1. PRODUCT AND COMPANY IDENTIFICATION

Transcription

1 Creation Date 03-Oct PRODUCT AND COMPANY IDENTIFICATION Revision Number 1 Product Identifier Product Description: Cat No. O Relevant identified uses of the substance or mixture and uses advised against Recommended Use Laboratory chemicals Uses advised against No Information available Details of the supplier of the safety data sheet Company Supplier REMEL (EUROPE) LIMITED Oxoid Ltd. Remel House Wade Road Clipper Boulevard West Basingstoke, Hants, UK Crossways, Dartford RG24 8PW Kent. DA2 6PT Telephone: +44 (0) UK Tel: (+44) Fax: (+44) mbd-sds@thermofisher.com address mbd-sds@thermofisher.com Emergency Telephone Number Carechem 24: +44 (0) HAZARDS IDENTIFICATION Classification of the substance or mixture REGULATION (EC) No 1272/2008 Not hazardous Classification according to EU Directives 67/548/EEC or 1999/45/EC For the full text of the R phrases mentioned in this Section, see Section 16 R -phrase(s) none Label Elements Signal Word None Hazard Statements Other Hazards Page 1 / 8

2 3. COMPOSITION/INFORMATION ON INGREDIENTS Component EC No. Weight % CAS-No Classification GHSCLAS REACH Reg. No. Glycerol ,4-Diazabicyclo[2.2.2]octane EEC No F; R11 Xn; R22 Xi; R36/38 Xi; R41 R52/53 Flam Sol. 2 (H228) Skin Irrit. 2 (H315) Eye Dam. 1 (H318) Eye Irrit. 2 (H319) Acute Tox. 4 (H302) Aquatic Chronic 3 (H412) For the full text of the R phrases mentioned in this Section, see Section FIRST AID MEASURES Description of first aid measures Eye Contact Skin Contact Ingestion Inhalation Notes to Physician Rinse thoroughly with plenty of water, also under the eyelids. Get medical attention if symptoms occur.. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes Clean mouth with water and drink afterwards plenty of water. Obtain medical attention. Move to fresh air. Get medical attention if symptoms occur.. Treat symptomatically 5. FIRE-FIGHTING MEASURES Extinguishing media Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment Extinguishing media which must not be used for safety reasons Page 2 / 8

3 Special hazards arising from the substance or mixture Thermal decomposition can lead to release of irritating gases and vapors Advice for fire-fighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation. Avoid contact with the skin and the eyes. Environmental precautions Prevent further leakage or spillage if safe to do so Methods and material for containment and cleaning up Soak up with inert absorbent material. 7. HANDLING AND STORAGE Precautions for Safe Handling Ensure adequate ventilation. Avoid contact with skin and eyes. Do not breathe vapors or spray mist. Keep away from open flames, hot surfaces and sources of ignition. Conditions for safe storage, including any incompatibilities Keep container tightly closed in a dry and well-ventilated place Specific End Uses Control parameters 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure limits Component European Union The United Kingdom France Belgium Spain Glycerol STEL: 30 mg/m 3 15 min TWA: 10 mg/m 3 8 hr VME: 10 mg/m 3 8 heures. aerosol TWA: 10 mg/m 3 8 uren VLA-ED: 10 mg/m 3 8 horas Component Italy Germany Portugal The Netherlands Finland Page 3 / 8

