DuPont Krovar I DF Herbicide

Transcription

1 This SDS adheres to the standards and regulatory requirements of the United States and may not meet the regulatory requirements in other countries. SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Tradename/Synonym : DPX-M2574 B Bromacil: [5-Bromo-3-sec-butyl-6-methyluracil] Diuron: [3-(3,4-Dichlorophenyl)-1,1-dimethylurea] MSDS Number : Product Use : Herbicide Manufacturer : DuPont 1007 Market Street Wilmington, DE Product Information : (outside the U.S ) Medical Emergency : (outside the U.S ) Transport Emergency : CHEMTREC: (outside the U.S ) SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Caution Harmful if swallowed or absorbed through the skin. Causes moderate eye irritation. Avoid contact with skin, eyes and clothing. Potential Health Effects This section includes potential acute adverse effects which could occur if this material is not used according to the label. Skin : May cause: slight irritation, Discomfort. Eyes : May cause: Irritation with discomfort, pain, redness, or visual impairment. Ingestion 1 / 12

2 Diuron : May cause: Abnormal decrease in number of red blood cells (anaemia) which could produce tiredness, rapid heartbeat, dizziness, pale skin, leg cramps, shortness of breath Repeated exposure Diuron : Adverse effects from repeated exposure may include: Bladder damage altered blood chemistry Quartz : DuPont has classified this material as a known human carcinogen. Target Organs Diuron : Blood Urinary system Bladder Carcinogenicity Material IARC NTP OSHA Quartz 1 X SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Component CAS-No. Concentration Bromacil % Diuron % Other Ingredients 20 % Present as an impurity in the clay component of this product: Quartz <1 % 2 / 12

3 SECTION 4. FIRST AID MEASURES Skin contact : Take off all contaminated clothing immediately. Rinse skin immediately with plenty of water for minutes. Call a poison control center or doctor for treatment advice. Eye contact Inhalation Ingestion General advice : Hold eye open and rinse slowly and gently with water for minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. : Move to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth, if possible. Call a poison control center or doctor for treatment advice. : Call a physician or poison control centre immediately. Have person sip a glass of water if able to swallow. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Never give anything by mouth to an unconscious person. : Have the product container or label with you when calling a poison control center or doctor, or going for treatment. For medical emergencies involving this product, call toll free See Label for Additional Precautions and Directions for Use. SECTION 5. FIREFIGHTING MEASURES Flammable Properties Flash point : no data available Ignition temperature Lower explosion limit : 420 C (788 F) : g/l Fire and Explosion Hazard Suitable extinguishing media Unsuitable extinguishing media : Dust may form explosive mixture in air. : Water spray, Foam, Dry chemical, Carbon dioxide (CO2) : High volume water jet, (contamination risk) 3 / 12

4 Firefighting Instructions : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. Prevent fire extinguishing water from contaminating surface water or the ground water system. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. (on small fires) If area is heavily exposed to fire and if conditions permit, let fire burn itself out since water may increase the area contaminated. Cool containers / tanks with water spray. Control Runoff. SECTION 6. ACCIDENTAL RELEASE MEASURES NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with cleanup. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up. Spill Cleanup Accidental Release Measures : Shovel or sweep up. Scoop into bags or boxes with plastic or aluminium shovel. Never return to container for reuse. If spill area is on ground near valuable plants or trees, remove top 2 inches of soil after initial cleanup. : Prevent material from entering sewers, waterways, or low areas. Follow applicable Federal, State/Provincial and Local laws/regulations. SECTION 7. HANDLING AND STORAGE Handling (Personnel) : Wash hands thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, or using the toilet. Remove clothing/ppe immediately if material gets inside. Wash thoroughly and put on clean clothing. Remove personal protective equipment immediately after handling this product. Wash the outside of gloves before removing. As soon as possible, wash thoroughly and change into clean clothing. Storage : Do not contaminate water, other pesticides, fertilizer, food or feed in storage. Store in original container. Store in a cool, dry place. Keep out of the reach of children. 4 / 12

