SAFETY DATA SHEET DIAMMONIUM PHOSPHATE Page 1 Issued: 10/06/2014 Revision No: 1

Transcription

1 Page 1 Issued: 10/06/2014 Revision No: 1 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING Product name: Product No.: , , , , , , , , , , , , , , , , , Synonyms, Trade Names: DIAMMONIUM ORTHOPHOSPHATE, DIAMMONIUM HYDROGENPHOSPHATE, DIAMMONIUMFOSFAT (DAB) FG, GRANULAR FOOD GRADE, TECHNICAL GRADE, PRAYPHOS DAP CAS-No.: EC No.: Relevant identified uses of the substance or mixture and uses advised against Identified uses: Food industry Manufacture of fertilizers Fire- resistant agent Paper production Company name: Nexchem Ltd Unit 1 Underwood Court Elm Tree Avenue Glenfield Leicester Leicestershire LE3 8SG Tel: Fax: Emergency Tel: +44 (0) or +44 (0) (24 Hours) sales@nexchem.co.uk 2. HAZARDS IDENTIFICATION Classification of the substance or mixture Classification (EC 1272/2008) Physical and Chemical Hazards: Human health: Environment: Classification (67/548/EEC): The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. Environment: The product is not expected to be hazardous to the environment.

2 Issued: 10/06/2014 Page 2 Label elements EC No.: Label In Accordance With (EC) No. 1272/2008: No pictogram required. Other hazards: None under normal conditions. 3. COMPOSITION / INFORMATION ON INGREDIENTS Substances: Product name: CAS-No.: EC No.: FIRST AID MEASURES (SYMPTOMS) Description of first aid measures: Inhalation: Move the exposed person to fresh air at once. Rinse nose and mouth with water. Get medical attention if any discomfort continues. Ingestion: Immediately rinse mouth and provide fresh air. Get medical attention if any discomfort continues. Do not induce vomiting. Skin contact: Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin immediately with soap and water. Get medical attention if any discomfort continues. Eye contact: Promptly wash eyes with plenty of water while lifting the eye lids. Get medical attention if any discomfort continues. Most important symptoms and effects, both acute and delayed: Skin contact: Prolonged skin contact may cause redness and irritation. Eye contact: May cause temporary eye irritation. Indication of any immediate medical attention and special treatment needed: No recommendation given, but first aid may still be required in case of accidental exposure, inhalation or ingestion of this chemical. If in doubt, GET MEDICAL ATTENTION PROMPTLY! 5. FIRE-FIGHTING MEASURES Extinguishing media: This product is not flammable. Use fire-extinguishing media appropriate for surrounding materials. Special hazards arising from the substance or mixture: Hazardous combustion products: None under normal conditions. Advice for firefighters: Protective equipment for fire-fighters: Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

3 Issued: 10/06/2014 Page 3 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures: Wear protective clothing as described in Section 8 of this safety data sheet. Environmental precautions: Do not discharge onto the ground or into water courses. Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY alerted to the Environmental Agency or other appropriate regulatory body. Methods and material for containment and cleaning up: Avoid generation and spreading of dust. Shovel into dry containers. Cover and move the containers. Flush the area with water. Reference to other sections: Wear protective clothing as described in Section 8 of this safety data sheet. 7. HANDLING AND STORAGE Precautions for safe handling: Avoid spilling, skin and eye contact. Avoid handling which leads to dust formation. Conditions for safe storage, including any incompatibilities: Store in tightly closed original container in a dry and cool place. Store in a cool and well-ventilated place. Store separated from: Alkalis. Oxidising material. Specific end use(s): The identified uses for this product are detailed in Section EXPOSURE CONTROLS / PERSONAL PROTECTION Control parameters: Exposure controls: Ingredient Comments No exposure limits noted for ingredient(s). Protective equipment Engineering measures: Respiratory equipment: Hand protection: Eye protection: Hygiene measures: Provide adequate ventilation. No specific recommendation made, but protection against nuisance dust must be used when the general level exceeds 10 mg/m3. Use suitable protective gloves if risk of skin contact. The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material. Wear approved safety goggles. DO NOT SMOKE IN WORK AREA! Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash promptly if skin becomes contaminated. Promptly remove any clothing that becomes contaminated. When using do not eat, drink or smoke.

4 Issued: 10/06/2014 Page 4 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties: Appearance: Crystalline powder. Colour: White / off-white. Odour: Ammonia. Solubility: Soluble in water. Insoluble in: Organic solvents. Melting point ( C): 155 Relative density: 1.62 Bulk Density: ~ kg/m3 ph-value, Conc. Solution: 8.0 (10g/l solution, 25 C) Solubility Value (G/100G H2O@20 C): 69 Decomposition temperature ( C): Other information: Not available. 10. STABILITY AND REACTIVITY Reactivity: Not known. Chemical stability: Stable under normal temperature conditions. Possibility of hazardous reactions: Not available. Conditions to avoid: Avoid excessive heat for prolonged periods of time. Incompatible materials: Materials to Avoid: Strong alkalis. Strong oxidising substances. Hazardous decomposition products: Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours. Ammonia or amines. 11. TOXICOLOGICAL INFORMATION Information on toxicological effects: Toxic Dose 1 - LD 50: 6500 mg/kg (oral rat) Skin contact: Powder may irritate skin. Eye contact: Particles in the eyes may cause irritation and smarting. 12. ECOLOGICAL INFORMATION Ecotoxicity: Toxicity: Acute Fish Toxicity: Not regarded as dangerous for the environment. Not considered toxic to fish. LC 50, 96 Hrs, Fish mg/l 155

5 Issued: 10/06/2014 Page 5 Persistence and degradability: Degradability: The degradability of the product has not been stated. Bioaccumulative potential: No data available on bioaccumulation. Mobility in soil: Mobility: The product is soluble in water. Results of PBT and vpvb assessment: Other adverse effects: Not available. 13. DISPOSAL CONSIDERATIONS General information: Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste Disposal Authority. Waste treatment methods: Dispose of waste and residues in accordance with local authority requirements. 14. TRANSPORT INFORMATION General: Road Transport Notes: Rail Transport Notes: Sea Transport Notes: Air Transport Notes: The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID). Not Classified UN number: UN proper shipping name: Transport hazard class(es): No information required. Packing group: No information required. Environmental hazards: Environmentally Hazardous Substance/Marine Pollutant: No. Special precautions for user: No information required. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: No information required.

6 Issued: 10/06/2014 Page REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture: Statutory Instruments: The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Approved Code Of Practice: Classification and Labelling of Substances and Preparations Dangerous for Supply. Safety Data Sheets for Substances and Preparations. Guidance Notes: CHIP for everyone HSG(108). EU Legislation: Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments. Water hazard classification: WGK 1 Chemical Safety Assessment: Inventory Information: No chemical safety assessment has been carried out. EINEC Note: The regulatory information given above only indicates the principal regulations specifically Applicable to the product described in the safety data sheet. The user's attention is drawn to the possible existence of additional provisions which complete these regulations. Refer to all applicable national, international and local regulations or provisions. 16. OTHER INFORMATION Legal disclaimer: The information contained in this SDS does not constitute a risk assessment, and should not replace the user's own assessment of risks as required by other health and safety legislation. This advice is given by Nexchem Ltd who accept no legal liability for it except otherwise provided by law. The information contained herein is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It should not therefore be construed as guaranteeing specific properties. [final page]