SAFETY DATA SHEET. Copper phthalocyanine direct dye salt < 2.5

Transcription

1 SAFETY DATA SHEET 1. Identification Product identifier N9K01Series[C][3] Other means of identification Recommended use Recommended restrictions Company identification 2. Hazard(s) identification Physical hazards Health hazards Environmental hazards OSHA defined hazards Inkjet printing None known. HP 1501 Page Mill Road Palo Alto, CA United States Telephone HP health effects line (Toll-free within the US) (Direct) HP Customer Care Line (Toll-free within the US) (Direct) Label elements Hazard symbol Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) None. None. Potential routes of overexposure to this product are skin and eye contact. Inhalation of vapor and ingestion are not expected to be significant routes of exposure for this product under normal use conditions. Complete toxicity data are not available for this specific formulation. Supplemental information This product is not classified as hazardous according to OSHA CFR (HazCom 2012). 3. Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number % Water Copper phthalocyanine direct dye salt Proprietary magnesium nitrate hexahydrate < 2.5 < 5 Composition comments Material name: N9K01Series[C][3] Version #: 18 Revision date: Issue date: This ink supply contains an aqueous ink formulation. This product has been evaluated using criteria specified in 29 CFR (Hazard Communication Standard). 1 / 6

2 4. First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Remove to fresh air. If symptoms persist, get medical attention. Wash affected areas thoroughly with mild soap and water. Get medical attention if irritation develops or persists. Do not rub eyes. Immediately flush with large amounts of clean, warm water (low pressure) for at least 15 minutes or until particles are removed. If irritation persists get medical attention. If ingestion of a large amount does occur, seek medical attention. 5. Fire-fighting measures Suitable extinguishing media Dry chemical, CO2, water spray or regular foam. Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Specific methods None known. Not applicable. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Environmental precautions 7. Handling and storage None established. Wear appropriate personal protective equipment. Dike the spilled material, where this is possible. Absorb with inert absorbent such as dry clay, sand or diatomaceous earth, commercial sorbents, or recover using pumps. Do not let product enter drains. Do not flush into surface water or sanitary sewer system. Precautions for safe handling Avoid contact with skin, eyes and clothing. Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Keep out of the reach of children. Keep away from excessive heat or cold. Occupational exposure limits No exposure limits noted for ingredient(s). Biological limit values Exposure guidelines Appropriate engineering controls No biological exposure limits noted for the ingredient(s). Exposure limits have not been established for this product. Use in a well ventilated area. Individual protection measures, such as personal protective equipment Eye/face protection Skin protection Hand protection Other Respiratory protection Thermal hazards General hygiene considerations 9. Physical and chemical properties Appearance Physical state Color Handle in accordance with good industrial hygiene and safety practice. Liquid. Cyan Material name: N9K01Series[C][3] Version #: 18 Revision date: Issue date: 2 / 6

3 Odor Odor threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) > F (> 93.3 C) Pensky-Martens Closed Cup Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Solubility(ies) Solubility (water) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Soluble in water <= 2 cp Other information For other VOC regulatory data/information see Section 15. VOC (Weight %) 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products 11. Toxicological information Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization < 156 g/l Stable under recommended storage conditions. Will not occur. Incompatible with strong bases and oxidizing agents. Upon decomposition, this product may yield gaseous nitrogen oxides, carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity Material name: N9K01Series[C][3] Version #: 18 Revision date: Issue date: 3 / 6

4 Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Further information Complete toxicity data are not available for this specific formulation Refer to Section 2 for potential health effects and Section 4 for first aid measures. 12. Ecological information Aquatic toxicity Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects 13. Disposal considerations Disposal instructions 14. Transport information DOT IATA IMDG ADR Further information 15. Regulatory information US federal regulations This product has not been tested for ecological effects. Do not dispose of together with general office waste. Do not allow this material to drain into sewers/water supplies. Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations. HP's Planet Partners (trademark) supplies recycling program enables simple, convenient recycling of HP original inkjet and LaserJet supplies. For more information and to determine if this service is available in your location, please visit Not a dangerous good under DOT, IATA, ADR, IMDG, or RID. US TSCA 12(b): Does not contain listed chemicals. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) CERCLA Hazardous Substance List (40 CFR 302.4) SARA 304 Emergency release notification OSHA Specifically Regulated Substances (29 CFR ) Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Material name: N9K01Series[C][3] Version #: 18 Revision date: Issue date: 4 / 6

