Safety Data Sheet Basazol Brown 43 L NA Revision date : 2017/07/26 Page: 1/10

Transcription

1 Revision date : 2017/07/26 Page: 1/10 1. Identification Product identifier used on the label Basazol Brown 43 L NA Recommended use of the chemical and restriction on use Recommended use*: Colorants for the paper industry * The Recommended use identified for this product is provided solely to comply with a Federal requirement and is not part of the seller's published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express or implied, including by incorporation into or reference in the seller's sales agreement. Details of the supplier of the safety data sheet Company: BASF Canada Inc. 100 Milverton Drive Mississauga, ON L5R 4H1, CANADA Telephone: Emergency telephone number CANUTEC (reverse charges): (613) BASF HOTLINE: (800) 454-COPE (2673) Other means of identification Chemical family: azo dye 2. Hazards Identification According to Hazardous Products Regulations (HPR) (SOR/ ) Classification of the product Met. Corr. 1 Corrosive to metals Skin Corr./Irrit. 1A Skin corrosion/irritation Eye Dam./Irrit. 1 Serious eye damage/eye irritation STOT SE 3 (irritating to Specific target organ toxicity single exposure respiratory system) Aquatic Acute 2 Hazardous to the aquatic environment - acute Aquatic Chronic 2 Hazardous to the aquatic environment - chronic Label elements

2 Revision date : 2017/07/26 Page: 2/10 Pictogram: Signal Word: Danger Hazard Statement: H290 H335 H314 H401 H411 May be corrosive to metals. May cause respiratory irritation. Causes severe skin burns and eye damage. Toxic to aquatic life. Toxic to aquatic life with long lasting effects. Precautionary Statements (Prevention): P280 Wear protective gloves/protective clothing/eye protection/face protection. P273 Avoid release to the environment. P271 Use only outdoors or in a well-ventilated area. P260 Do not breathe dust or mist. P264 Wash with plenty of water and soap thoroughly after handling. P234 Keep only in original packaging. Precautionary Statements (Response): P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P391 Collect spillage. P390 Absorb spillage to prevent material damage. Precautionary Statements (Storage): P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P406 Store in a corrosion-resistant/ container with a resistant inner liner. Precautionary Statements (Disposal): P501 Dispose of contents/container in accordance with local regulations. Hazards not otherwise classified If applicable information is provided in this section on other hazards which do not result in classification but which may contribute to the overall hazards of the substance or mixture. 3. Composition / Information on Ingredients According to Hazardous Products Regulations (HPR) (SOR/ ) CAS Number Weight % Chemical name HMIRA Registry #: 11731, Date of Filing: 26 July 2017

3 Revision date : 2017/07/26 Page: 3/ >= < 50.0% Acetic acid Trade Secret >= < 20.0% Acetate salt of azo linked phenylenediamines 4. First-Aid Measures Description of first aid measures General advice: Remove contaminated clothing. If inhaled: Remove the affected individual into fresh air and keep the person calm. Assist in breathing if necessary. Immediate medical attention required. If on skin: Wash affected areas thoroughly with soap and water. Immediate medical attention required. If in eyes: Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist. If swallowed: Rinse mouth and then drink plenty of water. Most important symptoms and effects, both acute and delayed Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11. Hazards: No hazard is expected under intended use and appropriate handling. Indication of any immediate medical attention and special treatment needed Note to physician Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. 5. Fire-Fighting Measures Extinguishing media Suitable extinguishing media: water spray, dry powder, foam, carbon dioxide Special hazards arising from the substance or mixture Hazards during fire-fighting: No particular hazards known. Advice for fire-fighters Protective equipment for fire-fighting: Firefighters should be equipped with self-contained breathing apparatus and turn-out gear.

