: Topenco 100 EC. Safety Data Sheet according to Regulation (EC) No. 453/2010 Date of issue: 18/06/2013 Revision date: : Version: 2.

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1 Date of issue: 18/06/2013 Revision date: : Version: 2.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category : Pesticide Uses advised against 1.3. Details of the supplier of the safety data sheet Globachem NV Brustem Industriepark - Lichtenberglaan 2019 B-3800 Sint-Truiden T F globachem@globachem.com Emergency telephone number Country Organisation/Company Address Emergency number SECTION 2: Hazards identification 2.1. Classification of the substance or mixture National Poisons Information Service (Newcastle Centre) Regional Drugs and Therapeutics Centre, Wolfson Unit National Poisons Information Service (Birmingham Centre) City Hospital National Poisons Information Service (Belfast Centre) Royal Victoria Hospital National Poisons Information Service (Cardiff Centre) Gwenwyn Ward, Llandough Hospital NPIS Edinburgh (Scottish Poisons Information Bureau) Royal Infirmary of Edinburgh Guy's & St Thomas' Poisons Unit Medical Toxicology Unit, Guy's & St Thomas' Hospital Trust Classification according to Directive 67/548/EEC or 1999/45/EC Xi; R36/38 N; R51/53 Full text of R-phrases: see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Directive 67/548/EEC or 1999/45/EC Hazard symbols : Claremont Place Newcastle-upon-Tyne NE1 4LP Newcastle Dudley Road B18 7QH Birmingham Grosvenor Road BT12 6BA Belfast Penarth CF64 2XX Cardiff 51 Little France Crescent EH16 4SA Edinburgh Avonley Road SE14 5ER London, R-phrases S-phrases Xi - Irritant N - Dangerous for the environment : R36/38 - Irritating to eyes and skin R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment : S2 - Keep out of the reach of children S13 - Keep away from food, drink and animal feedingstuffs S20/21 - When using do not eat, drink or smoke S24/25 - Avoid contact with skin and eyes 06/08/2013 EN (English) 1/6

2 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixture S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice Name Product identifier % Classification according to Directive 67/548/EEC penconazole (CAS No) ,15 Xn; R48/22 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] penconazole (CAS No) ,15 STOT RE 2, H373 Full text of R-, H- and EUH-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures 4.2. Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media 5.2. Special hazards arising from the substance or mixture 5.3. Advice for firefighters SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel For emergency responders 6.2. Environmental precautions 6.3. Methods and material for containment and cleaning up 6.4. Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities Storage conditions 7.3. Specific end use(s) : Keep only in the original container in a cool, well ventilated place away from : Direct sunlight. Keep container closed when not in use. 06/08/2013 EN (English) 2/6

3 SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Hand protection Eye protection Respiratory protection Other information : Wear protective gloves. : Chemical goggles or safety glasses. : Wear appropriate mask. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : amber. Odour Odour threshold ph : 4-8 % Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point : 62 C Self ignition temperature : 265 C Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Density : 0,98 g/ml Solubility Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic : 7,46 mpa.s (20 C +/- 0,1 C) Explosive properties : Not explosive. Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. 06/08/2013 EN (English) 3/6

4 SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat LD50 dermal rat LD50 dermal rabbit Irritation Corrosivity Sensitisation Repeated dose toxicity Carcinogenicity Mutagenicity Toxicity for reproduction Potential Adverse human health effects and symptoms > 2000 mg/kg > 2000 mg/kg Irritant : Irritating to eyes and skin. ph: 4-8 % ph: 4-8 % : Based on available data, the classification criteria are not met. SECTION 12: Ecological information Toxicity LC50 fishes 1 EC50 Daphnia 1 ErC50 (algae) mg/l (96 h) Oncorhynchus mykiss mg/l (48 h) Daphnia magna 1-10 mg/l (72 h) Pseudokirchneriella subcapitata Persistence and degradability Persistence and degradability Bioaccumulative potential Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects : Avoid release to the environment SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA UN number UN-No : 3082 UN-No.(IATA) : 3082 UN-No. (IMDG) : UN proper shipping name Proper Shipping Name : Dispose in a safe manner in accordance with local/national regulations. : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Transport document description : UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (penconazole), 9, III, (E) Transport hazard class(es) Class (UN) : 9 Class (IATA) : 9 06/08/2013 EN (English) 4/6

5 Class (IMDG) : 9 Hazard labels (UN) : Packing group Packing group (UN) : III Environmental hazards Dangerous for the environment : Other information : No supplementary information available Special precautions for user Overland transport Hazard identification number (Kemler No.) : 90 Classification code (UN) : M6 Orange plates : Special provision (ADR) : 274, 335, 601 Transport category (ADR) : 3 Tunnel restriction code : E Limited quantities (ADR) : 5L Excepted quantities (ADR) : E1 EAC code : 3Z Transport by sea Air transport Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions Contains no REACH candidate substance National regulations Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Full text of R-, H- and EUH-phrases:: STOT RE 2 Specific target organ toxicity Repeated exposure, Category 2 H373 May cause damage to organs through prolonged or repeated exposure R36/38 Irritating to eyes and skin R48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment N Dangerous for the environment 06/08/2013 EN (English) 5/6

6 Xi Xn Irritant Harmful SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 06/08/2013 EN (English) 6/6