For professional use only

Transcription

1 Date of issue: 7/09/2016 Revision date: 16/04/2015 Version: 2.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name : Dry Ink Cleaner 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Industrial/Professional use spec : Industrial For professional use only Uses advised against 1.3. Details of the supplier of the safety data sheet Heidelberg Druckmaschinen AG Kurfuersten-Anlage 60 D Heidelberg - GERMANY T F Consumables-msds@heidelberg.com 1.4. Emergency telephone number Emergency number : SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture/Substance: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Aspiration hazard, Category 1 Full text of H statements : see section 16 H304 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) : Signal word (CLP) Hazardous ingredients Hazard statements (CLP) Precautionary statements (CLP) : Danger GHS08 : Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, <2% aromatics; 4-hydroxy-4- methylpentan-2-one, diacetone alcohol : H304 - May be fatal if swallowed and enters airways : P301+P310 - IF SWALLOWED: Immediately call a doctor P331 - Do NOT induce vomiting P405 - Store locked up P501 - Dispose of contents/container to an authorised waste collection point 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture 9/09/2016 EN (English) 1/7

2 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, <2% aromatics Methoxypropoxypropanol, dipropyleenglycolmonomethyl ether substance with a Community workplace exposure limit (EC no) >= 50 Asp. Tox. 1, H304 (CAS No) (EC no) hydroxy-4-methylpentan-2-one, diacetone alcohol (CAS No) (EC no) (EC index no) <= 20 Not classified <= 10 Flam. Liq. 3, H226 Eye Irrit. 2, H319 STOT SE 3, H335 Specific concentration limits: Name Product identifier Specific concentration limits 4-hydroxy-4-methylpentan-2-one, diacetone alcohol (CAS No) (EC no) (EC index no) Full text of H-statements: see section 16 (C >= 10) Eye Irrit. 2, H319 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Assure fresh air breathing. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. Repeated exposure may cause skin dryness or cracking. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Get medical advice/attention. : Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician Most important symptoms and effects, both acute and delayed Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms/injuries after ingestion : May be fatal if swallowed and enters airways Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 9/09/2016 EN (English) 2/7

3 6.4. Reference to other sections See Heading 8. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. : Wash hands thoroughly after handling Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : Keep only in the original container in a cool, well ventilated place away from : Direct sunlight, Heat sources. Keep container closed when not in use. : Strong bases. Strong acids. SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Sources of ignition. Direct sunlight. EU Local name (2-Methoxymethylethoxy)-propanol EU IOELV TWA (mg/m³) 308 mg/m³ EU IOELV TWA (ppm) 50 ppm EU Notes Skin Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, <2% aromatics EU IOELV STEL (mg/m³) < 1200 mg/m³ EU IOELV STEL (ppm) < 184 ppm 8.2. Exposure controls Personal protective equipment: Avoid all unnecessary exposure. Hand protection: Protective gloves Eye protection: Chemical goggles or safety glasses Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment Other information: Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : Colourless. Odour : characteristic. Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point 9/09/2016 EN (English) 3/7

4 Boiling point Flash point : 62 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : Non flammable : 0,826 g/cm³ : < 20 mm²/s 9.2. Other information VOC content : 768,2 g/l SECTION 10: Stability and reactivity Reactivity Stable under normal conditions Chemical stability Stable under normal conditions Possibility of hazardous reactions Not established Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat > 5000 mg/kg LD50 dermal rat > mg/kg Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, <2% aromatics LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 5000 mg/kg LC50 inhalation rat (mg/l) 4,951 mg/kg 4-hydroxy-4-methylpentan-2-one, diacetone alcohol ( ) LD50 oral rat 3002 kilogram LD50 dermal rat mg/kg Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity : Repeated exposure may cause skin dryness or cracking Based on available data, the classification criteria are not met 9/09/2016 EN (English) 4/7

5 Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Dry Ink Cleaner Viscosity, kinematic Hydrocarbon Potential adverse human health effects and symptoms : May be fatal if swallowed and enters airways. < 20 mm²/s Yes. SECTION 12: Ecological information Toxicity LC50 fish 1 > mg/l EC50 Daphnia 1 > 100 mg/l ErC50 (algae) > 100 mg/l 4-hydroxy-4-methylpentan-2-one, diacetone alcohol ( ) LC50 fish mg/l EC50 Daphnia 1 > 1000 mg/l ErC50 (algae) 1000 mg/l Persistence and degradability Dry Ink Cleaner Persistence and degradability Not established. Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, <2% aromatics Persistence and degradability May biodegrade Bioaccumulative potential Dry Ink Cleaner Bioaccumulative potential Not established. Log Pow 0, Mobility in soil Results of PBT and vpvb assessment Other adverse effects : Avoid release to the environment SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations Ecology - waste materials SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN : Dispose in a safe manner in accordance with local/national regulations. : Avoid release to the environment. Hazardous waste due to toxicity. ADR IMDG IATA ADN RID UN number UN proper shipping name Not classified as dangerous in the meaning of transport regulations Not applicable Not applicable Not applicable Not applicable 9/09/2016 EN (English) 5/7

6 ADR IMDG IATA ADN RID Transport hazard class(es) Packing group Environmental hazards Marine pollutant : No No supplementary information available Special precautions for user - Overland transport Transport regulations (ADR) - Transport by sea Transport regulations (IMDG) - Air transport Transport regulations (IATA) - Inland waterway transport Transport regulations (ADN) - Rail transport Transport regulations (RID) Transport in bulk according to Annex II of MARPOL and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances VOC content : 768,2 g/l National regulations Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Data sources Other information : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. : None. Full text of H- and EUH-statements: Asp. Tox. 1 Aspiration hazard, Category 1 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Flam. Liq. 3 Flammable liquids, Category 3 STOT SE 3 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H226 Flammable liquid and vapour H304 May be fatal if swallowed and enters airways H319 Causes serious eye irritation H335 May cause respiratory irritation 9/09/2016 EN (English) 6/7

7 SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 9/09/2016 EN (English) 7/7