1. Identification of the substance/mixture and of the company/undertaking

Transcription

1 Safety data sheet Page: 1/9 1. Identification of the substance/mixture and of the company/undertaking Product identifier Versamid 115 Chemical name: Fatty acids, C18-unsatd., dimers, reaction products with polyethylenepolyamines Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: adjuvant, Epoxy curing agent Details of the supplier of the safety data sheet Company: BASF SE Ludwigshafen GERMANY Pigments and Resins Telephone: address: Emergency telephone number International emergency number: Telephone:

2 Page: 2/9 2. Hazards identification Special hazards to man and environment according to 67/548/EC: Symbols of danger: Xi - Irritant N - Dangerous for the environment R-phrases: R38 Irritating to skin. R41 Risk of serious damage to eyes. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrases: S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 After contact with skin, wash immediately with plenty of water. S37/39 Wear suitable gloves and eye/face protection. Special hazards to man and environment according to (EC) 1272/2008: Signal word: Danger Hazard statement: H315 - Causes skin irritation. H318 - Causes serious eye damage. H410 - Very toxic to aquatic life with long lasting effects. Precautionary statement: P262 - Do not get in eyes, on skin, or on clothing. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. P273 - Avoid release to the environment. Hazard trigger: Fatty acids, C18-unsatd., dimers, reaction products with polyethylenepolyamines

3 Page: 3/9 3. Composition/information on ingredients General chemical description: Fatty acids, C18-unsatd., dimers, reaction products with polyethylenepolyamines Declaration of ingredients (67/548/EC): Value (%) Designation Symbol R-phrases NOTE EU number >= 70 Fatty acids, C18-unsatd., dimers, reaction Xi, N R38, R41, R50/ products with polyethylenepolyamines >= 0,1 - < 1 Triethylentetramine C R21, R34, R43, R52/ Declaration of ingredients (EC/1272/2008): Value (%) Designation Symbol Hazard statement (M-Factor) >= 70 Fatty acids, C18-unsatd., dimers, reaction products with polyethylenepolyamines H315, H318, H410 (M=1) NOTE REACH Reg. No. / EU-No >= 0,1 - < 1 Triethylentetramine H312, H314, H317, H First aid measures General information: In case of adverse health effects seek medical advice. After inhalation: not relevant. After skin contact: Rinse with running water and soap. Apply replenishing cream. Change all contaminated clothing. After eye contact: Rinse immediately with plenty of running water (for 10 minutes), seek medical attention from a specialist. After ingestion: Rinse the mouth. Drink 1-2 glasses of water. 5. Fire fighting measures Suitable extinguishing media: foam, extinguishing powder, carbon dioxide Extinguishing media which must not be used for safety reasons: None known Special protection equipment for firefighters: Wear self-contained breathing apparatus.

4 Page: 4/9 Combustion products or gases to be formed: Nitrous gases, carbon monoxide 6. Accidental release measures General information: Keep away from sources of ignition and naked flames. Personal precautions: Wear protective equipment. Ensure adequate ventilation. Environmental precautions: Do not empty into drains / surface water / ground water. Inform authorities in the event of product spillage to water courses or sewage systems. Methods for cleaning and take-up: Remove with liquid-absorbing material (sand, peat, sawdust). 7. Handling and storage Handling: Ensure good ventilation/suction at the workplace. Avoid open flames and sources of ignition. Storage: Keep container tightly sealed. Ensure adequate ventilation. 8. Exposure controls/personal protection Additional information for system design: Ensure good ventilation/suction at the workplace. Hand protection: suitable protective gloves Eye protection: Goggles which can be tightly sealed. facial protection Skin protection: suitable protective clothing

5 Page: 5/9 9. Physical and chemical properties Designation Value Method/ Remark Delivery state: State: liquid Odor: ammoniacal Color(s): amber Odour Threshold ph-value Boiling point Melting point Flash point > 200,0 C Flammability Decomposition temperature Autoignition temperature Evaporation rate Oxidizing properties Upper/lower flammability or explosive limits Vapor pressure Density (25 C) Vapour Density Viscosity Viscosity (dynamic) (no information) Solubilities (20 C; Solvent: Water) Octanol/Water distribution coefficient 0,98 g/cm3 no information mpas ASTM D Insoluble no information 10. Stability and reactivity Materials to avoid: Reacts with acids, with strong oxidants, epoxides and ketones. Hazardous decomposition products: No decomposition if used according to specifications. 11. Toxicological information Acute toxicity Acute oral toxicity: LD50 > 2000 mg/kg body weight (analogy) GHS: No category Skin irritation: irritating (analogy) GHS: Category 2 Eye irritation: severely irritating (analogy) GHS: Category 1 Sensitizing: Mutagenicity

6 Page: 6/9 Carcinogenicity Reproductive toxicity STOT-single exposition STOT-repeated exposition Aspiration hazard 12. Ecological information Toxicity Acute fish toxicity: LC50 > 1 - <= 10 mg product/l. Method: ISO 7346/2 (semistatic) GHS: Category 2 Acute invertebrate toxicity: EC50 > 0,1 - <= 1 mg product/l. Method: Acute daphnia toxicity according to test method OECD 202. GHS: Category 1 Chronic fish toxicity: Chronic invertebrate toxicity: Chronic bacterial toxicity: EC0 > 100 mg product/l. Method: Chronic bacterial toxicity according to test method DIN p. 8. Primary degradation: Ultimate biodegradation: The product is poorly biodegradable. GHS: Category 1 Persistence Bioaccumulative potential Mobility in soil

7 Page: 7/9 Results of PBT and vpvb assessment 13. Disposal considerations Product disposal: Dispose of according to regulations.

8 Page: 8/9 14. Transport information Road transport ADR: Classification code: M6 Hazard ident. number: 90 UN no.: 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (dimer fatty acid(c18)poly amido amine resin) Tunnelcode: (E) Railroad transport RID: Classification code: M6 Hazard ident. number: 90 UN no.: 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (dimer fatty acid(c18)poly amido amine resin) Inland water transport ADN: Classification code: M6 Hazard ident. number: UN no.: 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (dimer fatty acid(c18)poly amido amine resin) Marine transport IMDG: EmS: F-A,S-F Seawater pollutant: marine pollutant UN no.: 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (dimer fatty acid(c18)poly amido amine resin) Air transport IATA: Packaging instructions (cargo): 964 Packaging instructions (passenger): 964 UN no.: 3082 Environmentally hazardous substance, liquid, n.o.s. (dimer fatty acid(c18)poly amido amine resin)

9 Page: 9/9 15. Regulatory information The labeling of the product is indicated in Section 2 National regulations/information: WGK: 2, water-endangering product. (German VwVwS of May 17, 1999; Appendix 4) Storage class VCI: Other information Risk phrases: Full text of the R-phrases indicated by codes in this safety data sheet. The labeling of the product is indicated in Section 2. R21 Harmful in contact with skin. R34 Causes burns. R38 Irritating to skin. R41 Risk of serious damage to eyes. R43 May cause sensitization by skin contact. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Hazard statement: Full text of the H-phrases indicated by codes in this safety data sheet. The labeling of the product is indicated in Section 2. H312 - Harmful in contact with skin. H314 - Causes severe skin burns and eye damage. H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H318 - Causes serious eye damage. H410 - Very toxic to aquatic life with long lasting effects. H412 - Harmful to aquatic life with long lasting effects. Further information: The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. The data do not describe the product's properties (product specification). Neither should any agreed property nor the suitability of the product for any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.