4 Revision date : 2017/07/26 Page: 4/10 Further information: Dispose of fire debris and contaminated extinguishing water in accordance with official regulations. Keep people away and stay on the upwind side. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Breathing protection required. Environmental precautions Do not empty into drains. Methods and material for containment and cleaning up For small amounts: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr). Dispose of absorbed material in accordance with regulations. For large amounts: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr). Dispose of absorbed material in accordance with regulations. 7. Handling and Storage Precautions for safe handling Ensure thorough ventilation of stores and work areas. Handle in accordance with good industrial hygiene and safety practice. Remove contaminated clothing and protective equipment before entering eating areas. Hands and/or face should be washed before breaks and at the end of the shift. When using do not eat, drink or smoke. Avoid all direct contact with the substance/product. Protection against fire and explosion: No special precautions necessary. Conditions for safe storage, including any incompatibilities Segregate from foods and animal feeds. Further information on storage conditions: Keep container tightly closed and dry; store in a cool place. Avoid extremes of temperature, especially frost and freezing conditions. Avoid extreme heat. Storage stability: Storage temperature: 0-60 C 8. Exposure Controls/Personal Protection Components with occupational exposure limits Acetic acid OSHA PEL PEL 10 ppm 25 mg/m3 ; TWA value 10 ppm 25 mg/m3 ; ACGIH TLV STEL value 15 ppm ; TWA value 10 ppm ; Advice on system design: Provide local exhaust ventilation to maintain recommended P.E.L. Personal protective equipment Respiratory protection: Wear respiratory protection if ventilation is inadequate.

5 Revision date : 2017/07/26 Page: 5/10 Hand protection: Chemical resistant protective gloves Eye protection: Tightly fitting safety goggles (chemical goggles). Wear face shield if splashing hazard exists. Body protection: Impermeable protective clothing General safety and hygiene measures: Do not inhale gases/vapours/aerosols. Handle in accordance with good industrial hygiene and safety practice. Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks). Take off immediately all contaminated clothing. Wash contaminated clothing before reuse. Store work clothing separately. 9. Physical and Chemical Properties Form: liquid Odour: of acetic acid, moderate odour Odour threshold: Colour: brown ph value: approx. 3.5 ( 100 g/l, 20 C) approx. 3-4 Freezing point: approx. -20 C ( 1 ATM) Boiling range: > 100 C C ( 1 ATM) Boiling point: C (other) ( 1,013 hpa) Literature data. Sublimation point: Flash point: > 100 C (DIN 51758) Flash point: 39 C (other, closed cup) Literature data. Flammability: not flammable Lower explosion limit: Upper explosion limit: Autoignition: Based on the water content the product does not ignite. Autoignition: 463 C Literature data. Vapour pressure: Vapour pressure: 12.1 mmhg ( 20 C) 20.9 hpa ( 25 C) Literature data. (measured)

6 Revision date : 2017/07/26 Page: 6/10 Density: Relative density: Vapour density: Partitioning coefficient n- octanol/water (log Pow): Self-ignition temperature: Thermal decomposition: Viscosity, dynamic: Viscosity, kinematic: Solubility in water: Miscibility with water: Solubility (quantitative): Solubility (qualitative): Evaporation rate: Other Information: 10. Stability and Reactivity Reactivity Corrosion to metals: Corrosive effect on metals. Oxidizing properties: not fire-propagating approx g/cm3 ( 20 C) not self-igniting miscible miscible miscible solvent(s): organic solvents, If necessary, information on other physical and chemical parameters is indicated in this section. Chemical stability The product is stable if stored and handled as prescribed/indicated. Possibility of hazardous reactions The product is chemically stable. Conditions to avoid Avoid extreme heat. Incompatible materials No substances known that should be avoided. Hazardous decomposition products Decomposition products: Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. Thermal decomposition: 11. Toxicological information Primary routes of exposure

