SAFETY DATA SHEET Windscreen Sealant

Transcription

1 Windscreen Sealant Page 1 of 9 SAFETY DATA SHEET Windscreen Sealant SDS according to Regulation (EC) No. 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), Annex II-EU SECTION 1: Identification of the substance/mixture and of the company/undertaking Date issued Product identifier Product name Article no. Windscreen Sealant BP Relevant identified uses of the substance or mixture and uses advised against Product group Windscreen Sealant Relevant identified uses Uses advised against 1.3. Details of the supplier of the safety data sheet SU22 Professional uses: publicly accessible (administration, education, entertainment, services, craftsmen) PC35 Washing and cleaning products (including solvent based products) PROC10 Roller application or brushing ERC8A Wide dispersive indoor use of processing aids in open systems ERC8E Wide dispersive outdoor use of reactive substances in open systems No specific uses advised against are identified. Company name Kleinmann GmbH Postal address Am Trieb 13 Postcode D City Sonnenbuehl Country Germany Tel +49(0)7128/ Fax +49(0)7128/ chemie@kleinmann.net Website Enterprise no. DE Emergency telephone number Emergency telephone 8-12, Mo.-Fr.:+49(0)7128/ SECTION 2: Hazards identification 2.1. Classification of substance or mixture Classification according to Regulation (EC) No 1272/2008 [CLP/GHS] Substance / mixture hazardous properties 2.2. Label elements Hazard Pictograms (CLP) Flam. Liq. 2;H225; For further information, please refer to section 11.

2 Windscreen Sealant Page 2 of 9 Composition on the label Signal word Hazard statements Precautionary statements 2.3. Other hazards Health effect Environmental effects Ethanol Danger H225 Highly flammable liquid and vapour. P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P280 Wear protective gloves/protective clothing/eye protection/face protection. In high concentrations, vapours and spray mists are narcotic and may cause headache, fatigue, dizziness and nausea. See section 11 for additional information on health hazards. This product does not contain any PBT or vpvb substances. SECTION 3: Composition/information on ingredients 3.2. Mixtures Substance Identification Classification Contents Ethanol CAS no.: EC no.: Index no.: Synonyms: Ethanol F; R11 Flam. Liq. 2;H225; > 60 % Substance comments - The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: First aid measures 4.1. Description of first aid measures General Remove affected person from source of contamination. Inhalation Fresh air. Get medical attention if any discomfort continues. Skin contact Eye contact Ingestion Recommended personal protective equipment for first aid responders Remove contaminated clothes and rinse skin thoroughly with water. Get medical attention if irritation persists after washing. Immediately rinse with water. Get medical advice/attention if you feel unwell. Rinse mouth thoroughly with water and give large amounts of milk or water to people not unconscious. Get medical attention if any discomfort continues. Wear necessary protective equipment. For personal protection, see section Most important symptoms and effects, both acute and delayed Acute symptoms and effects As described in section 2.2 and 2.3. Delayed symptoms and effects Inhalation of high vapour concentrations may cause symptoms such as mild irritation, headache, dizziness, fatigue, nausea and in serious cases unconsciousness Indication of any immediate medical attention and special treatment needed Other Information If unconscious: Call an ambulance/physician immediately. Show this Safety Data Sheet. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media 5.2. Special hazards arising from the substance or mixture Fire and explosion hazards FLAMMABLE Advice for firefighters Use fire-extinguishing media appropriate for surrounding materials.

3 Windscreen Sealant Page 3 of 9 Personal protective equipment Wear necessary protective equipment. For personal protection, see section 8. Fire fighting procedures Reference is made to the company fire procedure. If risk of water pollution occurs, notify appropriate authorities. Avoid breathing fire vapours. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal protection measures 6.2. Environmental precautions Environmental precautionary measures Avoid inhalation of vapours and aerosol spray. Wear necessary protective equipment. For personal protection, see section 8. Avoid discharge into water courses or onto the ground. Contact local authorities in case of spillage to drain/aquatic environment Methods and material for containment and cleaning up Cleaning method 6.4. Reference to other sections Other instructions See section 8 and section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Handling Dam and absorb spillages with sand, earth or other non-combustible material. Wash contaminated area with water. Avoid contact with eyes. Use work methods which minimize spreading of vapours, dust, smoke, aerosols, splashes etc. to the extent technically possible Conditions for safe storage, including any incompatibilities Storage Store in tightly closed original container. Keep away from food, drink and animal feeding stuffs. Store above freezing. Conditions for safe storage Storage Temperature Value: 0-25 C. Storage Stabilit Durability: 36 months Specific end use(s) Specific use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational Exposure limit values Substance Identification Value TWA Year Ethanol CAS no.: EC no.: Index no.: Synonyms: Ethanol / from substances Substance Ethanol Group: Worker Exposure route: Inhalation Exposure frequency: Short term (acute) Type of effect: Local effect Value: 1900 mg/m³ Group: Worker Exposure route: Dermal 8-hour TWA: 1000 ppm 8-hour TWA: 1920 mg/m3 2011