5 SARA 311/312 Hazardous chemical Other federal regulations Safe Drinking Water Act (SDWA) US state regulations No US. Massachusetts RTK - Substance List US. New Jersey Worker and Community Right-to-Know Act US. Pennsylvania Worker and Community Right-to-Know Law US. Rhode Island RTK US. California Proposition 65 Not Listed. Other information VOC content (less water, less exempt compounds) = < 574 g/l (U.S. requirement, not for emissions) VOC data based on formulation (Organic compounds minus solids) Regulatory information All chemical substances in this HP product have been notified or are exempt from notification under chemical substances notification laws in the following countries: US (TSCA), EU (EINECS/ELINCS), Switzerland, Canada (DSL/NDSL), Australia, Japan, Philippines, South Korea, New Zealand, and China. 16. Other information, including date of preparation or last revision Issue date Revision date Version # 18 Disclaimer Manufacturer information This Safety Data Sheet document is provided without charge to customers of HP. Data is the most current known to HP at the time of preparation of this document and is believed to be accurate. It should not be construed as guaranteeing specific properties of the products as described or suitability for a particular application. This document was prepared to the requirements of the jurisdiction specified in Section 1 above and may not meet regulatory requirements in other countries. HP 1501 Page Mill Road Palo Alto, CA US Direct Material name: N9K01Series[C][3] Version #: 18 Revision date: Issue date: 5 / 6

6 Explanation of abbreviations ACGIH CAS CERCLA CFR COC DOT EPCRA IARC NIOSH NTP OSHA PEL RCRA REC REL SARA STEL TCLP TLV TSCA VOC American Conference of Governmental Industrial Hygienists Chemical Abstracts Service Comprehensive Environmental Response Compensation and Liability Act Code of Federal Regulations Cleveland Open Cup Department of Transportation Emergency Planning and Community Right-to-Know Act (aka SARA) International Agency for Research on Cancer National Institute for Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Resource Conservation and Recovery Act Recommended Recommended Exposure Limit Superfund Amendments and Reauthorization Act of 1986 Short-Term Exposure Limit Toxicity Characteristics Leaching Procedure Threshold Limit Value Toxic Substances Control Act Volatile Organic Compounds Material name: N9K01Series[C][3] Version #: 18 Revision date: Issue date: 6 / 6

7 SAFETY DATA SHEET 1. Identification Product identifier N9K01Series[M][3] Other means of identification Recommended use Recommended restrictions Company identification 2. Hazard(s) identification Physical hazards Health hazards Environmental hazards OSHA defined hazards Inkjet printing None known. HP 1501 Page Mill Road Palo Alto, CA United States Telephone HP health effects line (Toll-free within the US) (Direct) HP Customer Care Line (Toll-free within the US) (Direct) Label elements Hazard symbol Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) None. None. Potential routes of overexposure to this product are skin and eye contact. Inhalation of vapor and ingestion are not expected to be significant routes of exposure for this product under normal use conditions. Complete toxicity data are not available for this specific formulation. Supplemental information This product is not classified as hazardous according to OSHA CFR (HazCom 2012). 3. Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number % Water pyrrolidone < 7.5 Polycyclic sulfonic acid, TMA salt Proprietary < 7.5 magnesium nitrate hexahydrate < 2.5 Material name: N9K01Series[M][3] Version #: 18 Revision date: Issue date: 1 / 6

