For professional use only

Transcription

1 Date of issue: 5/09/2016 Revision date: 7/04/2015 Version: 2.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name : Damp Clean COMBI 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Industrial/Professional use spec : Industrial For professional use only Uses advised against 1.3. Details of the supplier of the safety data sheet Heidelberg Druckmaschinen AG Kurfuersten-Anlage 60 D Heidelberg - GERMANY T F Consumables-msds@heidelberg.com 1.4. Emergency telephone number Emergency number : SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture/Substance: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Acute toxicity (oral), Category 4 Skin corrosion/irritation, Category 1A Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation Full text of H statements : see section 16 H302 H314 H335 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) : Signal word (CLP) Hazardous ingredients Hazard statements (CLP) Precautionary statements (CLP) : Danger GHS05 GHS07 : 2-butoxyethanol, ethylene glycol monobutyl ether, butyl cellosolve; Quaternary C12-14 alkyl methylamine ethoxylate methylchloride; 2-aminoethanol, ethanolamine : H302 - Harmful if swallowed H314 - Causes severe skin burns and eye damage H335 - May cause respiratory irritation : P260 - Do not breathe vapours P264 - Wash hands thoroughly after handling P270 - Do not eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area P280 - Wear eye protection, protective gloves P301+P312 - IF SWALLOWED: call a POISON CENTER or doctor/physician if you feel unwell 9/09/2016 EN (English) 1/7

2 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] 2-butoxyethanol, ethylene glycol monobutyl ether, butyl cellosolve (CAS No) (EC no) (EC index no) aminoethanol, ethanolamine (CAS No) (EC no) (EC index no) Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Inhalation:dust,mist), H332 Skin Irrit. 2, H315 Eye Irrit. 2, H Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Inhalation:dust,mist), H332 Skin Corr. 1A, H314 STOT SE 3, H335 Aquatic Acute 1, H400 Aquatic Chronic 3, H412 C9-11 alcohol ethoxylate (CAS No) Eye Irrit. 2, H319 Quaternary C12-14 alkyl methylamine ethoxylate methylchloride (CAS No) Acute Tox. 4 (Oral), H302 Skin Irrit. 2, H315 Eye Dam. 1, H318 Specific concentration limits: Name Product identifier Specific concentration limits 2-aminoethanol, ethanolamine (CAS No) (EC no) (EC index no) Full text of H-statements: see section 16 (C >= 5) STOT SE 3, H335 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. : Rinse mouth. Do NOT induce vomiting. Call a POISON CENTER or doctor/physician if you feel unwell Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : May cause respiratory irritation Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Alcohol resistant foam. Unsuitable extinguishing media : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment. : Do not enter fire area without proper protective equipment, including respiratory protection. 9/09/2016 EN (English) 2/7

3 SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials Reference to other sections See Heading 8. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Avoid contact during pregnancy/while nursing. Use only outdoors or in a wellventilated area. : Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling Conditions for safe storage, including any incompatibilities Technical measures Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : Comply with applicable regulations. : Keep only in the original container in a cool, well ventilated place away from : Direct sunlight. Keep container tightly closed. : Strong bases. Strong acids. SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Sources of ignition. Direct sunlight. EU Local name 2-Butoxyethanol EU IOELV TWA (mg/m³) 98 mg/m³ EU IOELV TWA (ppm) 20 ppm EU IOELV STEL (mg/m³) 246 mg/m³ EU IOELV STEL (ppm) 50 ppm EU Notes Skin 8.2. Exposure controls Personal protective equipment: Avoid all unnecessary exposure. Hand protection: Protective gloves Eye protection: Chemical goggles or safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment 9/09/2016 EN (English) 3/7

