SAFETY DATA SHEET. SECTION 1: Identification of the substance/mixture and of the company/undertaking.

Transcription

1 SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name or designation of the mixture Registration number Synonyms Issue date Version number Revision date Supersedes date - 05-January Relevant identified uses of the substance or mixture and uses advised against Industrial use. Identified uses Uses advised against None known Details of the supplier of the safety data sheet Manufacturer Laird Address 4707 Detroit Ave Cleveland, Ohio USA Telephone number Manufacturer Address clv-customerservice@lairdtech.com Laird C3&C4 Building, HongTai Industry Park, NO.87 Tai Feng Road, TEDA, Tianjin, China Telephone number +86(0) Corporate Office Address Laird PLC 100 Pall Mall, London, SW1Y 5NQ United Kingdom Telephone number +44 (0) Emergency telephone number Telephone hours SECTION 2: Hazards identification Within USA and Canada: (Chemtrec). Other Countries: hours per day, 7 days per week. Collect calls accepted Classification of the substance or mixture The mixture has been assessed and/or tested for its physical, health and environmental hazards and the following classification applies. Classification according to Regulation (EC) No 1272/2008 as amended This mixture does not meet the criteria for classification according to Regulation (EC) 1272/2008 as amended. Hazard summary 2.2. Label elements Label according to Regulation (EC) No. 1272/2008 as amended Hazard pictograms Signal word Hazard statements Precautionary statements Prevention Response Storage Disposal Not classified for health hazards. However, occupational exposure to the mixture or substance(s) may cause adverse health effects. Supplemental label information The mixture does not meet the criteria for classification. Observe good industrial hygiene practices. Wash hands after handling. Store away from incompatible materials. Dispose of waste and residues in accordance with local authority requirements Version #: 01 Revision date: - Issue date: 05-January-2017 A , Rev. A 1 / 6 01/12/2017, DCO

2 2.3. Other hazards Not a PBT or vpvb substance or mixture. SECTION 3: Composition/information on ingredients 3.2. Mixtures The components are not hazardous or are below required disclosure limits. Composition comments SECTION 4: First aid measures General information The full text for all H-statements is displayed in section 16. First aid personnel must be aware of own risk during rescue Description of first aid measures Inhalation Skin contact Eye contact Ingestion 4.2. Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures General fire hazards 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media 5.2. Special hazards arising from the substance or mixture 5.3. Advice for firefighters Special protective equipment for firefighters Special fire fighting procedures Specific methods Treat symptomatically. Will burn if involved in a fire. Use fire-extinguishing media appropriate for surrounding materials. SECTION 6: Accidental release measures During fire, gases hazardous to health may be formed. Selection of respiratory protection for firefighting: follow the general fire precautions indicated in the workplace. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Use standard firefighting procedures and consider the hazards of other involved materials. Use standard firefighting procedures and consider the hazards of other involved materials Personal precautions, protective equipment and emergency procedures For non-emergency Keep unnecessary personnel away. personnel For emergency responders 6.2. Environmental precautions 6.3. Methods and material for containment and cleaning up 6.4. Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities 7.3. Specific end use(s) Keep unnecessary personnel away. For personal protection, see Section 8 of the SDS. Avoid discharge into drains, water courses or onto the ground. Sweep up or gather material and place in appropriate container for disposal. For personal protection, see section 8 of the SDS. For waste disposal, see section 13 of the SDS. No special precautions are necessary beyond normal good hygiene practices. See Section 8 for additional personal protection advice when handling this product. Observe good industrial hygiene practices. Store in closed original container in a dry place. Industrial use. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Version #: 01 Revision date: - Issue date: 05-January / 6

3 Occupational exposure limits Latvia. OELs. Occupational exposure limit values of chemical substances in work environment Components Boron nitride (CAS ) Type TWA Value 6 mg/m3 Lithuania. OELs. Limit Values for Chemical Substances, General Requirements (Hygiene Norm HN 23:2007) Components Boron nitride (CAS ) Biological limit values Recommended monitoring procedures Derived no effect levels (DNELs) Predicted no effect concentrations (PNECs) 8.2. Exposure controls Appropriate engineering controls Type TWA Value No biological exposure limits noted for the ingredient(s). Follow standard monitoring procedures. 6 mg/m3 Used as intended, this product is not expected to generate potentially hazardous quantities of dust or fumes. In an industrial work environment no special precautions or control measures are required. Individual protection measures, such as personal protective equipment No special protective equipment required. General information Eye/face protection Skin protection - Hand protection - Other Respiratory protection Thermal hazards Hygiene measures Environmental exposure controls Not normally needed. Not normally needed. No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Not normally needed. Wear appropriate thermal protective clothing, when necessary. Wash hands after contact. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Odour Physical state Form Colour Odour threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Environmental manager must be informed of all major releases. Plate material. Solid. Solid. Green prepreg between metal sheets. > 204,4 C (> 400,0 F) Pensky-Martens Closed Cup Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Vapour pressure Vapour density Relative density Solubility(ies) Insoluble (20 C) Version #: 01 Revision date: - Issue date: 05-January / 6