8 Composition comments 4. First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed This ink supply contains an aqueous ink formulation. This product has been evaluated using criteria specified in 29 CFR (Hazard Communication Standard). Remove to fresh air. If symptoms persist, get medical attention. Wash affected areas thoroughly with mild soap and water. Get medical attention if irritation develops or persists. Do not rub eyes. Immediately flush with large amounts of clean, warm water (low pressure) for at least 15 minutes or until particles are removed. If irritation persists get medical attention. If ingestion of a large amount does occur, seek medical attention. 5. Fire-fighting measures Suitable extinguishing media Dry chemical, CO2, water spray or regular foam. Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Specific methods None known. Not applicable. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Environmental precautions 7. Handling and storage None established. Wear appropriate personal protective equipment. Dike the spilled material, where this is possible. Absorb with inert absorbent such as dry clay, sand or diatomaceous earth, commercial sorbents, or recover using pumps. Do not let product enter drains. Do not flush into surface water or sanitary sewer system. Precautions for safe handling Avoid contact with skin, eyes and clothing. Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Keep out of the reach of children. Keep away from excessive heat or cold. Occupational exposure limits No exposure limits noted for ingredient(s). Biological limit values Exposure guidelines Appropriate engineering controls No biological exposure limits noted for the ingredient(s). Exposure limits have not been established for this product. Use in a well ventilated area. Individual protection measures, such as personal protective equipment Eye/face protection Skin protection Hand protection Other Respiratory protection Thermal hazards General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. 9. Physical and chemical properties Appearance Material name: N9K01Series[M][3] Version #: 18 Revision date: Issue date: 2 / 6

9 Odor Physical state Color Odor threshold Liquid. Magenta ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) > F (> 93.3 C) Pensky-Martens Closed Cup Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Solubility(ies) Solubility (water) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Soluble in water <= 2 cp Other information For other VOC regulatory data/information see Section 15. VOC (Weight %) 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products 11. Toxicological information Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization < 156 g/l Stable under recommended storage conditions. Will not occur. Incompatible with strong bases and oxidizing agents. Upon decomposition, this product may yield gaseous nitrogen oxides, carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. Respiratory sensitization Skin sensitization Material name: N9K01Series[M][3] Version #: 18 Revision date: Issue date: 3 / 6

10 Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Further information Components 2-pyrrolidone (CAS ) Acute Oral LD50 Complete toxicity data are not available for this specific formulation Refer to Section 2 for potential health effects and Section 4 for first aid measures. Species Guinea pig Rat Test Results 6500 mg/kg 6500 mg/kg 12. Ecological information Aquatic toxicity This product has not been tested for ecological effects. Ecotoxicity Components Species 2-pyrrolidone (CAS ) Aquatic Crustacea EC50 Water flea (Daphnia pulex) Test Results mg/l, 48 hours Persistence and degradability Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) 2-pyrrolidone Mobility in soil Other adverse effects 13. Disposal considerations Disposal instructions 14. Transport information DOT IATA IMDG ADR Further information 15. Regulatory information US federal regulations Do not dispose of together with general office waste. Do not allow this material to drain into sewers/water supplies. Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations. HP's Planet Partners (trademark) supplies recycling program enables simple, convenient recycling of HP original inkjet and LaserJet supplies. For more information and to determine if this service is available in your location, please visit Not a dangerous good under DOT, IATA, ADR, IMDG, or RID. US TSCA 12(b): Does not contain listed chemicals. Material name: N9K01Series[M][3] Version #: 18 Revision date: Issue date: 4 / 6

11 TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) CERCLA Hazardous Substance List (40 CFR 302.4) SARA 304 Emergency release notification OSHA Specifically Regulated Substances (29 CFR ) Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance SARA 311/312 Hazardous chemical Other federal regulations Safe Drinking Water Act (SDWA) US state regulations No US. Massachusetts RTK - Substance List 2-pyrrolidone (CAS ) US. New Jersey Worker and Community Right-to-Know Act US. Pennsylvania Worker and Community Right-to-Know Law 2-pyrrolidone (CAS ) US. Rhode Island RTK US. California Proposition 65 Not Listed. Other information VOC content (less water, less exempt compounds) = < 533 g/l (U.S. requirement, not for emissions) VOC data based on formulation (Organic compounds minus solids) Regulatory information All chemical substances in this HP product have been notified or are exempt from notification under chemical substances notification laws in the following countries: US (TSCA), EU (EINECS/ELINCS), Switzerland, Canada (DSL/NDSL), Australia, Japan, Philippines, South Korea, New Zealand, and China. 16. Other information, including date of preparation or last revision Issue date Revision date Version # 18 Disclaimer Manufacturer information This Safety Data Sheet document is provided without charge to customers of HP. Data is the most current known to HP at the time of preparation of this document and is believed to be accurate. It should not be construed as guaranteeing specific properties of the products as described or suitability for a particular application. This document was prepared to the requirements of the jurisdiction specified in Section 1 above and may not meet regulatory requirements in other countries. HP 1501 Page Mill Road Palo Alto, CA US Direct Material name: N9K01Series[M][3] Version #: 18 Revision date: Issue date: 5 / 6

