MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET Product Trade Name: Revision Date: 19-Sep CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Trade Name: Synonyms: Chemical Family: Application: Manufacturer/Supplier Prepared By None Blend Hydrogen Sulfide Scavenger Halliburton Energy Services, Inc. P.O. Box 1431 Duncan, Oklahoma Emergency Telephone: (281) Chemical Compliance Telephone: COMPOSITION/INFORMATION ON INGREDIENTS Substances CAS Number PERCENT (w/w) ACGIH TLV-TWA OSHA PEL-TWA 1,3,5 Trimethylbenzene % TWA: 25 ppm 25 ppm Diethylamine % TWA: 5 ppm 25 ppm STEL: 15 ppm 1,2,3-Trimethylbenzene % 25 ppm Not applicable Naphthalene < 0.1% TWA: 10 ppm 10 ppm STEL: 15 ppm Light aromatic solvent % Not applicable Not applicable 1,2,4 Trimethylbenzene % 25 ppm Not applicable Isopropanol % TWA: 200 ppm 400 ppm STEL: 400 ppm Xylene % TWA: 100 ppm 100 ppm STEL: 150 ppm Cumene % TWA: 50 ppm 50 ppm (S) Hydrogen sulfide < 0.1% TWA: 1 ppm 20 ppm STEL: 5 ppm Diisobutyl ketone % 25 ppm 50 ppm 3. HAZARDS IDENTIFICATION Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed. May be absorbed through the skin. Potential carcinogen. Combustible. 4. FIRST AID MEASURES Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention. Page 1 of 7

2 Skin Eyes Ingestion Notes to Physician In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. Get medical attention. Remove contaminated clothing and launder before reuse. Immediately flush eyes with large amounts of water for at least 30 minutes. Seek prompt medical attention. Do not induce vomiting. Administer 2-3 tablespoons of activated charcoal. Burnt toast can be used if charcoal is unavailable. Obtain medical assistance immediately. Not Applicable 5. FIRE FIGHTING MEASURES Flash Point/Range (F): Flash Point/Range (C): Flash Point Method: Autoignition Temperature (F): Autoignition Temperature (C): Flammability Limits in Air - Lower (%): Flammability Limits in Air - Upper (%): TCC Fire Extinguishing Media Special Exposure Hazards Special Protective Equipment for Fire-Fighters Carbon Dioxide, Dry Chemicals, Foam. May be ignited by heat, sparks or flames. Use water spray to cool fire exposed surfaces. Closed containers may explode in fire. Avoid spraying water directly into storage containers due to danger of boilover. Decomposition in fire may produce toxic gases. Vapors are heavier than air and may accumulate in low areas. Vapors may travel along the ground to be ignited at distant locations. Full protective clothing and approved self-contained breathing apparatus required for fire fighting personnel. NFPA Ratings: Health 3, Flammability 3, Reactivity 0 HMIS Ratings: Health 3, Flammability 3, Reactivity 0, PPE: X 6. ACCIDENTAL RELEASE MEASURES Personal Precautionary Measures Environmental Precautionary Measures Procedure for Cleaning / Absorption Use appropriate protective equipment. Wear self-contained breathing apparatus in enclosed areas. Prevent from entering sewers, waterways, or low areas. Isolate spill and stop leak where safe. Remove ignition sources and work with non-sparking tools. Contain spill with sand or other inert materials. Scoop up and remove. 7. HANDLING AND STORAGE Handling Precautions Storage Information Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after use. Launder contaminated clothing before reuse. Ground and bond containers when transferring from one container to another. Avoid breathing mist. Keep from heat, sparks, and open flames. Keep container closed when not in use. Page 2 of 7

3 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls Respiratory Protection Use in a well ventilated area. Local exhaust ventilation should be used in areas without good cross ventilation. Not normally needed. But if significant exposures are possible then the following respirator is recommended: Organic vapor respirator. Hand Protection Skin Protection Eye Protection Other Precautions Nitrile gloves. Neoprene gloves. Rubber boots. Nitrile coated apron or clothing. Chemical goggles; also wear a face shield if splashing hazard exists. Eyewash fountains and safety showers must be easily accessible. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: Dark Odor: Aromatic hydrocarbon Sweet ph: Specific 20 C (Water=1): C (lbs./gallon): 7.25 Bulk 20 C (lbs/ft3): Boiling Point/Range (F): Boiling Point/Range (C): Freezing Point/Range (F): Freezing Point/Range (C): Vapor 20 C (mmhg): Vapor Density (Air=1): >1 Percent Volatiles: Evaporation Rate (Butyl Acetate=1): > 1 Solubility in Water (g/100ml): Disperses Solubility in Solvents (g/100ml): VOCs (lbs./gallon): Viscosity, 20 C (centipoise): Viscosity, 20 C (centistokes): Partition Coefficient/n-Octanol/Water: Molecular Weight (g/mole): 10. STABILITY AND REACTIVITY Stability Data: Hazardous Polymerization: Conditions to Avoid Incompatibility (Materials to Avoid) Hazardous Decomposition Products Stable Will Not Occur Keep away from heat, sparks and flame. Strong oxidizers. Carbon monoxide and carbon dioxide. Page 3 of 7