4 Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Explosive properties Oxidising properties 9.2. Other information Not explosive. Not oxidising. No relevant additional information available. SECTION 10: Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. No dangerous reaction known under conditions of normal use. Avoid temperatures exceeding the decomposition temperature. Contact with incompatible materials. Strong oxidising agents. Carbon oxides. Metal oxides. SECTION 11: Toxicological information General information Under normal conditions of intended use, this material does not pose a risk to health. Information on likely routes of exposure Inhalation Not likely, due to the form of the product. Skin contact No adverse effects due to skin contact. Eye contact No adverse effects due to eye contact are expected. Ingestion No harmful effects expected in amounts likely to be ingested by accident. Symptoms Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory sensitisation Skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Mixture versus substance information Other information No adverse effects are expected. This product is an article. No data available. None known. SECTION 12: Ecological information Toxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Components Species Reaction product: bisphenol-a-(epichlorohydrin) (CAS ) Aquatic Crustacea EC50 Daphnia magna Test results 2,7 mg/l, 48 hours Fish LC50 Oncorhynchus mykiss 1,2 mg/l, 96 hours Persistence and degradability No data available Version #: 01 Revision date: - Issue date: 05-January / 6

5 12.3. Bioaccumulative potential Partition coefficient n-octanol/water (log Kow) Bioconcentration factor (BCF) Mobility in soil Results of PBT and vpvb assessment No data available. The product is insoluble in water and will sediment in water systems. Not a PBT or vpvb substance or mixture Other adverse effects An environmental hazard cannot be excluded in the event of unprofessional handling or disposal Additional information Estonia Dangerous substances in groundwater Data Copper (CAS ) Estonia Dangerous substances in soil Data Copper (CAS ) SECTION 13: Disposal considerations Copper (Cu) 1000 UG/L Copper (Cu) 15 UG/L Copper (Cu) 100 mg/kg Copper (Cu) 150 mg/kg Copper (Cu) 500 mg/kg Waste treatment methods Residual waste Contaminated packaging EU waste code Disposal methods/information Special precautions Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. The Waste code should be assigned in discussion between the user, the producer and the waste disposal company. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose in accordance with all applicable regulations. SECTION 14: Transport information ADR RID ADN IATA IMDG Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulations Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I and II, as amended Regulation (EC) No. 850/2004 On persistent organic pollutants, Annex I as amended Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 1 as amended Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 2 as amended Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 3 as amended Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex V as amended Version #: 01 Revision date: - Issue date: 05-January / 6

6 Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry, as amended Copper (CAS ) Regulation (EC) No. 1907/2006, REACH Article 59(10) Candidate List as currently published by ECHA Authorisations Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorisation, as amended Restrictions on use Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as amended Directive 2004/37/EC: on the protection of workers from the risks related to exposure to carcinogens and mutagens at work, as amended. Other EU regulations Directive 2012/18/EU on major accident hazards involving dangerous substances, as amended Reaction product: bisphenol-a-(epichlorohydrin) (CAS ) Other regulations National regulations The product is classified and labelled in accordance with Regulation (EC) 1272/2008 (CLP Regulation) as amended. This Safety Data Sheet complies with the requirements of Regulation (EC) No 1907/2006, as amended. Follow national regulation for work with chemical agents. Young people under 18 years old are not allowed to work with this product according to EU Directive 94/33/EC on the protection of young people at work, as amended Chemical safety assessment No Chemical Safety Assessment has been carried out. SECTION 16: Other information List of abbreviations References Information on evaluation method leading to the classification of mixture Full text of any H-statements not written out in full under Sections 2 to 15 Training information Disclaimer The classification for health and environmental hazards is derived by a combination of calculation methods and test data, if available. Follow training instructions when handling this material. Laird cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available Version #: 01 Revision date: - Issue date: 05-January / 6