5 SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering controls Personal protective equipment Skin and body protection Protective measures : Ensure adequate ventilation. When handlers use closed systems, enclosed cabs, or aircraft in a manner that meets the requirements listed in the Worker Protection Standard (WPS) for agricultural pesticides [40 CFR (d)(4-6)], the handler PPE requirements may be reduced or modified as specified in the WPS. Refer to the product label for additional Engineering Controls. : Pilots, flaggers and groundboom applicators must wear: Long sleeved shirt and long pants Shoes plus socks Groundboom applicators must wear: Chemical resistant gloves made of any waterproof material Mixers, loaders, applicators and other handlers must wear: Long sleeved shirt and long pants Shoes plus socks Chemical resistant gloves made of any waterproof material Polyvinylchloride A NIOSH approved dust/mist filtering respirator with any N, R, P, or HE filter or with approval number prefix TC-21C. Chemical resistant apron when mixing, loading, or cleaning equipment or spills. : Follow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions for washables exist, use detergent and hot water. Keep and wash PPE separately from other laundry. Exposure Guidelines Exposure Limit Values Bromacil PEL: (OSHA) 1 ppm 10 mg/m3 8 hr. TWA TLV (ACGIH) 10 mg/m3 TWA AEL * (DUPONT) 10 mg/m3 8 & 12 hr. TWA Diuron TLV (ACGIH) 10 mg/m3 TWA 5 / 12

6 AEL * (DUPONT) 1 mg/m3 8 & 12 hr. TWA Total dust. Quartz PEL: (OSHA) 2.4 millions of particles per cubic foot of air TWA Respirable. Remarks The exposure limit is calculated from the equation, 250/(%SiO2+5), using a value of 100% SiO2. Lower percentages of SiO2 will yield higher exposure limits. PEL: (OSHA) 0.1 mg/m3 TWA Respirable. Remarks The exposure limit is calculated from the equation, 10/(%SiO2+2), using a value of 100% SiO2. Lower percentages of SiO2 will yield higher exposure limits. PEL: (OSHA) 0.3 mg/m3 TWA Total dust. Remarks The exposure limit is calculated from the equation, 30/(%SiO2+2), using a value of 100% SiO2. Lower values of % SiO2 will give higher exposure limits. TLV (ACGIH) mg/m3 TWA Respirable fraction. AEL * (DUPONT) 0.02 mg/m3 8 hr. TWA Respirable dust. AEL * (DUPONT) 0.01 mg/m3 12 hr. TWA Respirable dust. * AEL is DuPont's Acceptable Exposure Limit. Where governmentally imposed occupational exposure limits which are lower than the AEL are in effect, such limits shall take precedence. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Form : solid, granules Color : brown Odor : none Bulk density : g/ml 6 / 12

7 Water solubility : dispersible SECTION 10. STABILITY AND REACTIVITY Stability : Stable at normal temperatures and storage conditions. Incompatibility Hazardous reactions : None reasonably foreseeable. : Hazardous polymerisation does not occur. SECTION 11. TOXICOLOGICAL INFORMATION Inhalation 4 h LC50 : > 5.2 mg/l, rat Dermal LD50 : > 2,000 mg/kg, rabbit Oral LD50 : 2,300 mg/kg, rat Skin irritation : slight irritation, rabbit Eye irritation : slight irritation, rabbit Sensitisation : Animal test did not cause sensitization by skin contact., guinea pig Bromacil Repeated dose toxicity : The following effects occurred at levels of exposure that significantly exceed those expected under labeled usage conditions. Oral rat Liver effects, Organ weight changes, Thyroid effects, Reduced body weight gain Inhalation rat 7 / 12

8 Increased liver weight, altered blood chemistry Carcinogenicity : The following effects occurred at levels of exposure that significantly exceed those expected under labeled usage conditions. An increased incidence of tumours was observed in laboratory animals. Mutagenicity : Did not cause genetic damage in cultured bacterial cells. Genetic damage in cultured mammalian cells was observed in some laboratory tests but not in others. Did not cause genetic damage in animals. Reproductive toxicity : Animal testing showed no reproductive toxicity. Teratogenicity : Animal testing showed effects on embryo-fetal development at levels equal to or above those causing maternal toxicity. Diuron Repeated dose toxicity : The following effects occurred at levels of exposure that significantly exceed those expected under labeled usage conditions. Oral rat Red blood cell destruction causing abnormal decrease in number of red blood cells (anaemia), Spleen effects, bone marrow changes, Kidney effects, Bladder effects, Reduced body weight gain Oral dog Red blood cell destruction causing abnormal decrease in number of red blood cells (anaemia), Spleen effects, bone marrow changes, Reduced body weight gain Inhalation rat Red blood cell destruction causing abnormal decrease in number of red blood cells (anaemia), Spleen effects 8 / 12