4 Windscreen Sealant Page 4 of 9 Value: 343 mg/kg bw/day Group: Worker Exposure route: Inhalation Value: 950 mg/m³ Group: Consumer Exposure route: Inhalation Exposure frequency: Short term (acute) Type of effect: Local effect Value: 950 mg/m³ Group: Consumer Exposure route: Dermal Value: 206 mg/kg bw/day Group: Consumer Exposure route: Inhalation Value: 114 mg/m³ Group: Consumer Exposure route: Oral Value: 87 mg/kg bw/day Exposure route: Water Value: 0,96 mg/l Remarks: Freshwater. ECHA Exposure route: Water Value: 0,79 mg/l Remarks: Marine water. ECHA Exposure route: Water Value: 2,75 mg/l Remarks: Intermittent releases. ECHA Exposure route: Sewage treatment plant STP Value: 580 mg/l Exposure route: Sediment Value: 3,6 mg/kg sediment dw Remarks: Freshwater. ECHA Exposure route: Sediment Value: 2,9 mg/l Remarks: Marine water. ECHA Exposure route: Soil

5 Windscreen Sealant Page 5 of Exposure controls Recommended monitoring procedures Limitation of exposure on workplace Respiratory protection Respiratory protection Hand protection Hand protection Value: 0,63 mg/kg soil dw Not known. Personal protection equipment should be chosen according to the CEN standards and in discussion with the supplier of the personal protective equipment. In case of inadequate ventilation or when the product is heated, use suitable respiratory equipment with gas filter (type A2). Protective gloves should be used if there is a risk of direct contact or splash. Use protective gloves made of: Butyl rubber. Neoprene. Nitrile. Breakthrough time Breakthrough time for nitrile rubber, neoprene and butyl rubber is approx. 3 hours. The recommendation is a qualified estimate based on knowledge of the components. Elastic gloves stretch when used as glove thickness and thus the breakthrough time reduced. The EN standard test is performed at 23 C, but the practical temperature of the glove is approx. 35 C. The breakthrough time of the different glove guides, is therefor reduced by a factor 3. Eye / face protection Eye protection Skin protection Skin protection (except hands) No special precautions. Thermal hazards Thermal hazards See section 5. Appropriate environmental exposure control Environmental exposure controls See section 6. Wear approved, tight fitting safety glasses where splashing is probable. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Liquid. Colour Colourless to pale yellow. Odour Odour of alcohol. ph (as supplied) Value: ~ 5 Freezing point Value: < 0 C Boiling point / boiling range Value: > 35 C Flash point Value: 15 C Comments, Evaporation rate Not determined. Explosion limit Value: 3,5-15,0 Vol% Vapour pressure Value: < 20 kpa Bulk density Value: ~ 0,79 kg/l. Solubility description Completely soluble in water. Comments, Partition coefficient: n- octanol / water Comments, Spontaneous combustability Comments, Decomposition temperature Viscosity Not relevant. Not determined. Not relevant. Value: 49 Sec