4 Other information: Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : Colourless. Odour : characteristic. Odour threshold ph : 12,4-12,8 Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point : > 100 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Density : 0,996 g/cm³ Solubility : Soluble in water. Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information VOC content : 22 % SECTION 10: Stability and reactivity Reactivity Thermal decomposition generates : Corrosive vapours Chemical stability Stable under normal conditions Possibility of hazardous reactions Not established Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. Thermal decomposition generates : Corrosive vapours. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity : Oral: Harmful if swallowed. ATE CLP (oral) 1293,094 mg/kg bodyweight 9/09/2016 EN (English) 4/7

5 mg/kg LD50 dermal rat >= 2000 mg/kg LC50 inhalation rat (mg/l) 2,2 mg/l/4h C9-11 alcohol ethoxylate ( ) LD50 dermal rabbit > 5000 mg/kg > 2000 mg/kg Quaternary C12-14 alkyl methylamine ethoxylate methylchloride ( ) mg/kg 2-aminoethanol, ethanolamine ( ) LD50 dermal rabbit LC50 inhalation rat (mg/l) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential adverse human health effects and symptoms mg/kg > 2000 mg/kg 1-5 mg/l/4h : Causes severe skin burns and eye damage. ph: 12,4-12,8 : Serious eye damage, category 1, implicit ph: 12,4-12,8 Based on available data, the classification criteria are not met : May cause respiratory irritation. : Harmful if swallowed. SECTION 12: Ecological information Toxicity 1474 mg/l 1550 mg/l 911 mg/l C9-11 alcohol ethoxylate ( ) 10 mg/l 10 mg/l 10 mg/l Quaternary C12-14 alkyl methylamine ethoxylate methylchloride ( ) mg/l 1-10 mg/l 1-10 mg/l 2-aminoethanol, ethanolamine ( ) NOEC (acute) 349 mg/l 65 mg/l 1 mg/l 1,2 mg/l 9/09/2016 EN (English) 5/7

6 12.2. Persistence and degradability Damp Clean COMBI Persistence and degradability C9-11 alcohol ethoxylate ( ) Biodegradation > 60 % Not established. Quaternary C12-14 alkyl methylamine ethoxylate methylchloride ( ) Biodegradation > 60 % Bioaccumulative potential Damp Clean COMBI Bioaccumulative potential Not established. Log Pow 0,81 2-aminoethanol, ethanolamine ( ) Log Pow -1, Mobility in soil Results of PBT and vpvb assessment Other adverse effects : Avoid release to the environment SECTION 13: Disposal considerations Waste treatment methods Waste treatment methods Waste disposal recommendations Ecology - waste materials SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN : Dispose of contents/container in accordance with licensed collector s sorting instructions. : Dispose in a safe manner in accordance with local/national regulations. : Avoid release to the environment. ADR IMDG IATA ADN RID UN number UN proper shipping name Not classified as dangerous in the meaning of transport regulations Not applicable Not applicable Not applicable Not applicable Transport hazard class(es) Packing group Environmental hazards Marine pollutant : No Special precautions for user No supplementary information available - Overland transport Transport regulations (ADR) - Transport by sea Transport regulations (IMDG) - Air transport Transport regulations (IATA) 9/09/2016 EN (English) 6/7

7 - Inland waterway transport Transport regulations (ADN) - Rail transport Transport regulations (RID) Transport in bulk according to Annex II of MARPOL and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances VOC content : 22 % National regulations Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Data sources Other information : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. : None. Full text of H- and EUH-statements: Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4 Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 4 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Acute 1 Hazardous to the aquatic environment Acute Hazard, Category 1 Aquatic Chronic 3 Hazardous to the aquatic environment Chronic Hazard, Category 3 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Skin Corr. 1A Skin corrosion/irritation, Category 1A Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT SE 3 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H302 Harmful if swallowed H312 Harmful in contact with skin H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage H319 Causes serious eye irritation H332 Harmful if inhaled H335 May cause respiratory irritation H400 Very toxic to aquatic life H412 Harmful to aquatic life with long lasting effects SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 9/09/2016 EN (English) 7/7