7 Revision date : 2017/07/26 Page: 7/10 Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquefied gases. Acute Toxicity/Effects Acute toxicity Assessment of acute toxicity: Virtually nontoxic after a single ingestion. Virtually nontoxic after a single skin contact. The inhalation of a highly enriched/saturated vapor-air-mixture represents an unlikely acute hazard. Oral Type of value: LD50 Species: rat Value: > 5,000 mg/kg (BASF-Test) The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Inhalation Species: rat Exposure time: 8 h Inhalation-risk test (IRT): No mortality within 8 hours as shown in animal studies. The inhalation of a highly saturated vapor-air mixture represents no acute hazard. Dermal Type of value: LD50 Species: rat Value: > 5,000 mg/kg (BASF-Test) The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Assessment other acute effects Assessment of STOT single: Causes temporary irritation of the respiratory tract. Irritation / corrosion Assessment of irritating effects: Corrosive! Damages skin and eyes. Sensitization Assessment of sensitization: A sensitizing effect on particularly sensitive individuals cannot be excluded. Chronic Toxicity/Effects Repeated dose toxicity Assessment of repeated dose toxicity: Genetic toxicity Assessment of mutagenicity: The substance was mutagenic in a bacterial test system. The substance was not mutagenic in mammalian cell culture. The substance was not mutagenic in a test with mammals. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Carcinogenicity Assessment of carcinogenicity: Based on the ingredients there is no suspicion of a carcinogenic effect in humans.

8 Revision date : 2017/07/26 Page: 8/10 Reproductive toxicity Assessment of reproduction toxicity: Other Information The product has not been tested. The statement has been derived from the properties of the individual components. Symptoms of Exposure The most important known symptoms and effects are described in the labelling (see section 2) and/or in section Ecological Information Toxicity Aquatic toxicity Assessment of aquatic toxicity: Acutely toxic for aquatic organisms. May cause long-term adverse effects in the aquatic environment. Depending on local conditions and existing concentrations, disturbances in the biodegradation process of activated sludge are possible. Persistence and degradability Assessment biodegradation and elimination (H2O) Colourants are by their nature very stable and are therefore not readily biodegradable under conditions prevailing in surface water or in effluent treatment plants. Elimination information % colour reduction (Static test) Bioaccumulative potential Assessment bioaccumulation potential Discharge into the environment must be avoided. Assessment bioaccumulation potential Accumulation in organisms is not to be expected. Mobility in soil Assessment transport between environmental compartments The substance will not evaporate into the atmosphere from the water surface. Adsorption to solid soil phase is expected. The substance will not evaporate into the atmosphere from the water surface. Adsorption to solid soil phase is not expected.

9 Revision date : 2017/07/26 Page: 9/10 Additional information Other ecotoxicological advice: The product has not been tested. The statement has been derived from the properties of the individual components. 13. Disposal considerations Waste disposal of substance: Must be disposed of or incinerated in accordance with local regulations. Container disposal: Uncontaminated packaging can be re-used. Packs that cannot be cleaned should be disposed of in the same manner as the contents. 14. Transport Information Land transport TDG Hazard class: 8 Packing group: III ID number: UN 2801 Hazard label: 8, EHSM Proper shipping name: DYE, LIQUID, CORROSIVE, N.O.S. (contains ACETIC ACID, C.I.BASIC BROWN 1) Sea transport IMDG Hazard class: 8 Packing group: III ID number: UN 2801 Hazard label: 8, EHSM Marine pollutant: YES Proper shipping name: DYE, LIQUID, CORROSIVE, N.O.S. (contains ACETIC ACID, C.I.BASIC BROWN 1) Air transport IATA/ICAO Hazard class: 8 Packing group: III ID number: UN 2801 Hazard label: 8 Proper shipping name: DYE, LIQUID, CORROSIVE, N.O.S. (contains ACETIC ACID, C.I.BASIC BROWN 1) 15. Regulatory Information Federal Regulations Registration status:

10 Revision date : 2017/07/26 Page: 10/10 Chemical DSL, CA released / listed 16. Other Information SDS Prepared by: BASF NA Product Regulations SDS Prepared on: 2017/07/26 We support worldwide Responsible Care initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products. Basazol Brown 43 L NA is a registered trademark of BASF Canada or BASF SE END OF DATA SHEET