12 Explanation of abbreviations ACGIH CAS CERCLA CFR COC DOT EPCRA IARC NIOSH NTP OSHA PEL RCRA REC REL SARA STEL TCLP TLV TSCA VOC American Conference of Governmental Industrial Hygienists Chemical Abstracts Service Comprehensive Environmental Response Compensation and Liability Act Code of Federal Regulations Cleveland Open Cup Department of Transportation Emergency Planning and Community Right-to-Know Act (aka SARA) International Agency for Research on Cancer National Institute for Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Resource Conservation and Recovery Act Recommended Recommended Exposure Limit Superfund Amendments and Reauthorization Act of 1986 Short-Term Exposure Limit Toxicity Characteristics Leaching Procedure Threshold Limit Value Toxic Substances Control Act Volatile Organic Compounds Material name: N9K01Series[M][3] Version #: 18 Revision date: Issue date: 6 / 6

13 SAFETY DATA SHEET 1. Identification Product identifier N9K01Series[Y][3] Other means of identification Recommended use Recommended restrictions Company identification 2. Hazard(s) identification Physical hazards Health hazards Environmental hazards OSHA defined hazards Inkjet printing None known. HP 1501 Page Mill Road Palo Alto, CA United States Telephone HP health effects line (Toll-free within the US) (Direct) HP Customer Care Line (Toll-free within the US) (Direct) Label elements Hazard symbol Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) None. None. Potential routes of overexposure to this product are skin and eye contact. Inhalation of vapor and ingestion are not expected to be significant routes of exposure for this product under normal use conditions. Complete toxicity data are not available for this specific formulation. Supplemental information This product is not classified as hazardous according to OSHA CFR (HazCom 2012). 3. Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number % Water pyrrolidone < 7.5 Yellow colorant Proprietary < 7.5 magnesium nitrate hexahydrate < 2.5 Material name: N9K01Series[Y][3] Version #: 18 Revision date: Issue date: 1 / 6

14 Composition comments 4. First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed This ink supply contains an aqueous ink formulation. This product has been evaluated using criteria specified in 29 CFR (Hazard Communication Standard). Remove to fresh air. If symptoms persist, get medical attention. Wash affected areas thoroughly with mild soap and water. Get medical attention if irritation develops or persists. Do not rub eyes. Immediately flush with large amounts of clean, warm water (low pressure) for at least 15 minutes or until particles are removed. If irritation persists get medical attention. If ingestion of a large amount does occur, seek medical attention. 5. Fire-fighting measures Suitable extinguishing media Dry chemical, CO2, water spray or regular foam. Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Specific methods None known. Not applicable. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Environmental precautions 7. Handling and storage None established. Wear appropriate personal protective equipment. Dike the spilled material, where this is possible. Absorb with inert absorbent such as dry clay, sand or diatomaceous earth, commercial sorbents, or recover using pumps. Do not let product enter drains. Do not flush into surface water or sanitary sewer system. Precautions for safe handling Avoid contact with skin, eyes and clothing. Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Keep out of the reach of children. Keep away from excessive heat or cold. Occupational exposure limits No exposure limits noted for ingredient(s). Biological limit values Exposure guidelines Appropriate engineering controls No biological exposure limits noted for the ingredient(s). Exposure limits have not been established for this product. Use in a well ventilated area. Individual protection measures, such as personal protective equipment Eye/face protection Skin protection Hand protection Other Respiratory protection Thermal hazards General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. 9. Physical and chemical properties Appearance Material name: N9K01Series[Y][3] Version #: 18 Revision date: Issue date: 2 / 6