6 Windscreen Sealant Page 6 of 9 Explosive properties Oxidising properties 9.2. Other information Other physical and chemical properties Comments No data recorded. Method of testing: 2 mm Auslaufbecher Ikke eksplosiv Does not meet the criteria for oxidising. SECTION 10: Stability and reactivity Reactivity Reactivity Chemical stability Stability Possibility of hazardous reactions Possibility of hazardous reactions No information required Conditions to avoid Conditions to avoid Avoid frost Incompatible materials Materials to avoid No information required Hazardous decomposition products Hazardous decomposition products In case of fire, toxic gases (CO, CO2, NOx) may be formed. SECTION 11: Toxicological information Information on toxicological effects Toxicological Information: Other toxicological data Toxicological data for substances Substance Ethanol LD50 oral LC50 inhalation There are no known reactivity hazards associated with this product. Stable under normal temperature conditions and recommended use. Toxicological tests on the product has not been performed. Value: mg/kg Animal test species: rat Duration: single dose Test reference: OECD 401 Comments: ECHA Value: mg/l Animal test species: rat Duration: 4h Test reference: OECD 401 Comments: ECHA Other information regarding health hazards General Potential acute effects Inhalation Skin contact Eye contact Ingestion Symptoms of Exposure Symptoms of overexposure Solvent vapours are hazardous and may cause nausea, sickness and headaches. Prolonged or repeated contact leads to drying of skin. In high concentrations, vapours are narcotic and may cause headache, fatigue, dizziness and nausea. Skin irritation is not anticipated when used normally. Splashes will irritate and cause redness and pain. Ingestion may cause irritation of the gastrointestinal tract, vomiting and diarrhoea. Inhalation of high volume of vapour may cause: Drowsiness, dizziness,

7 Windscreen Sealant Page 7 of 9 disorientation, vertigo. SECTION 12: Ecological information Toxicity Ecotoxicity Aquatic, comments The product is not expected to be hazardous to the environment. No data recorded Persistence and degradability Persistence and degradability The product is expected to be biodegradable Bioaccumulative potential Bioaccumulative potential The product does not contain any substances expected to be bioaccumulating Mobility in soil Mobility Not regarded as dangerous for the environment. The product is water soluble and may spread in water systems Results of PBT and vpvb assessment PBT assessment results Not Classified as PBT/vPvB by current EU criteria Other adverse effects Environmental details, summation SECTION 13: Disposal considerations Waste treatment methods Specify the appropriate methods of disposal Product classified as hazardous waste Packaging classified as hazardous waste EWC waste code Other Information For this product no classification is required for environmental hazards. Dispose of waste and residues in accordance with local authority requirements. Yes Yes SECTION 14: Transport information UN number ADR 1170 RID 1170 IMDG 1170 ICAO/IATA UN proper shipping name ADR ETHANOL SOLUTION RID ETHANOL SOLUTION IMDG ETHANOL SOLUTION ICAO/IATA ETHANOL SOLUTION Transport hazard class(es) ADR 3 Hazard no. 33 RID 3 IMDG 3 ICAO/IATA Packing group ADR II EWC: 0706 wastes from the MFSU of fats, grease, soaps, detergents, disinfectants and cosmetics When handling waste, consideration should be made to the safety precautions applying to handling of the product. Waste code applies to product remnants in pure form.

8 Windscreen Sealant Page 8 of 9 RID IMDG ICAO/IATA II II II Environmental hazards Special precautions for user EmS F-E, S-D Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Additional information. Additional information. Not relevant. SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EEC-directive Other Label Information Regulation (EC) No 648/2004 of the European Parliament and of the Council of 31 March 2004 on detergents. Dangerous Preparations Directive 1999/45/EC. Dangerous Substance Directive 67/548/EEC. As a general rule, persons under 18 years of age are not allowed to work with this product. Users must be carefully instructed in the proper work procedure, the dangerous properties of the product and the necessary safety instructions. For professional users only. Legislation and regulations The Management of Health and Safety at Work Regulations 1999 (SI 1999 No. 3242). Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. The List of Wastes (England) (Amendment) Regulations (SI 2005 No. 895) Chemical safety assessment Chemical safety assessment performed No SECTION 16: Other information Classification according to Regulation (EC) No 1272/2008 [CLP/GHS] List of relevant R-phrases (under headings 2 and 3). List of relevant H-phrases (Section 2 and 3). Training advice Information which has been added, deleted or revised Flam. Liq. 2; H225; R11 Highly flammable. Version 1 Responsible for safety data sheet Kleinmann GmbH H225 Highly flammable liquid and vapour. No particular training or education is required but the user must be familiar with this SDS. Users must be carefully instructed in the proper work procedure, the dangerous properties of the product and the necessary safety instructions. New safety data sheet.

9 Windscreen Sealant Page 9 of 9 Prepared by MP