4 Additional Guidelines Not Applicable 11. TOXICOLOGICAL INFORMATION Principle Route of Exposure Eye or skin contact, inhalation. Sympotoms related to exposure Acute Toxicity Inhalation Eye Contact Skin Contact Ingestion Chronic Effects/Carcinogenicity Causes severe respiratory burns. Causes severe eye burns. May cause skin burns. Harmful if absorbed through the skin. Causes burns of the mouth, throat and stomach. Aspiration into the lungs may cause chemical pneumonitis including coughing, difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal. Cumene ( ) is classified by IARC as: Group 2B, Possibly carcinogenic to humans. Toxicology data for the components Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation 1,3,5 Trimethylbenzene mg/kg ( Rat ) 5000 mg/kg ( No data available 24 g/m 3 ( Rat ) 4 h Rat ) Diethylamine mg/kg ( Rat ) 582 mg/kg ( Rabbit ) 12.1 mg/l ( Rat ) 4 h 4000 ppm ( Rat ) 4 h 1,2,3-Trimethylbenzene mg/kg ( Rat ) No data available No data available Naphthalene mg/kg ( Rat ) 2500 mg/kg (Rat) 340 mg/m 3 ( Rat ) 1 h 20 g/kg (Rabbit) 1120 mg/kg (Rabbit) Light aromatic solvent mg/kg ( Rat ) 2000 mg/kg ( Rabbit ) 5.2 mg/l ( Rat ) 4 h 3400 ppm ( Rat ) 4 h 1,2,4 Trimethylbenzene mg/kg ( Rat ) 8970 mg/kg ( 3160 mg/kg ( Rabbit ) 18 g/m 3 ( Rat ) 4 h Rat ) Isopropanol mg/kg ( Rat ) mg/kg ( Rat ) 72.6 mg/l ( Rat ) 4 h 3600 mg/kg (mouse) mg/kg ( Rabbit ) Xylene mg/kg ( Rat ) 1700 mg/kg ( Rabbit ) mg/l ( Rat ) 4 h 5000 ppm ( Rat ) 4 h Cumene mg/kg ( Rat ) 3160 mg/kg ( Rabbit ) mg/m 3 ( Rat ) 4 h Hydrogen sulfide No data available No data available 0.99 mg/l ( Rat ) 1 h mg/l ( Rat ) 4 h Diisobutyl ketone No data available No data available No data available 12. ECOLOGICAL INFORMATION Ecotoxicological Information Ecotoxicity Product Acute Fish Toxicity: Acute Crustaceans Toxicity: Acute Algae Toxicity: Not determined Not determined Not determined Ecotoxicity Substance Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to Microorganisms 1,3, LC50: 3.48 mg/l Trimethylbenzene Daphnia Magna (Water Flea) EC50: 50 mg/l (Daphnia magna) Diethylamine ,2,3-Trimethylbenzen e Page 4 of 7

5 Naphthalene EC50: 0.4 mg/l (Skeletonema costatum) mg/l 1.2 mg/l (Oncorhynchus gorbuscha) LC50: 2.16 mg/l Light aromatic solvent ,2,4 Trimethylbenzene Isopropanol EC50: > 1000 mg/l(desmodesmus subspicatus) LC50: mg/l LC50: 9640 mg/l Xylene LC50: 13.4 mg/l EC50: 6.14 mg/l EC50: mg/l EC50: 3.82 mg/l Cumene Hydrogen sulfide Diisobutyl ketone Persistence and degradability 12.3 Bioaccumulative potential Substances Log Pow Naphthalene ,2,4 Trimethylbenzene Mobility in soil 12.5 Results of PBT and vpvb assessment Other adverse effects 13. DISPOSAL CONSIDERATIONS Disposal Method Contaminated Packaging Disposal should be made in accordance with federal, state, and local regulations. Follow all applicable national or local regulations. 14. TRANSPORT INFORMATION Land Transportation DOT UN2924, Flammable Liquid, Corrosive, N.O.S. (Contains Isopropanol, Diethylamine), 3, (8), III, (42 C) NAERG 132 Canadian TDG Flammable Liquid, Corrosive, N.O.S. (Contains Isopropanol, Diethylamine), 3, (8), UN2924, III, (42 C) ADR UN2924, Flammable Liquid, Corrosive, N.O.S (Contains Isopropanol, Diethylamine), 3, (8), III Air Transportation Page 5 of 7

6 ICAO/IATA UN2924, Flammable Liquid, Corrosive, N.O.S, 3, (8), III (Contains Isopropanol, Diethylamine) Sea Transportation IMDG UN2924, Flammable Liquid, Corrosive, N.O.S (Contains Isopropanol, Diethylamine), 3, (8), III, (42 C) EmS F-E, S-C Other Transportation Information Labels: Flammable Liquid Corrosive 15. REGULATORY INFORMATION US Regulations US TSCA Inventory EPA SARA Title III Extremely Hazardous Substances EPA SARA (311,312) Hazard Class Product contains one or more components not listed on the inventory. Not applicable Acute Health Hazard Chronic Health Hazard Fire Hazard EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372: Xylene// ,2,4-Trimethylbenzene// EPA CERCLA/Superfund Reportable Spill Quantity EPA RCRA Hazardous Waste Classification EPA Reportable Spill Quantity is 382 Gallons based on Diethylamine (CAS: ). If product becomes a waste, it does meet the criteria of a hazardous waste as defined by the US EPA, because of: Ignitability D001 California Proposition 65 MA Right-to-Know Law NJ Right-to-Know Law PA Right-to-Know Law The California Proposition 65 regulations apply to this product. One or more components listed. One or more components listed. One or more components listed. Canadian Regulations Canadian DSL Inventory Product contains one or more components not listed on the inventory. Page 6 of 7

7 WHMIS Hazard Class D1B Toxic Materials D2A Very Toxic Materials E Corrosive Material B3 Combustible Liquids 16. OTHER INFORMATION The following sections have been revised since the last issue of this SDS Not applicable Additional Information For additional information on the use of this product, contact your local Halliburton representative. For questions about the Safety Data Sheet for this or other Halliburton products, contact Chemical Compliance at Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user. ***END OF MSDS*** Page 7 of 7