15 Odor Physical state Color Odor threshold Liquid. Yellow ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) > F (> 93.3 C) Pensky-Martens Closed Cup Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Solubility(ies) Solubility (water) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Soluble in water <= 2 cp Other information For other VOC regulatory data/information see Section 15. VOC (Weight %) 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products 11. Toxicological information Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization < 155 g/l Stable under recommended storage conditions. Will not occur. Incompatible with strong bases and oxidizing agents. Upon decomposition, this product may yield gaseous nitrogen oxides, carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. Respiratory sensitization Skin sensitization Material name: N9K01Series[Y][3] Version #: 18 Revision date: Issue date: 3 / 6

16 Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Further information Components 2-pyrrolidone (CAS ) Acute Oral LD50 Complete toxicity data are not available for this specific formulation Refer to Section 2 for potential health effects and Section 4 for first aid measures. Species Guinea pig Rat Test Results 6500 mg/kg 6500 mg/kg 12. Ecological information Aquatic toxicity This product has not been tested for ecological effects. Ecotoxicity Components Species 2-pyrrolidone (CAS ) Aquatic Crustacea EC50 Water flea (Daphnia pulex) Test Results mg/l, 48 hours Persistence and degradability Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) 2-pyrrolidone Mobility in soil Other adverse effects 13. Disposal considerations Disposal instructions 14. Transport information DOT IATA IMDG ADR Further information 15. Regulatory information US federal regulations Do not dispose of together with general office waste. Do not allow this material to drain into sewers/water supplies. Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations. HP's Planet Partners (trademark) supplies recycling program enables simple, convenient recycling of HP original inkjet and LaserJet supplies. For more information and to determine if this service is available in your location, please visit Not a dangerous good under DOT, IATA, ADR, IMDG, or RID. US TSCA 12(b): Does not contain listed chemicals. Material name: N9K01Series[Y][3] Version #: 18 Revision date: Issue date: 4 / 6

17 TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) CERCLA Hazardous Substance List (40 CFR 302.4) SARA 304 Emergency release notification OSHA Specifically Regulated Substances (29 CFR ) Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance SARA 311/312 Hazardous chemical Other federal regulations Safe Drinking Water Act (SDWA) US state regulations No US. Massachusetts RTK - Substance List 2-pyrrolidone (CAS ) US. New Jersey Worker and Community Right-to-Know Act US. Pennsylvania Worker and Community Right-to-Know Law 2-pyrrolidone (CAS ) US. Rhode Island RTK US. California Proposition 65 Not Listed. Other information Regulatory information VOC content (less water, less exempt compounds) = < 527 g/l (U.S. requirement, not for emissions) VOC data based on formulation (Organic compounds minus solids) All chemical substances in this HP product have been notified or are exempt from notification under chemical substances notification laws in the following countries: US (TSCA), EU (EINECS/ELINCS), Switzerland, Canada (DSL/NDSL), Australia, Japan, Philippines, South Korea, New Zealand, and China. 16. Other information, including date of preparation or last revision Issue date Revision date Version # 18 Disclaimer Manufacturer information This Safety Data Sheet document is provided without charge to customers of HP. Data is the most current known to HP at the time of preparation of this document and is believed to be accurate. It should not be construed as guaranteeing specific properties of the products as described or suitability for a particular application. This document was prepared to the requirements of the jurisdiction specified in Section 1 above and may not meet regulatory requirements in other countries. HP 1501 Page Mill Road Palo Alto, CA US Direct Material name: N9K01Series[Y][3] Version #: 18 Revision date: Issue date: 5 / 6

18 Explanation of abbreviations ACGIH CAS CERCLA CFR COC DOT EPCRA IARC NIOSH NTP OSHA PEL RCRA REC REL SARA STEL TCLP TLV TSCA VOC American Conference of Governmental Industrial Hygienists Chemical Abstracts Service Comprehensive Environmental Response Compensation and Liability Act Code of Federal Regulations Cleveland Open Cup Department of Transportation Emergency Planning and Community Right-to-Know Act (aka SARA) International Agency for Research on Cancer National Institute for Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Resource Conservation and Recovery Act Recommended Recommended Exposure Limit Superfund Amendments and Reauthorization Act of 1986 Short-Term Exposure Limit Toxicity Characteristics Leaching Procedure Threshold Limit Value Toxic Substances Control Act Volatile Organic Compounds Material name: N9K01Series[Y][3] Version #: 18 Revision date: Issue date: 6 / 6

