITLE III SECTION 313 SUPPLIER NOTIFICATION: This regulation requires submission of annual reports of toxic chemical(s) that appear in section 313 of the Emergency Planning and Community Right To Know Act of 1986 and 40 CFR 372. This information must be included in all SDS s that are copied and distributed for the material. The toxic chemicals contained in this product are: Vinyl Chloride CALIFORNIA PROPOSITION 65: This regulation requires a warning for California Proposition 65 chemical(s) under the statute. The California proposition 65 chemical(s) contained in this product are: Vinyl Chloride WARNING: This product contains a chemical (lead) known by the State of California to cause cancer, birth defects, or other reproductive harm. Vinyl chloride: Carcinogen. No Significant Risk Level (NSRL) 3 µg/day STATE TOXIC SUBSTANCE OR HAZARDOUS SUBSTANCE LIST (State Right-to-Know): Florida Toxic Substance(s): None Massachusetts hazardous substance: Vinyl Chloride Pennsylvania hazardous substance: Vinyl Chloride New Jersey Vinyl Chloride Illinois: None Section 16: Other Information Initial issue date: December 20, 2013 Final revision date: August 23, 2015 Revision Number: 3 Revision explanation Compliance with the OSHA GHS SDS format Information Sources: RTECS, ECHA, REACH, OSHA 29CFR FOR INDUSTRIAL USE ONLY THIS SAFETY DATA SHEET IS OFFERED SOLELY FOR YOUR INFORMATION, CONSIDERATION, AND INVESTIGATION. THE DATA DESCRIBED IN THIS SDS CONSIST OF DATA ON LITERATURE, OUR ACQUISITIONAL DATA, AND ANALOGICAL INFERENCE BY DATA OF SIMILAR CHEMICAL SUBSTANCES OR PRODUCTS. SHIN-ETSU CHEMICAL CO. LTD. PROVIDES NO WARRANTIES, EITHER EXPRESSED OR IMPLIED, AND ASSUMES NO RESPONSIBILITY FOR THE ACCURACY OR COMPLETENESS OF THE DATA CONTAINED HEREIN. ADDITIONAL INFORMATION

6 Part No. VINYBLAN 701 / 700 SDS Page 6 of 6 THIS DATA IS OFFERED IN GOOD FAITH AS TYPICAL VALUES AND NOT AS A PRODUCT SPECIFICATION. NO WARRANTY, EITHER EXPRESSED OR IMPLIED, IS MADE. THE RECOMMENDED HANDLING PROCEDURES ARE BELIEVED TO BE GENERALLY APPLICABLE.