: Mulch Worx Black Mulch Colorant

Transcription

1 Date of issue: 05/31/2017 Version: 1.0 SECTION 1: Identification 1.1. Identification Product form Product name : Mixtures : Mulch Worx Black Mulch Colorant 1.2. Recommended use and restrictions on use 1.3. Supplier Sanco Industries, Inc S. Calhoun Street Fort Wayne, IN Phone: Toll Free: Emergency telephone number Emergency number : 24 Hour Contact - CHEMTREC SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Not classified 2.2. GHS Label elements, including precautionary statements GHS-US labeling No labeling applicable 2.3. Other hazards which do not result in classification 2.4. Unknown acute toxicity (GHS US) Not applicable SECTION 3: Composition/Information on ingredients 3.1. Substances Not applicable product is a mixture 3.2. Mixtures Name Product identifier % GHS-US classification Carbon black* (CAS No) Carc. 2, H351 Ammonium salt of modified acrylic copolymer 4-5 Eye Irrit. 2B, H320 *See Section 11.1 for information on the carcinogenicity of carbon black Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the product label where possible). : Allow victim to breathe fresh air. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects (acute and delayed) Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use Immediate medical attention and special treatment, if necessary 05/31/2017 EN (English US) Page 1

2 SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media Unsuitable extinguishing media 5.2. Specific hazards arising from the chemical : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream Special protective equipment and precautions for fire-fighters Firefighting instructions Protection during firefighting SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Contain all water used for fire-fighting to the greatest extent possible. : Do not enter fire area without proper protective equipment, including respiratory protection For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel For emergency responders Protective equipment Emergency procedures 6.2. Environmental precautions : Equip cleanup crew with proper protection. : Ventilate area. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. : Keep only in the original container in a cool, well ventilated place. Keep container closed when not in use. : Strong bases. Strong acids. SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Sources of ignition. Direct sunlight. ACGIH ACGIH TWA (mg/m³) 3 mg/m³ (inhalable fraction) OSHA OSHA PEL (TWA) (mg/m³) 3.5 mg/m³ IDLH US IDLH (mg/m³) 1750 mg/m³ NIOSH NIOSH REL (TWA) (mg/m³) 3.5 mg/m³ 0.1 mg/m³ (in presence of Polycyclic aromatic hydrocarbons) Ammonium salt of modified acrylic copolymer Not applicable 8.2. Appropriate engineering controls Appropriate engineering controls : Ensure that proper ventilation is provided to maintain exposures below regulated limits. 05/31/2017 EN (English US) 2/5

3 8.3. Individual protection measures/personal protective equipment Personal protective equipment: Avoid all unnecessary exposure. Hand protection: Wear protective gloves. Eye protection: Chemical goggles or safety glasses Respiratory protection: Wear appropriate mask Other information: Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Color Odor Odor threshold : Liquid : Black : None ph : 9-10 Melting point Freezing point Boiling point : > 100 C Flash point : > 126 C Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) Vapor pressure Relative vapor density at 20 C Relative density Solubility Log Pow Auto-ignition temperature Decomposition temperature Viscosity, kinematic Viscosity, dynamic Explosion limits Explosive properties Oxidizing properties 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Stable Possibility of hazardous reactions None expected Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases. : Non flammable : Highly dispersible 05/31/2017 EN (English US) 3/5

4 10.6. Hazardous decomposition products Carbon monoxide. Carbon dioxide. Oxides of nitrogen. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity : Carbon black is designated by IARC as a Group 2B carcinogen (possibly carcinogenic to humans). This classification is based on exposure to airborne respirable carbon black particles. In this product, carbon black is present in a liquid mixture so that inhalation is not an anticipated route of exposure. IARC group In OSHA Hazard Communication Carcinogen list Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard Potential Adverse human health effects and symptoms SECTION 12: Ecological information Toxicity Persistence and degradability Mulch Worx Black Mulch Colorant Persistence and degradability Persistence and degradability 2B - Possibly carcinogenic to humans Yes : Bioaccumulative potential Mulch Worx Black Mulch Colorant Bioaccumulative potential Bioaccumulative potential Mobility in soil Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations Disposal methods Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local, state, and federal regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT 05/31/2017 EN (English US) 4/5

5 SECTION 15: Regulatory information US Federal regulations Listed on the United States TSCA (Toxic Substances Control Act) inventory International regulations CANADA Listed on the Canadian DSL (Domestic Sustances List) EU-Regulations Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) Listed on ELINCS (European List of Notified Chemical Substances) National regulations Listed on the AICS (Australian Inventory of Chemical Substances) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the Korean ECL (Existing Chemicals List) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed on the Canadian IDL (Ingredient Disclosure List) US State regulations California - Proposition 65 WARNING: This product contains chemicals known to the State of California to cause cancer. SECTION 16: Other information Other information Full text of H-phrases: --- H H : None. Causes eye irritation Suspected of causing cancer SDS US (GHS HazCom 2012) While Sanco Industries, Inc. believes the data set forth is accurate to the best of our knowledge, Sanco Industries, Inc. makes no warranties and expressly disclaims all liability for reliance thereon. Such data is offered solely for your consideration and verification. 05/31/2017 EN (English US) 5/5