9 Carcinogenicity : The following effects occurred at levels of exposure that significantly exceed those expected under labeled usage conditions. An increased incidence of tumours was observed in laboratory animals. Mutagenicity : Overall weight of evidence indicates that the substance is not mutagenic. Reproductive toxicity : Animal testing did not show any effects on fertility. Teratogenicity : Animal testing showed effects on embryo-fetal development at levels equal to or above those causing maternal toxicity. Quartz Repeated dose toxicity : Inhalation Fluid retention in lungs (pulmonary oedema), lung effects, Inflammation, Chronic lung disease, Fibrosis SECTION 12. ECOLOGICAL INFORMATION Aquatic Toxicity Bromacil 96 h LC50 : Lepomis macrochirus (Bluegill sunfish) 127 mg/l 96 h LC50 : Oncorhynchus mykiss (rainbow trout) 36 mg/l 72 h ErC50 : Pseudokirchneriella subcapitata (green algae) mg/l NOEC : Algae mg/l 48 h EC50 : Daphnia magna (Water flea) 119 mg/l Diuron 96 h LC50 : Oncorhynchus mykiss (rainbow trout) 17.4 mg/l 72 h EC50 : Algae mg/l 9 / 12

10 72 h NOEC : Algae 0.01 mg/l 48 h EC50 : Daphnia magna (Water flea) 1.4 mg/l Additional ecological information : Environmental Hazards: Do not apply directly to water, or to areas where surface water is present, or to intertidal areas below the mean high water mark. Do not contaminate water when cleaning equipment or disposing of equipment washwaters or rinsate. See product label for additional application instructions relating to environmental precautions. SECTION 13. DISPOSAL CONSIDERATIONS Waste Disposal : Do not contaminate water, food or feed by disposal. Wastes resulting from the use of this product must be disposed of on site or at an approved waste disposal facility. Container Disposal : Refer to the product label for instructions. In the event of a major spill, fire or other emergency, call day or night. SECTION 14. TRANSPORT INFORMATION IATA_C UN number : 3077 Proper shipping name : Environmentally hazardous substance, solid, n.o.s. (Diuron, Bromacil) Class : 9 Packing group : III Labelling No. : 9MI IMDG UN number : 3077 Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Diuron, Bromacil) Class : 9 Packing group : III Labelling No. : 9 10 / 12

11 Marine pollutant : yes (Diuron, Bromacil) Not regulated by DOT in single packages containing less than 100 pounds Diuron. SECTION 15. REGULATORY INFORMATION SARA 313 Regulated Chemical(s) Title III hazard classification CERCLA Reportable Quantity : Bromacil, Diuron : Acute Health Hazard: Yes Chronic Health Hazard: Yes Fire: No Reactivity/Physical hazard: No Pressure: No : 250 lbs Based on the percentage composition of this chemical in the product.: Diuron EPA Reg. No. : In the United States this product is regulated by the US Environmental Protection Agency (EPA) under the Federal Insecticide, Fungicide and Rodenticide Act (FIFRA). It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Read and follow all label directions. This product is excluded from listing requirements under EPA/TSCA. California Prop. 65 PA Right to Know Regulated Chemical(s) : WARNING! This product contains a chemical known to the State of California to cause cancer.diuron, Quartz, Titanium dioxide : Substances on the Pennsylvania Hazardous Substances List present at a concentration of 1% or more (0.01% for Special Hazardous Substances): Bromacil, Diuron, Kaolin, Sodium sulphate, Silica gel, precipitated, crystalline-free SECTION 16. OTHER INFORMATION 11 / 12

12 NFPA HMIS Health : 1 1 Flammability : 1 1 Reactivity/Physical hazard : 0 0 Trademark of E.I. du Pont de Nemours and Company. DuPont's registered trademark Contact person : DuPont Crop Protection, Wilmington, DE, 19898, Phone: The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Significant change from previous version is denoted with a double bar. 12 / 12