1. IDENTIFICATION. Alcohol/glycol air freshener HAZARDS IDENTIFICATION

Transcription

1 Namco Mfg., Inc Blalock Rd. Houston, TX Safety Data Sheet Issue Date: 04-Mar-2009 Version 1 1. IDENTIFICATION Product Identifier Product Name PH Glycol Air Freshener WITH SPRING GREEN Other means of identification SDS # Product Code #53 #2033A Recommended use of the chemical and restrictions on use Recommended Use Alcohol/glycol air freshener. Details of the supplier of the safety data sheet Supplier Address Wepak Namco Corporation Mfg., Inc. 314 W. Bland St Blalock Rd. Charlotte, NC Houston, TX Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr) HAZARDS IDENTIFICATION Appearance Clear liquid Physical State Liquid Odor Honeysuckle Classification WC A Serious eye damage/eye irritation Category 2 Flammable Liquids Category 4 Signal Word Warning Hazard Statements Causes serious eye irritation Combustible liquid Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Keep away from heat/sparks/open flames/hot surfaces. No smoking Wear protective gloves/protective clothing/eye protection/face protection Page 1 / 7

2 PH WITH SPRING GREEN Precautionary Statements - Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IN CASE OF FIRE: Use CO2, dry chemical, or foam for extinction Precautionary Statements - Storage Store in a well-ventilated place. Keep cool Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% Proprietary 1,2 Propanediol Proprietary Nonylphenoxypoly-(Ethyleneoxy) Ethanol Proprietary **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.** First Aid Measures 4. FIRST-AID MEASURES Eye Contact Skin Contact Inhalation Ingestion Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If eye irritation persists: Get medical advice/attention. Wash off immediately with plenty of water for at least 15 minutes. Get medical attention if necessary. Remove to fresh air. Induce vomiting, but only if victim is fully conscious. Call a physician. Most important symptoms and effects Symptoms Exposed individuals may experience eye tearing, redness, and discomfort. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media. Specific Hazards Arising from the Chemical Combustible material. Page 2 / 7

3 PH WITH SPRING GREEN Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protective equipment as required. Methods and material for containment and cleaning up Methods for Containment Methods for Clean-Up Prevent further leakage or spillage if safe to do so. Contain and collect with an inert absorbent and place into an appropriate container for disposal. Dispose of in accordance with federal, state and local regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Wash thoroughly after handling. Use personal protection recommended in Section 8. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Conditions for safe storage, including any incompatibilities Storage Conditions Incompatible Materials Keep containers tightly closed in a dry, cool and well-ventilated place. None known based on information supplied. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH STEL: 400 ppm TWA: 200 ppm Appropriate engineering controls TWA: 400 ppm TWA: 980 mg/m 3 (vacated) TWA: 400 ppm (vacated) TWA: 980 mg/m 3 (vacated) STEL: 500 ppm (vacated) STEL: 1225 mg/m 3 IDLH: 2000 ppm TWA: 400 ppm TWA: 980 mg/m 3 STEL: 500 ppm STEL: 1225 mg/m 3 Engineering Controls Apply technical measures to comply with the occupational exposure limits. Individual protection measures, such as personal protective equipment Eye/Face Protection Skin and Body Protection Respiratory Protection Wear eye/face protection. Wear suitable gloves. Ensure adequate ventilation, especially in confined areas. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Page 3 / 7

4 PH WITH SPRING GREEN Information on basic physical and chemical properties Physical State Liquid Appearance Clear liquid Odor Honeysuckle Color Clear Odor Threshold Property Values Remarks Method ph 6 Melting Point/Freezing Point Not available Boiling Point/Boiling Range Not available Flash Point 81 C / 178 F Evaporation Rate Not available Flammability (Solid, Gas) n/a-liquid Upper Flammability Limits None Lower Flammability Limit None Vapor Pressure Vapor Density Not available Specific Gravity 0.95 (1=Water) Water Solubility Completely soluble Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to Avoid Keep out of reach of children. Incompatible Materials None known based on information supplied. Hazardous Decomposition Products None known based on information supplied. Information on likely routes of exposure Product Information 10. STABILITY AND REACTIVITY 11. TOXICOLOGICAL INFORMATION Eye Contact Skin Contact Causes serious eye irritation. Avoid contact with skin. Inhalation Avoid breathing vapors or mists. Page 4 / 7

5 PH WITH SPRING GREEN Ingestion Do not taste or swallow. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 = 4396 mg/kg ( Rat ) = mg/kg ( Rat ) = = 72.6 mg/l ( Rat ) 4 h mg/kg ( Rabbit ) 1,2 Propanediol = mg/kg ( Rat ) = mg/kg ( Rabbit ) Nonylphenoxypoly-(Ethyleneoxy) Ethanol = 1800 µl/kg ( Rabbit ) - Information on physical, chemical and toxicological effects Symptoms Please see section 4 of this SDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity Not classifiable as a human carcinogen. Chemical Name ACGIH IARC NTP OSHA Group 3 X Legend IARC (International Agency for Research on Cancer) Group 3 IARC components are "not classifiable as human carcinogens" OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Numerical measures of toxicity 12. ECOLOGICAL INFORMATION Ecotoxicity An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Chemical Name Algae/aquatic plants Fish Toxicity to microorganisms 1,2 Propanediol : 96 h Desmodesmus subspicatus mg/l EC : 72 h Desmodesmus subspicatus mg/l EC : 96 h Pseudokirchneriella subcapitata mg/l EC : 96 h Pimephales promelas mg/l LC50 flow-through 11130: 96 h Pimephales promelas mg/l LC50 static : 96 h Lepomis macrochirus µg/l LC : 96 h Oncorhynchus mykiss mg/l LC50 static 41-47: 96 h Oncorhynchus mykiss ml/l LC50 static 51400: 96 h Pimephales promelas mg/l LC50 static 710: 96 h Pimephales promelas mg/l LC50 Crustacea 13299: 48 h Daphnia magna mg/l EC : 24 h Daphnia magna mg/l EC : 48 h Daphnia magna mg/l EC50 Static Persistence/Degradability. Bioaccumulation. Page 5 / 7

6 PH WITH SPRING GREEN Mobility Chemical Name Partition Coefficient 0.05 Other Adverse Effects 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. Disposal should be in accordance with applicable regional, national and local laws and regulations. US EPA Waste Number Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes Nonylphenoxypoly-(Ethylene oxy) Ethanol Included in waste stream: K060 California Hazardous Waste Status Chemical Name California Hazardous Waste Status Toxic Ignitable 14. TRANSPORT INFORMATION Note DOT IATA IMDG According to 49 CFR (f)(1), this material should be additionally classified as a combustible liquid when shipped in bulk packages (greater than 119 gal.). Not regulated Not regulated Not regulated 15. REGULATORY INFORMATION International Inventories Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances Page 6 / 7

7 PH WITH SPRING GREEN KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances US Federal Regulations SARA 313 Chemical Name CAS No Weight-% SARA Threshold Values % - Proprietary 1.0 US State Regulations U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania X X X 1,2 Propanediol X X 16. OTHER INFORMATION NFPA HMIS Health Hazards Health Hazards 1 Flammability Flammability 1 Instability Physical Hazards 0 Special Hazards Personal Protection Issue Date: Revision Date: Revision Note: 04-Mar Apr-2014 New format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 7 / 7