SAFETY DATA SHEET. Klercide Active Chlorine Unit Dose concentrate

Transcription

1 Section: 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Other means of identification : Not applicable. Recommended use : Surface Disinfectant Restrictions on use : Reserved for industrial and professional use. Product dilution information : No dilution information provided. Company : ECOLAB PTY LTD 2 Drake Avenue Macquarie Park, NSW Australia Emergency telephone number : , Issuing date : Section: 2. HAZARDS IDENTIFICATION GHS Classification Acute toxicity (Oral) : Category 4 Serious eye damage/eye : Category 2A irritation GHS Label element Hazard pictograms : Signal Word Hazard Statements Precautionary Statements Other hazards : Warning : Harmful if swallowed. Causes serious eye irritation. : Prevention: Wash skin thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves/ eye protection/ face protection. Response: IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell. Rinse mouth. If eye irritation persists: Get medical advice/ attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Disposal: Dispose of contents/ container to an approved waste disposal plant. : Mixing this product with acid or ammonia releases chlorine gas. Do not mix with bleach or other chlorinated products will cause chlorine gas. Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS / 8

2 Pure substance/mixture : Mixture Chemical Name CAS-No. Concentration: (%) troclosene sodium adipic acid Section: 4. FIRST AID MEASURES In case of eye contact In case of skin contact If swallowed : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention. : Rinse with plenty of water. : Contact the Poison's Information Centre (eg Australia ; New Zealand ). Rinse mouth. Get medical attention if symptoms occur. If inhaled Protection of first-aiders Notes to physician Most important symptoms and effects, both acute and delayed : Remove to fresh air. Treat symptomatically. Get medical attention immediately. : If potential for exposure exists refer to Section 8 for specific personal protective equipment. : Treat symptomatically. : See Section 11 for more detailed information on health effects and symptoms. Section: 5. FIREFIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Specific hazards during firefighting Hazardous combustion products Special protective equipment for firefighters Specific extinguishing methods Hazchem Code : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : None known. : Exposure to decomposition products may be a hazard to health. : Decomposition products may include the following materials: Carbon oxides : Use personal protective equipment. : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. : 2Z Section: 6. ACCIDENTAL RELEASE MEASURES / 8

3 Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up : Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Avoid inhalation, ingestion and contact with skin and eyes. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. : Do not allow contact with soil, surface or ground water. : Sweep up and shovel into suitable containers for disposal. Section: 7. HANDLING AND STORAGE Advice on safe handling Conditions for safe storage : Do not ingest. Avoid contact with skin and eyes. Do not breathe dust/fume/gas/mist/vapours/spray. Use only with adequate ventilation. Wash hands thoroughly after handling. Mixing this product with acid or ammonia releases chlorine gas. Do not mix with bleach or other chlorinated products will cause chlorine gas. : Keep out of reach of children. Keep container tightly closed. Store in suitable labeled containers. Storage temperature : 0 C to 25 C Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Contains no substances with occupational exposure limit values. Biological occupational exposure limits Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards. Personal protective equipment Eye protection Hand protection Skin protection Respiratory protection Hygiene measures : Safety glasses with side-shields : No special protective equipment required. : No special protective equipment required. : No special protective equipment required. : Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Wash face, hands and any exposed skin thoroughly after handling. Section: 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Colour Odour : solid : white : Chlorine / 8

4 ph : , (1 %) Flash point Odour Threshold Melting point/freezing point Initial boiling point and boiling range Evaporation rate Flammability (solid, gas) Upper explosion limit Lower explosion limit Vapour pressure Relative vapour density Relative density Water solubility Solubility in other solvents Partition coefficient: n- octanol/water Auto-ignition temperature Thermal decomposition Viscosity, kinematic Explosive properties Oxidizing properties Molecular weight VOC : Not applicable. : soluble : Yes Section: 10. STABILITY AND REACTIVITY Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products : Mixing this product with acid or ammonia releases chlorine gas. Do not mix with bleach or other chlorinated products will cause chlorine gas. : None known. : Acids : Decomposition products may include the following materials: Carbon oxides Section: 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Eye contact, Skin contact Potential Health Effects Eyes Skin : Causes serious eye irritation. : Health injuries are not known or expected under normal use / 8

5 Ingestion Inhalation Chronic Exposure : Harmful if swallowed. : Health injuries are not known or expected under normal use. : Health injuries are not known or expected under normal use. Experience with human exposure Eye contact Skin contact Ingestion Inhalation : Redness, Pain, Irritation : No symptoms known or expected. : Abdominal pain : No symptoms known or expected. Toxicity Product Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Carcinogenicity Reproductive effects Germ cell mutagenicity Teratogenicity STOT - single exposure STOT - repeated exposure Aspiration toxicity Components Acute inhalation toxicity Components Acute dermal toxicity : LD50 : 1,500 mg/kg : No skin irritation : Eye irritation : adipic acid 4 h LC50 rat: 7.7 mg/l : troclosene sodium LD50 rabbit: > 10,000 mg/kg adipic acid LD50 rabbit: 7,940 mg/kg Section: 12. ECOLOGICAL INFORMATION Ecotoxicity Environmental Effects : This product has no known ecotoxicological effects / 8

6 Product Toxicity to fish Toxicity to daphnia and other aquatic invertebrates Toxicity to algae Components Toxicity to algae : adipic acid 96 h EC50: 26.6 mg/l Persistence and degradability Poorly biodegradable Bioaccumulative potential no data available Mobility in soil no data available Other adverse effects no data available Section: 13. DISPOSAL CONSIDERATIONS Disposal methods : Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. The product should not be allowed to enter drains, water courses or the soil. Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not reuse empty containers. Dispose of in accordance with local, state, and federal regulations. Section: 14. TRANSPORT INFORMATION The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (ADG) Not dangerous goods Air transport (IATA) UN number : 3077 Description of the goods : Environmentally hazardous substance, solid, n.o.s. (troclosene sodium) Class : 9 Packing group : III Environmentally hazardous : Yes Sea transport (IMDG/IMO) UN number : / 8

7 Description of the goods : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (troclosene sodium) Class : 9 Packing group : III Marine pollutant : Yes Section: 15. REGULATORY INFORMATION National regulatory information Standard for the Uniform Scheduling of Medicines and Poisons : Schedule 6 The components of this product are reported in the following inventories: United States TSCA Inventory : On TSCA Inventory Canadian Domestic Substances List (DSL) : All components of this product are on the Canadian DSL. Australia. Industrial Chemical (Notification and Assessment) Act : New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand : Japan. ENCS - Existing and New Chemical Substances Inventory : Korea. Korean Existing Chemicals Inventory (KECI) : Philippines Inventory of Chemicals and Chemical Substances (PICCS) : China Inventory of Existing Chemical Substances : Taiwan Chemical Substance Inventory : Section: 16. OTHER INFORMATION Sources of key data used to compile the Safety Data Sheet Globally Harmonized System of Classification and Labelling of Chemicals (GHS) IARC: (International Agency for Research on Cancer) US. National Toxicology Program (NTP) Report on Carcinogens ECHA List of Publishable Substances Registered EU HPVCs (High Production Volume Chemicals) Issuing date : Date of first issue : Version : 1.3 Prepared by : Regulatory Affairs / 8

8 REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text / 8