19 SAFETY DATA SHEET 1. Identification Product identifier N9K02Series Other means of identification Recommended use Recommended restrictions Company identification 2. Hazard(s) identification Physical hazards Health hazards Environmental hazards OSHA defined hazards Label elements Hazard symbol Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Inkjet printing None known. HP 1501 Page Mill Road Palo Alto, CA United States Telephone HP health effects line (Toll-free within the US) (Direct) HP Customer Care Line (Toll-free within the US) (Direct) None. None. Carbon black is classified by the IARC as a Group 2B carcinogen (the substance is possibly carcinogenic to humans). Carbon black in this preparation, due to its bound form, does not present this carcinogenic risk. Potential routes of overexposure to this product are skin and eye contact. Inhalation of vapor and ingestion are not expected to be significant routes of exposure for this product under normal use conditions. Complete toxicity data are not available for this specific formulation. None of the other ingredients in this preparation are classified as carcinogens according to ACGIH, EU, IARC, MAK, NTP or OSHA. Supplemental information This product is not classified as hazardous according to OSHA CFR (HazCom 2012). 3. Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number % Water pyrrolidone < 10 1,5-pentanediol < 5 Modified carbon black Proprietary < 5 Material name: N9K02Series Version #: 12 Revision date:. Issue date: 1 / 6

20 Composition comments This ink supply contains an aqueous ink formulation. This product has been evaluated using criteria specified in 29 CFR (Hazard Communication Standard). Carbon black is present only in a bound form in this preparation. 4. First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Remove to fresh air. If symptoms persist, get medical attention. Wash affected areas thoroughly with mild soap and water. Get medical attention if irritation develops or persists. Do not rub eyes. Immediately flush with large amounts of clean, warm water (low pressure) for at least 15 minutes or until particles are removed. If irritation persists get medical attention. If ingestion of a large amount does occur, seek medical attention. 5. Fire-fighting measures Suitable extinguishing media Dry chemical, CO2, water spray or regular foam. Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Specific methods None known. Not applicable. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Environmental precautions 7. Handling and storage None established. Wear appropriate personal protective equipment. Dike the spilled material, where this is possible. Absorb with inert absorbent such as dry clay, sand or diatomaceous earth, commercial sorbents, or recover using pumps. Do not let product enter drains. Do not flush into surface water or sanitary sewer system. Precautions for safe handling Avoid contact with skin, eyes and clothing. Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Keep out of the reach of children. Keep away from excessive heat or cold. Occupational exposure limits No exposure limits noted for ingredient(s). Biological limit values Exposure guidelines Appropriate engineering controls No biological exposure limits noted for the ingredient(s). Exposure limits have not been established for this product. Use in a well ventilated area. Individual protection measures, such as personal protective equipment Eye/face protection Skin protection Hand protection Other Respiratory protection Thermal hazards General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. Material name: N9K02Series Version #: 12 Revision date: Issue date:. 2 / 6

21 9. Physical and chemical properties Appearance Odor Physical state Color Odor threshold Black. ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) > F (> C) Setaflash Closed Cup Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Solubility(ies) Solubility (water) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Soluble in water >= 2 cp Other information For other VOC regulatory data/information see Section 15. VOC (Weight %) 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products < 147 g/l 11. Toxicological information Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Stable under recommended storage conditions. Will not occur. Incompatible with strong bases and oxidizing agents. Upon decomposition, this product may yield gaseous nitrogen oxides, carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. Material name: N9K02Series Version #: 12 Revision date: Issue date: 3 / 6