4 Component Italy Germany Portugal The Netherlands Finland TWA: 10 mg/m 3 8 horas TWA: 20 mg/m 3 8 tunteina Glycerol MAK: 50 mg/m 3 8 Stunden. inhalable fraction Peak: 100 mg/m 3 Component Austria Denmark Switzerland Poland Norway NDS: 10 mg/m 3 8 godzinach Glycerol STEL: 100 mg/m 3 15 Minuten MAK: 50 mg/m 3 8 Stunden Component Bulgaria Croatia Ireland Cyprus Czech Republic Glycerol TWA: 10 mg/m 3 8 satima. TWA: 10 mg/m 3 8 hr. TWA: 10 mg/m 3 8 hodinách. Ceiling: 15 mg/m 3 Component Estonia Gibraltar Greece Hungary Iceland Glycerol TWA: 10 mg/m 3 8 TWA: 10 mg/m 3 tundides. Component Russia - TWA Slovak Republic Slovenia Sweden Turkey Skin notation MAC: 1 mg/m 3 1,4- Diazabicyclo[2.2.2]octa ne Biological limit values Derived No Effect Level (DNEL) Predicted No Effect Concentration (PNEC) This product, as supplied, does not contain any hazardous materials with biological limits established by the region specific regulatory bodies. Exposure controls Engineering Measures Personal protective equipment Eye Protection Hand Protection Skin and body protection Respiratory Protection Ensure adequate ventilation, especially in confined areas Safety glasses with side-shields Protective gloves Long sleeved clothing When workers are facing concentrations above the exposure limit they must use appropriate certified respirators Hygiene Measures Environmental exposure controls Handle in accordance with good industrial hygiene and safety practice Prevent product from entering drains Page 4 / 8

5 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid Appearance Opaque ph 10.0 Boiling Point/Range Not applicable Melting Point/Range Flash Point Not applicable Autoignition Temperature 10. STABILITY AND REACTIVITY Reactivity Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions Hazardous Polymerization Hazardous Reactions. No information available Conditions to Avoid Heat, flames and sparks Incompatible Materials Peroxides, Strong oxidizing agents. Hazardous Decomposition Products None under normal use conditions 11. TOXICOLOGICAL INFORMATION Information on Toxicological Effects Acute Toxicity Product Information Product does not present an acute toxicity hazard based on known or supplied information Component Information Page 5 / 8

6 Component LD50 Oral LD50 Dermal LC50 Inhalation Glycerol mg/kg ( Rat ) mg/kg ( Rat ) 1,4-Diazabicyclo[2.2.2]octane 1700 mg/kg ( Rat ) Chronic Toxicity Carcinogenicity There are no known carcinogenic chemicals in this product Sensitization Mutagenic Effects Reproductive Effects Developmental Effects Target Organs Endocrine Disruptor Information No information available Respiratory system Eyes Kidney Skin None known 12. ECOLOGICAL INFORMATION Toxicity Ecotoxicity effects Component Freshwater Algae Freshwater Fish Microtox Water Flea Glycerol ml/l LC50 96 h 500 mg/l EC50 > 24 h 1,4- Diazabicyclo[2.2.2]octa ne mg/l LC50 96 h Persistence and degradability No information available Bioaccumulative potential Component Glycerol Mobility in soil log Pow Page 6 / 8

7 Results of PBT and vpvb assessment Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Waste from Residues / Unused Products Contaminated Packaging Dispose of in accordance with local regulations Empty containers should be taken to local recyclers for disposal 14. TRANSPORT INFORMATION IMDG/IMO Not regulated ADR Not regulated IATA Not regulated 15. REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work International Inventories Component EINECS ELINCS NLP TSCA DSL NDSL PICCS ENCS CHINA AICS KECL Glycerol X X - X X X X X 1,4-Diazabicyclo[2.2.2]octane X X - X X X X X Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory EINECS/ELINCS - European Inventory Lists DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List PICCS - Philippines Inventory of Chemicals and Chemical Substances ENCS - Japan Existing and New Chemical Substances Page 7 / 8

8 CHINA - China Inventory of Existing Chemical Substances AICS - Inventory of Chemical Substances KECL - Existing and Evaluated Chemical Substances Chemical Safety Assessment 16. OTHER INFORMATION Text of R phrases mentioned in Section 2-3 R11 - Highly flammable R22 - Harmful if swallowed R41 - Risk of serious damage to eyes R36/38 - Irritating to eyes and skin R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment Revision Date 03-Oct-2011 Revision Summary Not applicable This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006 Disclaimer The information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of Safety Data Sheet Page 8 / 8