22 Respiratory or skin sensitization Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Further information Components 2-pyrrolidone (CAS ) Acute Oral LD50 Carbon black is classified as a carcinogen by the IARC (possibly carcinogenic to humans, Group 2B) and by the State of California under Proposition 65. In their evaluations of carbon black, both organizations indicate that exposure to carbon black, per se, does not occur when it remains bound within a product matrix, specifically, rubber, ink, or paint. Carbon black is present only in a bound form in this preparation. Complete toxicity data are not available for this specific formulation Refer to Section 2 for potential health effects and Section 4 for first aid measures. Species Guinea pig Rat Test Results 6500 mg/kg 6500 mg/kg 12. Ecological information Aquatic toxicity Not expected to be harmful to aquatic organisms. Ecotoxicity Product Species N9K02Series (CAS Mixture) Aquatic Acute Fish LC50 Fathead minnow (Pimephales promelas) Components Species 2-pyrrolidone (CAS ) Aquatic Crustacea EC50 Water flea (Daphnia pulex) Test Results > 750 mg/l, 96 hours Test Results mg/l, 48 hours Persistence and degradability Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) 2-pyrrolidone Mobility in soil Other adverse effects 13. Disposal considerations Disposal instructions Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations. Do not allow this material to drain into sewers/water supplies. HP's Planet Partners (trademark) supplies recycling program enables simple, convenient recycling of HP original inkjet and LaserJet supplies. For more information and to determine if this service is available in your location, please visit Material name: N9K02Series Version #: 12 Revision date: Issue date: 4 / 6

23 14. Transport information DOT IATA IMDG ADR Further information 15. Regulatory information US federal regulations Not a dangerous good under DOT, IATA, ADR, IMDG, or RID. US TSCA 12(b): Does not contain listed chemicals. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) CERCLA Hazardous Substance List (40 CFR 302.4) SARA 304 Emergency release notification OSHA Specifically Regulated Substances (29 CFR ) Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance SARA 311/312 Hazardous chemical Other federal regulations Safe Drinking Water Act (SDWA) US state regulations No US. Massachusetts RTK - Substance List 2-pyrrolidone (CAS ) US. New Jersey Worker and Community Right-to-Know Act US. Pennsylvania Worker and Community Right-to-Know Law 2-pyrrolidone (CAS ) US. Rhode Island RTK US. California Proposition 65 Not Listed. Other information Regulatory information VOC content (less water, less exempt compounds) = <709 g/l (U.S. requirement, not for emissions ) VOC data based on formulation (Organic compounds minus solids) All chemical substances in this HP product have been notified or are exempt from notification under chemical substances notification laws in the following countries: US (TSCA), EU (EINECS/ELINCS), Switzerland, Canada (DSL/NDSL), Australia, Japan, Philippines, South Korea, New Zealand, and China. 16. Other information, including date of preparation or last revision Issue date Revision date Material name: N9K02Series Version #: 12 Revision date: Issue date: 5 / 6

24 Version # 12 Disclaimer Manufacturer information Explanation of abbreviations This Safety Data Sheet document is provided without charge to customers of HP. Data is the most current known to HP at the time of preparation of this document and is believed to be accurate. It should not be construed as guaranteeing specific properties of the products as described or suitability for a particular application. This document was prepared to the requirements of the jurisdiction specified in Section 1 above and may not meet regulatory requirements in other countries. HP 1501 Page Mill Road Palo Alto, CA US Direct ACGIH CAS CERCLA CFR COC DOT EPCRA IARC NIOSH NTP OSHA PEL RCRA REC REL SARA STEL TCLP TLV TSCA VOC American Conference of Governmental Industrial Hygienists Chemical Abstracts Service Comprehensive Environmental Response Compensation and Liability Act Code of Federal Regulations Cleveland Open Cup Department of Transportation Emergency Planning and Community Right-to-Know Act (aka SARA) International Agency for Research on Cancer National Institute for Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Resource Conservation and Recovery Act Recommended Recommended Exposure Limit Superfund Amendments and Reauthorization Act of 1986 Short-Term Exposure Limit Toxicity Characteristics Leaching Procedure Threshold Limit Value Toxic Substances Control Act Volatile Organic Compounds Material name: N9K02Series Version #: 12 Revision date: Issue date: 6 / 6